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Volumn 63, Issue , 2011, Pages 395-430

Photocatalysis by inorganic solid materials: Revisiting its definition, concepts, and experimental procedures

Author keywords

Band structure and excitation; Electron hole recombination; Energy conversion; Langmuir Hinshelwood mechanism; Photocatalysis and catalysis; Photocatalytic activity; Physical property activity correlation; Quantum efficiency; Synergetic effect

Indexed keywords


EID: 79960264328     PISSN: 08988838     EISSN: None     Source Type: Book Series    
DOI: 10.1016/B978-0-12-385904-4.00001-9     Document Type: Book
Times cited : (77)

References (71)
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    • Papers reporting activation energy of photocatalytic reactions in the period 2000-2004. Figures and compounds in square brackets and parentheses, respectively, show activation energy in the unit of kJ mol-1 and substrate. (a), [10.9 (acetone)]
    • Vorontsov A.V., Stoyanova I.V., Kozlov D.V., Simagina V.I., Savinov E.N. J. Catal. 2000, 189:360. Papers reporting activation energy of photocatalytic reactions in the period 2000-2004. Figures and compounds in square brackets and parentheses, respectively, show activation energy in the unit of kJ mol-1 and substrate. (a), [10.9 (acetone)].
    • (2000) J. Catal. , vol.189 , pp. 360
    • Vorontsov, A.V.1    Stoyanova, I.V.2    Kozlov, D.V.3    Simagina, V.I.4    Savinov, E.N.5
  • 7
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    • [17.1 (1,3-dihydroxy-5-methoxybenzene)]
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  • 21
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    • " Honda-Fujishima effect" is a well-known chemical phenomenon closely related to photocatalysis and the paper published in Nature in 1972 had undoubtedly promoted research activity of photocatalysis but not an origin of heterogeneous photocatalysis in the bibliographic sense (Ref. 3(a))
    • Fujishima A., Honda K. Nature 1972, 238:37. " Honda-Fujishima effect" is a well-known chemical phenomenon closely related to photocatalysis and the paper published in Nature in 1972 had undoubtedly promoted research activity of photocatalysis but not an origin of heterogeneous photocatalysis in the bibliographic sense (Ref. 3(a)).
    • (1972) Nature , vol.238 , pp. 37
    • Fujishima, A.1    Honda, K.2
  • 27
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    • A probable first report on photocatalytic liberation of hydroxyl radical Jaeger, C. D.; Bard, A. J
    • Jaeger C.D., Bard A.J. A probable first report on photocatalytic liberation of hydroxyl radical Jaeger, C. D.; Bard, A. J. J. Phys. Chem. 1979, 83:3146.
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    • Jaeger, C.D.1    Bard, A.J.2
  • 28
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    • Recent papers on photocatalytic production of hydroxyl radical: (a)
    • Hirakawa T., Nosaka Y. Langmuir 2002, 18:3247. Recent papers on photocatalytic production of hydroxyl radical: (a).
    • (2002) Langmuir , vol.18 , pp. 3247
    • Hirakawa, T.1    Nosaka, Y.2
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    • An example of papers showing the coincidence of equilibrium adsorption constants obtained from the photocatalytic reaction rate and adsorption in the dark, see:
    • Amano F., Nogami K., Ohtani B. Langmuir 2010, 26:7174. An example of papers showing the coincidence of equilibrium adsorption constants obtained from the photocatalytic reaction rate and adsorption in the dark, see:.
    • (2010) Langmuir , vol.26 , pp. 7174
    • Amano, F.1    Nogami, K.2    Ohtani, B.3
  • 36
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    • Examples of papers reporting adsorption in the dark are as follows: (a)
    • Cunningham J., Sedlak P. J. Photochem. Photobiol. A: Chem. 1994, 77:255. Examples of papers reporting adsorption in the dark are as follows: (a).
    • (1994) J. Photochem. Photobiol. A: Chem. , vol.77 , pp. 255
    • Cunningham, J.1    Sedlak, P.2
