Dependence of extraction properties of 2,6-dicarboxypyridine diamides on extractant structure

Solvent Extraction and Ion Exchange

Volumn 29, Issue 4, 2011, Pages 619-636

  Alyapyshev, M Yu ^a   Babain, V A ^a   Tkachenko, L I ^a   Eliseev, I I ^a   Didenko, A V ^b   Petrov, M L ^b  

^a KHLOPIN RADIUM INSTITUTE   (Russian Federation)

^b ST PETERSBURG STATE INSTITUTE OF TECHNOLOGY TECHNICAL UNIVERSITY   (Russian Federation)

Author keywords

Actinides; Diamides of pyridine 2,6 dicarboxylic acid; Extraction; Lanthanides

Indexed keywords

DIAMIDES; DIPICOLINIC ACIDS; EXTRACTANTS; EXTRACTION PROPERTIES; LIQUID-LIQUID EXTRACTION; STRUCTURE-REACTIVITY RELATIONSHIPS;

AMERICIUM; LIQUIDS; ORGANIC ACIDS; RARE EARTH ELEMENTS; URANIUM;

SOLVENT EXTRACTION;

EID: 79960673505     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366299.2011.581049     Document Type: Article

References (23)

1. Cuillerdier, C.; Musikas, C.; Hoel, P.; Nigond, L.; Vitart, X. Malonamides as new extractants for nuclear waste solutions. Sep. Sci. Technol. 1991, 26, 1229-1244.
2. Modolo, G.; Vijgen, H.; Serrano-Purroy, D.; Christiansen, B.; Malmbeck, R.; Sorel, C.; Baron, P. DIAMEX Counter-current extraction process for recovery of trivalent actinides from simulated high active concentrate. Sep. Sci. Technol. 2007, 42, 439-452.
3. Sasaki, Y.; Tachimori, S. Extraction of actinides(III), (IV), (V), (VI), and lanthanides(III) by structurally tailored diamides. Solv. Extr. Ion Exch. 2002, 20, 21-34.
4. Zhu, Z.-X.; Sasaki, Y.; Suzuki, H.; Suzuki, S.; Kimura, T. Cumulative study on solvent extraction of elements by N, N, N', N'-tetraoctyl-3-oxapentanediamide (TODGA) from nitric acid into n-dodecane. Anal. Chim. Acta 2004, 527, 163-168.
5. Mowafy, E.A.; El-Nagar, I.M.; Shalash, A.M. Development of novel organic extractants for application in various radioactive waste remediation. Arab J. Nucl. Sci. Appl. 2004, 37, 43-56.
6. Mowafy, E.A.; El-Nagar, I.M.; Shalash, A.M. Extraction and separation of U(VI), Th(IV) and Fe(III) with N, N'-dialkyl-4-pyridine carboxamides and N, N'-tetra-alkyl-2,6-pyridine dicarboxamides as new organic extractants from chloride medium. Arab J. Nucl. Sci. Appl. 2004, 37, 69-82.
7. Mowafy, E.A.; Shalash, A.M.; El-Nagar, I.M. Extraction of certain radionuclides by bipicolinamides as new extractants from nitric acid medium. Ind. J. Chem., A. 2003, 42, 3012-3016.
8. Babain, V.A.; Alyapyshev, M. Yu.; Smirnov, I.V.; Shadrin, A. Yu. Extraction of Am and Eu with N, N'-substituted pyridine-2,6-dicarboxamides in fluorinated diluents. Radiochem. 2006, 48, 369-373.
9. Mowafy, E.A. Evaluation of selectivity and radiolysis behavior of some promising isonicotinamids and dipicolinamides as extractants. Radiochim. Acta 2007, 95, 539-545.
10. Alyapyshev, M. Yu.; Babain, V.A.; Antonov, N.G.; Smirnov, I.V. Extraction of americium and europium from perchloric acid solutions with N, N'-dialkyl and N, N, N', N'-tetraalkylpyridine-2,6-dicarboxamides. Russ. J. Appl. Chem. 2006, 79, 1808-1815.
