An unprecedented 1-D mixed-valence Cu(II)/Cu(I) metal-organic framework bearing 2-phenyl imidazole dicarboxylates

Inorganic Chemistry Communications

Volumn 14, Issue 9, 2011, Pages 1432-1435

  Zhu, Yu ^a   Wang, Wen Yue ^a   Guo, Meng Wei ^a   Li, Gang ^a   Lu, Hui Jie ^a  

^a ZHENGZHOU UNIVERSITY   (China)

Author keywords

Copper; Crystal structure; Mixed valence; Phenyl imidazole dicarboxylate; Polymer

Indexed keywords

EID: 79960838169     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.05.039     Document Type: Article

References (39)

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37. Crystal structure analysis: A suitable single crystal of the compound 1 was selected for single-crystal X-ray diffraction analyses. The intensity data were measured on a Bruker smart APEXII CCD imaging plate area detector with graphite monochromated Mo-Kα radiation (λ = 0.71073 Å). Single crystal of 1 was selected and mounted on a glass fiber. All data were collected at room temperature using the ω-2θ scan technique and corrected for Lorenz-polarization effects. A correction for secondary extinction was applied. The structure was solved by direct methods and expanded using the Fourier technique. The non-hydrogen atoms were refined with anisotropic thermal parameters. Hydrogen atoms were included but not refined. All calculations were performed using the SHELXL-97 crystallographic software package [38].
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