  • 44
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    • This stoichiometry was clarified for the first time by the author's group and reported as, Before submission to this journal, we submitted a part of the experimental results to Chemistry Letters as the first paper in the author's career in the field of photocatalysis, but the paper was rejected presumably due to a reviewer's comment that the co
    • Nishimoto S.-i., Ohtani B., Kajiwara H., Kagiya T. J. Chem. Soc., Faraday Trans. 1 1983, 79:2685. This stoichiometry was clarified for the first time by the author's group and reported as, Before submission to this journal, we submitted a part of the experimental results to Chemistry Letters as the first paper in the author's career in the field of photocatalysis, but the paper was rejected presumably due to a reviewer's comment that the content had been reported in a Russian journal without showing bibliographic data (We could not find this.). To submit the results as a full paper, additional experiments were carried out to support the stoichiometry. For example, an oxygen-isotope experiment was performed and showed the origin of molecular oxygen to be water. As a result, we were able to have the paper published, and it has been cited more than 100 times, including recent citations. This is an example of rejection of a submitted paper not always being disadvantageous for the authors.
    • (1983) J. Chem. Soc., Faraday Trans. 1 , vol.79 , pp. 2685
    • Nishimoto, S.-I.1    Ohtani, B.2    Kajiwara, H.3    Kagiya, T.4
  • 45
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    • Fifteen years before the publication of this paper, Sato had reported the nitrogen incorporation in titania lattice, but he reported this to be " NOx doping"
    • Asahi R., Morikawa T., Ohwaki T., Aoki K., Taga Y. Science 2001, 293:269. Fifteen years before the publication of this paper, Sato had reported the nitrogen incorporation in titania lattice, but he reported this to be " NOx doping" .
    • (2001) Science , vol.293 , pp. 269
    • Asahi, R.1    Morikawa, T.2    Ohwaki, T.3    Aoki, K.4    Taga, Y.5
  • 51
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    • This paper claimed inappropriate use of organic dyes as test compounds for visible light-sensitive photocatalysts. Citation of this paper was not expected at all, since the authors using methylene blue (MB) as a model compound for photocatalytic reaction never want to refer to this and, on the other hand, those who do not use MB need not to refer to this. However, there has been an appreciable num
    • Yan X., Ohno T., Nishijima K., Abe R., Ohtani B. Chem. Phys. Lett. 2006, 429:606. This paper claimed inappropriate use of organic dyes as test compounds for visible light-sensitive photocatalysts. Citation of this paper was not expected at all, since the authors using methylene blue (MB) as a model compound for photocatalytic reaction never want to refer to this and, on the other hand, those who do not use MB need not to refer to this. However, there has been an appreciable number of citations and, to the author's surprise, approximately half of the citations of this paper were for reasonable use of MB, indicating that authors of those papers did not read the paper.
    • (2006) Chem. Phys. Lett. , vol.429 , pp. 606
    • Yan, X.1    Ohno, T.2    Nishijima, K.3    Abe, R.4    Ohtani, B.5
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    • Watanabe et al. have reported similar action spectrum analysis of photoinduced degradation of Rhodamine B with a cadmium sulfide suspension and pointed out a similar dye-sensitization mechanism:
    • Watanabe T., Takizawa T., Honda K. J. Phys. Chem. 1977, 81:1845. Watanabe et al. have reported similar action spectrum analysis of photoinduced degradation of Rhodamine B with a cadmium sulfide suspension and pointed out a similar dye-sensitization mechanism:.
    • (1977) J. Phys. Chem. , vol.81 , pp. 1845
    • Watanabe, T.1    Takizawa, T.2    Honda, K.3