11. Alyapyshev, M. Yu.; Babain, V.A.; Smirnov, I.V.; Shadrin, A. Yu. Separation of americium and europium from solutions of nitric and perchloric acid using dipicolinic acid diamides. Chech. J. Phys. 2006, 56, D469-D475.
12. Babain, V.A.; Alyapyshev, M. Yu.; Kiseleva, R.N. Metal extraction by N, N'-dialkyl-N, N'-diaryl-dipicolinamides from nitric acid solutions. Radiochim. Acta 2007, 95, 217-223.
13. Shimada, A.; Yaita, T.; Narita, H.; Tachimori, S.; Okuno, K. Extraction studies of lanthanide(III) ions with N, N'-dimethyl-N, N'-diphenylpyridine-2,6-dicarboxyamide (DMDPhPDA) from nitric acid solutions. Solv. Extr. Ion Exch. 2004, 22, 147-161.
14. 3solutions using N, N'-dimethyl-N, N'-diphenylpyridine-2,6-dicarboxamide. Solv. Extr. Res. Dev. 2004, 11, 1-10.
15. Nigond, L.; Condamines, N.; Cordier, P.Y.; Livet, J.; Madic, C.; Cuillerdier, C.; Musikas, C.; Hudson, M.J. Recent advances in the treatment of nuclear wastes by the use of diamide and picolinamide extractants. Sep. Sci. Technol. 1995, 30, 2075-2099.
16. Clayden, J.; Greeves, N.; Warren, S.; Wothers, P. Organic Chemistry; Oxford University Press: New York, 2001.
17. Paulenova, A.; Alyapyshev, M. Yu.; Babain, V.A.; Herbst, R.S.; Law, J.D. Extraction of lanthanides with diamides of dipicolinic acid from nitric acid solutions. I. Sep. Sci. Technol. 2008, 43, 2606-2618.
18. Gordon, A.J.; Ford, R.A. The Chemist's Companion: A Handbook of Practical Data, Techniques, and References; Wiley-Interscience: New York, 1972.
19. Pearson, D.E.; Baxter, J.F.; Martin, J.C. Hammett's sigma constants in certain electrophilic reactions. J. Org. Chem. 1952, 17, 1511-1518.
20. Renaud, F.; Piguet, C.; Bernardinelli, G.; Biinzli, J.-C.G.; Hopfgartner, G. In search for mononuclear helical lanthanide building blocks with predetermined properties: Triple-stranded helical complexes with N, N, N', N'-tetraethylpyridine-2,6-dicarboxamide. Chem. Europ. J. 1997, 3, 1646-1659.
21. Alyapyshev, M. Yu.; Babain, V.A.; Pokhitonov, Yu.A.; Esimantovskiy, V.M. Extraction of palladium from nitric acid by diamides of dipicolinic acid. Proceedings of the International Conference on Advanced Nuclear Fuel Cycles and Systems, Global 2007, Boise, Idaho, September 9-13, 2007, pp. 1836-1839.
22. Romanovskiy, V.N.; Smirnov, I.V.; Babain, V.A.; Todd, T.A.; Herbst, R.S.; Law, J.D.; Brewer, K.N. The universal solvent extraction (UNEX) process. I. Development of the UNEX process solvent for the separation of cesium, strontium, and the actinides from acidic radioactive waste. Solv. Extr. Ion Exch. 2001, 19, 1-21.
23. Todd, T.A.; Law, J.D.; Herbst, R.S.; Romanovskiy, V.N.; Smirnov, I.V.; Babain, V.A.; Esimantovskiy, V.M.; Zaitsev, B.N.; Nazin, E.G.; Egorov, G.F. Development and characterization of a universal solvent mixture for the separation of Cs, Sr, actinides and rare-earth elements from acidic radioactive waste. Proceedings of the International Solvent Extraction Conference ISEC-2002, South Africa, Cape Town, 17-21 March, 2002, pp. 1220-1228.