Characterization of porous materials using combined small-angle X-ray and neutron scattering techniques

Journal of Membrane Science

Volumn 379, Issue 1-2, 2011, Pages 138-145

  Hu, Naiping ^a   Borkar, Neha ^a   Kohls, Doug ^a   Schaefer, Dale W ^a  

^a University of Cincinnati   (United States)

Author keywords

Membrane filter; Porosity; Porous material; SANS; SAXS

Indexed keywords

ANALYSIS METHOD; CELLULOSE ESTERS; CHORD LENGTHS; MEMBRANE FILTERS; NEUTRON SCATTERING TECHNIQUES; QUANTITATIVE INFORMATION; SANS; SAXS; SCATTERING DATA; SKELETAL DENSITY; SMALL-ANGLE X-RAYS; ULTRA-SMALL; ULTRA-SMALL-ANGLE NEUTRON SCATTERING;

ESTERS; MANUFACTURE; MUSCULOSKELETAL SYSTEM; NEUTRON SCATTERING; PORE SIZE; POROUS MATERIALS; SCANNING ELECTRON MICROSCOPY; STRUTS;

CHARACTERIZATION;

CELLULOSE; MIXED CELLULOSE ESTER; POROUS POLYMER; UNCLASSIFIED DRUG;

ANALYTICAL PARAMETERS; ARTICLE; MEAN PORE CHORD LENGTH; PORE SIZE; POROSITY; PRIORITY JOURNAL; QUANTITATIVE ANALYSIS; SCANNING ELECTRON MICROSCOPY; SKELETAL CHORD LENGTH; SKELETAL COMPOSITION; SKELETAL DENSITY; ULTRA SMALL ANGLE NEUTRON SCATTERING; ULTRA SMALL ANGLE X RAY SCATTERING; X RAY CRYSTALLOGRAPHY;

EID: 79960626433     PISSN: 03767388     EISSN: 18733123     Source Type: Journal    
DOI: 10.1016/j.memsci.2011.05.053     Document Type: Article

References (38)