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    • Photocatalytic reaction of MB in aerated titania suspensions was reported in 1937 by a Japanese photochemist:, (in Japanese). As far as the author knows, this is the first report on titania photocatalysis
    • Horio M. Nihon Gakujutsu Kyokai Hokoku 1937, 12:204. Photocatalytic reaction of MB in aerated titania suspensions was reported in 1937 by a Japanese photochemist:, (in Japanese). As far as the author knows, this is the first report on titania photocatalysis.
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    • Horio, M.1
  • 55
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    • When organic dyes themselves are a pollutant to be decomposed, visible light-induced, but not photocatalytic, reaction can be a useful technique, e.g.
    • Chen X., Zheng Z., Ke X., Jaatinen E., Xie T., Wang D., Guo C., Zhao J., Zhu H. Green Chem. 2010, 12:414. When organic dyes themselves are a pollutant to be decomposed, visible light-induced, but not photocatalytic, reaction can be a useful technique, e.g.,.
    • (2010) Green Chem. , vol.12 , pp. 414
    • Chen, X.1    Zheng, Z.2    Ke, X.3    Jaatinen, E.4    Xie, T.5    Wang, D.6    Guo, C.7    Zhao, J.8    Zhu, H.9
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    • This paper showed that the rate of photocatalytic reaction in the presence of molecular oxygen, i.e., photocatalytic oxidative decomposition, may strongly depend on the intensity of light irradiation, while the rate of reaction in the absence of oxygen seems to be almost independent of light intensity
    • Torimoto T., Aburakawa Y., Kawahara Y., Ikeda S., Ohtani B. Chem. Phys. Lett. 2004, 392:220. This paper showed that the rate of photocatalytic reaction in the presence of molecular oxygen, i.e., photocatalytic oxidative decomposition, may strongly depend on the intensity of light irradiation, while the rate of reaction in the absence of oxygen seems to be almost independent of light intensity.
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    • Some exceptions have been reported, e.g., bismuth tungstate (Bi2WO6) shows a relatively high level of photocatalytic activity for oxidative decomposition of acetaldehyde in air: (a)
    • Amano F., Nogami K., Ohtani B. J. Phys. Chem. C 2009, 113:1536. Some exceptions have been reported, e.g., bismuth tungstate (Bi2WO6) shows a relatively high level of photocatalytic activity for oxidative decomposition of acetaldehyde in air: (a).
    • (2009) J. Phys. Chem. C , vol.113 , pp. 1536
    • Amano, F.1    Nogami, K.2    Ohtani, B.3
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    • A recent review on nanostructured titania photocatalysts:
    • Chen X., Mao S.S. Chem. Rev. 2007, 107:2891. A recent review on nanostructured titania photocatalysts:.
    • (2007) Chem. Rev. , vol.107 , pp. 2891
    • Chen, X.1    Mao, S.S.2
  • 64
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    • Examples of papers discussing the property-activity correlation are: (a)
    • Enríquez R., Agriosa A.G., Pichat P. Catal. Today 2007, 120:196. Examples of papers discussing the property-activity correlation are: (a).
    • (2007) Catal. Today , vol.120 , pp. 196
    • Enríquez, R.1    Agriosa, A.G.2    Pichat, P.3
  • 70
    • 0038390143 scopus 로고    scopus 로고
    • It was suggested that transfer of photoexcited electrons and positive holes between interconnecting anatase and rutile particles may enhance charge separation and hence improve the efficiency of utilization of electron-hole pairs:
    • Hurum D.C., Agrios A.G., Gray K.A., Rajh T., Thurnauer C. J. Phys. Chem. B 2003, 107:4545. It was suggested that transfer of photoexcited electrons and positive holes between interconnecting anatase and rutile particles may enhance charge separation and hence improve the efficiency of utilization of electron-hole pairs:.
    • (2003) J. Phys. Chem. B , vol.107 , pp. 4545
    • Hurum, D.C.1    Agrios, A.G.2    Gray, K.A.3    Rajh, T.4    Thurnauer, C.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.