Bi-acylation of cellulose: Determining the relative reactivities of the acetyl and fatty-acyl moieties

Cellulose

Volumn 18, Issue 4, 2011, Pages 1015-1021

  Peydecastaing, J ^a   Vaca Garcia, C ^a   Borredon, E ^a  

^a UNIVERSITÉ DE TOULOUSE   (France)

Author keywords

Acetic fatty esters; Mixed anhydrides; Mixed cellulose esters

Indexed keywords

ACETIC ANHYDRIDES; ACETIC-FATTY ESTERS; ACYL ESTERS; ACYL GROUP; ALIPHATIC CHAINS; DEGREE OF SUBSTITUTION; MIXED ANHYDRIDES; MIXED CELLULOSE ESTERS; RELATIVE REACTIVITIES;

ACETIC ACID; CELLULOSE; ESTERIFICATION;

ESTERS;

EID: 79960031906     PISSN: 09690239     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10570-011-9528-9     Document Type: Article

References (9)

1. Chemeris MM, Musko NP et al (2003). Synthesis of cellulose esters in a trifluoroacetic acid medium. Efiry Tsellyulozy i Krakhmala: Sintez, Svoistva, Primenenie, Materialy Yubileinoi Vserossiiskoi Nauchno-Tekhnicheskoi Konferentsii s Mezhdunarodnym Uchastiem, 10th, Suzdal, Russian Federation, 5-8 May 2003, pp 108-115.
2. Malm CJ, Hiatt GD (1939) Mixed organic acid esters of cellulose such as mixed cellulose acetate-oleate, -linoleate or -stearate suitable for precipitation and washing with water. Eastman Kodak Co, USA. US Patent 2, 172, 250.
3. Matsuzaki K, Miyata T (1967) Synthesis of mixed cellulose esters of a, b-unsaturated carboxylic and acetic acids and their utilization II. Reaction of mixtures of a, b-unsaturated carboxylic acid and acetic anhydride with cellulose. Kogyo Kagaku Zasshi 70: 770-774.
4. Peydecastaing J, Vaca-Garcia C et al (2008) Quantitative analysis of mixtures of various linear anhydrides and carboxylic acids. Chromatographia 68: 685-688.
5. Peydecastaing J, Vaca-Garcia C et al (2009a) Accurate determination of the degree of substitution of long chain cellulose esters. Cellulose 16(2): 289-297.
6. Peydecastaing J, Vaca-Garcia C et al (2009b) Consecutive reactions in an oleic acid and acetic anhydride reaction medium. Eur J Lipid Sci Technol 111: 723-729.
7. Vaca-Garcia C, Borredon ME (1999) Solvent-free fatty acylation of cellulose and lignocellulosic wastes. Part 2. Reactions with fatty acids. Bioresour Technol 70(2): 135-142.
8. Vaca-Garcia C, Thiebaud S et al (1998) Cellulose esterification with fatty acids and acetic anhydride in lithium chloride/N, N-dimethylacetamide medium. J Am Oil Chem Soc 75: 315-319.
9. Yang B, Montgomery R (2008) Preparation and physical properties of starch mixed esters. Starch 60: 146-158.