1. Gregg S.J., Sing K.S.W. Adsorption Surface Area and Porosity 1982, Academic Press, London, New York. 2nd ed.
2. Barton T.J., Bull L.M., Klemperer W.G., Loy D.A., McEnaney B., Misono M., Monson P.A., Pez G., Scherer G.W., Vartuli J.C., Yaghi O.M. Tailored porous materials. Chem. Mater. 1999, 11:2633-2656.
3. Barret E.P., Joyner L.G., Halenda P.P. The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. JACS 1951, 73:373-380.
4. Brun M., Lallemand A., Quinson J.-F., Eyraud C. A new method for the simultaneous determination of the size and the shape of pores: the thermoporometry. Thermochim. Acta 1977, 21:59-88.
5. Brunauer S., Emmett P.H., Teller E. Adsorption of gases in multimolecular layers. JACS 1938, 60:309-319.
6. Avnir D., Farin D., Pfeifer P. Chemistry in noninteger dimensions between 2 and 3.2. Fractal surfaces of adsorbents. J. Chem. Phys. 1983, 79:3566-3571.
7. Pfeifer P., Avnir D., Farin D. Ideally irregular surfaces, of dimension greater than 2, in theory and practice. Surf. Sci. 1983, 126:569-572.
8. Kaneko K., Ishii C. Superhigh surface-area determination of microporous solids. Colloids Surf. 1992, 67:203-212.
9. Sing K.S.W., Everett D.H., Haul R.A.W., Moscou L., Pierotti R.A., Rouquerol J., Siemieniewska T. Reporting physisorption data for gas solid systems with special reference to the determination of surface-area and porosity (recommendations 1984). Pure Appl. Chem. 1985, 57:603-619.
10. Purcell W. Capillary pressures - their measurement using mercury and the calculation of permeability therefrom. Am. Inst. Min. Metall. Petrol. Engrs. 1949, 186:39-48.
11. Thompson A.H., Katz A.J., Raschke R.A. Mercury injection in porous-media - a resistance devils staircase with percolation geometry. Phys. Rev. Lett. 1987, 58:29-32.
12. Ksiazczak A., Radomski A., Zielenkiewicz T. Nitrocellulose porosity - thermoporometry. J. Therm. Anal. Calorim. 2003, 74:559-568.
13. Nakao S. Determination of pore-size and pore-size distribution. 39 filtration membranes. J. Membr. Sci. 1994, 96:131-165.
14. Ramaswamy S., Greenberg A.R., Peterson M.L. Non-invasive measurement of membrane morphology via UFDR: pore-size characterization. J. Membr. Sci. 2004, 239:143-154.
15. Schaefer D.W., Pekala R., Beaucage G. Origin of porosity in resorcinol formaldehyde aerogels. J. Non-Cryst. Solids 1995, 186:159-167.
16. Schaefer D.W., Beaucage G., Loy D.A., Shea K.J., Lin J.S. Structure of arylene-bridged polysilsesquioxane xerogels and aerogels. Chem. Mater. 2004, 16:1402-1410.
17. Schaefer D.W., Agamalian M.M. Ultra-small-angle neutron scattering: a new tool for materials research. Curr. Opin. Solid State Mater. Sci. 2004, 8:39-47.
18. Beaucage G., Ulibarri T.A., Black E.P., Schaefer D.W. Multiple size scale structures in silica-siloxane composites studied by small-angle scattering. Hybrid Org. -Inorg. Compos. 1995, 97-111. American Chemical Society, Washington, DC. J.E. Mark, C.Y.-C. Lee, P.A. Bianconi (Eds.).
19. Justice R.S., Schaefer D.W., Vaia R.A., Tomlin D.W., Bunning T.J. Interface morphology and phase separation in polymer-dispersed liquid crystal composites. Polymer 2005, 46:4465-4473.
20. Cipelletti L., Carpineti M., Giglio M. Fractal morphology, spatial order, and pore structure in microporous membrane filters. Langmuir 1996, 12:6446-6451.
21. Cipelletti L, Carpineti M., Giglio M. Microporous membrane filters: a static light scattering study. Physica A 1997, 235:248-256.
22. Porod G. Die Röntgenkleinwinkelstreuung von dichtgepackten kolloiden Systemen. Kolloid-Z. 1951, 124:83-114.
23. Wu W. Small-angle X-ray study of particulate reinforced composites. Polymer 1982, 23:1907-1912.
24. Cipelletti L., Carpineti M., Giglio M. Static light scattering characterisation of microporous membrane filters. J. Mol. Struct. 1996, 383:31-35.
25. Ilavsky J., Jemian P.R. Irena: tool suite for modeling and analysis of small-angle scattering. J. Appl. Crystallogr. 2009, 42:347-353.
26. Barker J.G., Glinka C.J., Moyer J.J., Kim M.H., Drews A.R., Agamalian M. Design and performance of a thermal-neutron double-crystal diffractometer for USANS at NIST. J. Appl. Crystallogr. 2005, 38:1004-1011.
27. Kline S.R. Reduction and analysis of SANS and USANS data using IGOR Pro. J. Appl. Crystallogr. 2006, 39:895-900.
28. Guinier A., Fournet G. Small Angle Scattering of X-rays 1955, Wiley, New York.
29. Debye P., Anderson R., Brumberger H. Scattering by an inhomogeneous solid. II. The correlation function and its application. J. Appl. Phys. 1957, 28:679.
30. Fernandez A.M., Wignall G.D., Sperling L.H. Multicomponent polymer materials. Adv. Chem. Ser. 1986, 153-170. American Chemical Society, Washington, DC. D.R. Paul, L.H. Sperling (Eds.).
31. Martin J.E., Hurd A.J. Scattering from fractals. J. Appl. Crystallogr. 1987, 20:61-78.
32. Schaefer D.W., Bunker B.C., Wilcoxon J.P. Fractals and phase-separation. Proc. R. Soc. Lond. Ser. A-Math. Phys. Eng. Sci. 1989, 423:35-53.
33. Keefer K.D., Schaefer D.W. Growth of fractally rough colloids. Phys. Rev. Lett. 1986, 56:2376-2379.
34. Roe R.-J. Methods of X-ray and Neutron Scattering in Polymer Science 2000, Oxford University Press, New York.
35. Zeman L. Characterization of microfiltration membranes by image-analysis of electron-micrographs. 2. Functional and morphological parameters. J. Membr. Sci. 1992, 71:233-246.
36. Zeman L., Denault L. Characterization of microfiltration membranes by image-analysis of electron-micrographs. 1. Method development. J. Membr. Sci. 1992, 71:221-231.
37. Kim K.J., Fane A.G., Benaim R., Liu M.G., Jonsson G., Tessaro I.C., Broek A.P., Bargeman D. A comparative-study of techniques used for porous membrane characterization - pore characterization. J. Membr. Sci. 1994, 87:35-46.
38. Charcosset C., Bernengo J.C. Comparison of microporous membrane morphologies using confocal scanning laser microscopy. J. Membr. Sci. 2000, 168:53-62.