Polyoxometalate-based ionic liquids as catalysts for deep desulfurization of fuels

Fuel Processing Technology

Volumn 92, Issue 10, 2011, Pages 1842-1848

  Zhu, Wenshuai ^a   Huang, Wangli ^a   Li, Huaming ^a   Zhang, Ming ^a   Jiang, Wei ^a   Chen, Guangying ^b   Han, Changri ^b  

^a JIANGSU UNIVERSITY   (China)

^b HAINAN NORMAL UNIVERSITY   (China)

Author keywords

Catalysis; Characterization; Oxidative desulfurization; Polyoxometalate based ionic liquids

Indexed keywords

4 ,6-DIMETHYL-DIBENZOTHIOPHENE; 4 ,6-DMDBT; DBT(DIBENZOTHIOPHENE); DE-SULFURIZATION PROCESS; DEEP DESULFURIZATION; DESULFURIZATION EFFICIENCY; DIESEL OIL; ENVIRONMENTAL CATALYSIS; EXPERIMENTAL EVALUATION; HIGH ACTIVITY; IMIDAZOLIUM; KEGGIN-TYPE; LOW-SULFUR DIESEL; MOLAR RATIO; OPTIMAL CONDITIONS; OXIDATIVE DESULFURIZATION; PHOSPHOMOLYBDATES; PHOSPHOTUNGSTATE; POLYOXOMETALATE-BASED IONIC LIQUIDS; REACTION SYSTEM;

CATALYSIS; CATALYSTS; CATALYTIC OXIDATION; CHARACTERIZATION; DESULFURIZATION; DIESEL FUELS; HYBRID MATERIALS; IONS; OXIDES; SULFUR;

IONIC LIQUIDS;

EID: 79960561542     PISSN: 03783820     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuproc.2011.04.030     Document Type: Article

References (39)

