Fischer aminocarbene complexes of chromium and iron: Anomalous electrochemical reduction of p-carbonyl substituted derivatives

Electrochimica Acta

Volumn 56, Issue 19, 2011, Pages 6853-6859

  Hoskovcová, Irena ^a   Zvěřinová, Radka ^a   Roháčová, Jana ^a   Dvořák, Dalimil ^a   Tobrman, Tomáš ^a   Záliš, Stanislav ^b   Ludvík, Jiří ^b  

^a INSTITUTE OF CHEMICAL TECHNOLOGY   (Czech Republic)

^b J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

Author keywords

DFT calculations; Electrochemistry; Fischer aminocarbene complexes; LFER; LUMO location

Indexed keywords

AMINO CARBENE COMPLEXES; CARBONYL FUNCTION; DFT CALCULATION; DICARBONYL COMPOUNDS; DOUBLE BOND CHARACTER; ELECTROCHEMICAL REDUCTIONS; ELECTRON DELOCALIZATION; ELECTRON DISTRIBUTIONS; ELECTRONIC INTERACTIONS; LFER; LUMO LOCATION; P-PHENYLENE; REDOX PROPERTY; REDUCTION POTENTIAL; TITLE COMPOUNDS;

CARBONYLATION; CHROMIUM; COMPLEXATION; ELECTROCHEMISTRY; ELECTROLYTIC REDUCTION; IRON COMPOUNDS;

CHROMIUM COMPOUNDS;

EID: 79960412113     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2011.05.096     Document Type: Article

References (13)

1. I. Hoskovcová, J. Roháčová, L. Meca, T. Tobrman, D. Dvořák, and J. Ludvík Electrochim. Acta 50 2005 4911
2. I. Hoskovcová, J. Roháčová, D. Dvořák, T. Tobrman, S. Záliš, R. Zvěřinová, and J. Ludvík Electrochim. Acta 55 2010 8341
3. S. Watanuki, N. Ochifuji, and M. Mori Organometalics 14 1995 5062 (and references therein)
4. M.A. Fernandez-Rodríguez, P. Garcia-Garcia, and E. Aguillar Chem. Commun. 46 2010 7670
5. T. Tobrman, L. Meca, H. Dvořáková, J. Černý, and D. Dvořák Organometallics 25 2006 5540
6. M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, J.A. Montgomery Jr., T. Vreven, K.N. Kudin, J.C. Burant, J.M. Millam, S.S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G.A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J.E. Knox, H.P. Hratchian, J.B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R.E. Stratmann, O. Yazyev, A.J. Austin, R. Cammi, C. Pomelli, J.W. Ochterski, P.Y. Ayala, K. Morokuma, G.A. Voth, P. Salvador, J.J. Dannenberg, V.G. Zakrzewski, S. Dapprich, A.D. Daniels, M.C. Strain, O. Farkas, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J.V. Ortiz, Q. Cui, A.G. Baboul, S. Clifford, J. Cioslowski, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R.L. Martin, D.J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, M. Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, C. Gonzalez, and J.A. Pople Gaussian 03, Revision C. 02 2004 Gaussian, Inc. Wallingford, CT
7. A.D. Becke J. Chem. Phys. 98 1993 5648
8. A.D. Becke Phys. Rev. A 38 1988 3098
9. P.C. Hariharan, and J.A. Pople Theor. Chim. Acta 28 1973 213
10. V.A. Rassolov, J.A. Pople, M.A. Ratner, and T.L. Windus J. Chem. Phys. 109 1998 1223
11. M. Havránek, M. Hušák, and D. Dvořák Organometallics 14 1995 5024
12. Yu. Kargin, O. Manoušek, and P. Zuman J. Electroanal. Chem. 12 1966 443
13. P. Zuman, O. Manoušek, and S.K. Vig J. Electroanal. Chem. 19 1968 147