1. J. Esser, P. Wasserscheid, and A. Jess Deep desulfurization of oil refinery streams by extraction with ionic liquids Green Chem. 6 2004 314 322
2. C. Song An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel Catal. Today 86 2003 211 263
3. R. Sundararaman, X.L. Ma, and C.S. Song Oxidative desulfurization of jet and diesel fuels using hydroperoxide generated in situ by catalytic air oxidation Ind. Eng. Chem. Res. 49 2010 5561 5568
4. P.G. Rickert, M.R. Antonio, M.A. Firestone, K.A. Kubatko, T. Szreder, J.F. Wishart, and M.L. Dietz Tetraalkylphosphonium polyoxometalate ionic liquids: novel, organic-inorganic hybrid materials J. Phys. Chem. B 111 2007 4685 4692 (Pubitemid 46826373)
5. C.L. Hill, and C.M. Prosser-McCartha Homogeneous catalysis by transition metal oxygen anion clusters Coord. Chem. Rev. 143 1995 407 455
6. 2 oxidation of isobutyraldehyde using Keggin, Dawson and transition metal-substituted lacunary heteropolyanions J. Mol. Catal. A: Chem. 184 2002 451 464 (Pubitemid 34760371)
7. M.T. Pope, and A. Müller Polyoxometalate chemistry: an old field with new dimensions in several disciplines Angew. Chem. Int. Ed. 30 1991 34 48
8. G. Li, Y. Ding, J. Wang, X. Wang, and J. Suo New progress of Keggin and Wells-Dawson type polyoxometalates catalyze acid and oxidative reactions J. Mol. Catal. A: Chem. 262 2007 67 76 (Pubitemid 46080699)
9. N. Mizuno, and M. Misono Heterogeneous catalysis Chem. Rev. 98 1998 199 218
10. 2 as oxidant Fuel 88 2009 431 436
11. 36] catalyst assembled in emulsion droplets J. Catal. 239 2006 369 375
12. C. Li, Z.X. Jiang, J.B. Gao, Y.X. Yang, S.J. Wang, F.P. Tian, F.X. Sun, X.P. Sun, P.L. Ying, and C.R. Han Ultra-deep desulfurization of diesel: oxidation with a recoverable catalyst assembled in emulsion Chem. Eur. J. 10 2004 2277 2280
13. M.C. Capel-Sanchez, P. Perez-Presas, J.M. Campos-Martin, and J.L.G. Fierro Highly efficient deep desulfurization of fuels by chemical oxidation Catal. Today 157 2010 390 396
14. W.S. Zhu, H.M. Li, Q.Q. Gu, P.W. Wu, G.P. Zhu, Y.S. Yan, and G.Y. Chen Kinetics and mechanism for oxidative desulfurization of fuels catalyzed by peroxo-molybdenum amino acid complexes in water-immiscible ionic liquids J. Mol. Catal. A: Chem. 336 2011 16 22
15. 40 as efficient and recoverable catalyst for the oxidative removal of dibenzothiophene Catal. Today 150 2010 37 41
16. W.S. Zhu, H.M. Li, X. Jiang, Y.S. Yan, J.D. Lu, L.N. He, and J.X. Xia Commercially available molybdic compound-catalyzed ultra-deep desulfurization of fuels in ionic liquids Green Chem. 10 2008 641 646 (Pubitemid 351782884)
17. D. Huang, Y.C. Lu, Y.J. Wang, and G.S. Luo Catalytic kinetics of dibenzothiophene oxidation with the combined catalyst of quaternary ammonium bromide and phosphotungstic acid Ind. Eng. Chem. Res. 46 2007 6221 6227 (Pubitemid 47477330)
18. W.S. Zhu, H.M. Li, X. Jiang, Y.S. Yan, J.D. Lu, and J.X. Xia Oxidative desulfurization of fuels catalyzed by peroxotungsten and peroxomolybdenum complexes in ionic liquids Energy Fuels 21 2007 2514 2516 (Pubitemid 47595577)
19. W.L. Huang, W.S. Zhu, H.M. Li, H. Shi, G.P. Zhu, H. Liu, and G.Y. Chen Heteropolyanion-based ionic liquid for deep desulfurization of fuels in ionic liquids Ind. Eng. Chem. Res. 49 2010 8998 9003
20. S.S. Wang, W. Liu, Q.X. Wan, and Y. Liu Homogeneous epoxidation of lipophilic alkenes by aqueous hydrogen peroxide: catalysis of a Keggin-type phosphotungstate-functionalized ionic liquid in amphipathic ionic liquid solution Green Chem. 11 2009 1589 1594
21. P.G. Rickert, M.R. Antonio, M.A. Firestone, K.A. Kubatko, T. Szreder, J.F. Wishart, and M.L. Dietz Tetraalkylphosphonium polyoxometalates: electroactive, "task-specific" ionic liquids Dalton Trans. 5 2007 529 531 (Pubitemid 46150743)
22. T. Rajkumar, and G.R. Rao Synthesis and characterization of hybrid molecular material prepared by ionic liquid and silicotungstic acid Mater. Chem. Phys. 112 2008 853 857
23. B. Smarsly, and H. Kaper Liquid inorganic-organic nanocomposites: novel electrolytes and ferrofluids Angew. Chem. Int. Ed. 44 2005 3809 3811 (Pubitemid 40885688)
24. A.B. Bourlinos, R. Herrera, N. Chalkias, D.D. Jiang, Q. Zhang, L.A. Archer, and E.P. Giannelis Surface-functionalized nanoparticles with liquid-like behavior Adv. Mater. 17 2005 234 237 (Pubitemid 40242482)
25. A.B. Bourlinos, K. Raman, R. Herrera, Q. Zhang, L.A. Archer, and E.P. Giannelis A liquid derivative of 12-tungstophosphoric acid with unusually high conductivity J. Am. Chem. Soc. 126 2004 15358 15359 (Pubitemid 39577452)
26. Y. Leng, J. Wang, D.R. Zhu, X.Q. Ren, H.Q. Ge, and L. Shen Heteropolyanion-based ionic liquids: reaction-induced self-separation catalysts for esterification Angew. Chem. Int. Ed. 48 2009 168 171
27. 2 Chem. Eur. J. 12 2006 4176 4184 (Pubitemid 43759739)
28. K. Yamaguchi, C. Yoshida, S. Uchida, and N. Mizuno Peroxotungstate immobilized on ionic liquid-modified silica as a heterogeneous epoxidation catalyst with hydrogen peroxide J. Am. Chem. Soc. 127 2005 530 531 (Pubitemid 40174372)
29. X.Y. Shi, and J.F. Wei Selective oxidation of sulfide catalyzed by peroxotungstate immobilized on ionic liquid-modified silica with aqueous hydrogen peroxide J. Mol. Catal. A: Chem. 280 2008 142 147
30. 3- immobilized on ionic liquid-modified polymer as a heterogeneous catalyst for alcohol oxidation with hydrogen peroxide Synth. Commun. 38 2008 1610 1616 (Pubitemid 351591661)
31. T. Rajkumar, and G.R. Rao Investigation of hybrid molecular material prepared by ionic liquid and polyoxometalate anion J. Chem. Sci. 120 2008 587 594
32. C. Rocchiccioli-Deltcheff, A. Aouissi, M.M. Bettahar, S. Launay, and M. Fournier Catalysis by 12-molybdophosphates: 1. Catalytic reactivity of 12-molybdophosphoric acid related to its thermal behavior investigated through IR, Raman, polarographic, and X-ray diffraction studies: a comparison with 12-molybdosilicic acid J. Catal. 164 1996 16 27
33. T. Rajkumar, and G. Ranga Rao Characterization of hybrid molecular material prepared by 1-butyl 3-methyl imidazolium bromide and phosphotungstic acid Mater. Lett. 62 2008 4134 4136
34. 40) combined with cetylpyridinium bromide in the epoxidation of cyclopentene J. Mol. Catal. A: Chem. 230 2005 121 128 (Pubitemid 40312848)
35. 2/ionic liquid emulsion system Green Chem. 13 2011 1210 1216
36. 3 J. Am. Chem. Soc. 117 1995 681 691
37. 40: transform-and-retransform process between catalytic precursor and catalytic activity species J. Mol. Catal. A: Chem. 289 2008 22 27
38. L.L. Liu, C.C. Chen, X.F. Hu, T. Mohamood, W.H. Ma, J. Lin, and J.C. Zhao A role of ionic liquid as an activator for efficient olefin epoxidation catalyzed by polyoxometalate New. J. Chem. 32 2008 283 289 (Pubitemid 351230318)
39. 2 systems Appl. Catal. A: Gen. 219 2001 267 280