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Nitrosobenzenes are also known to form stable crystals composed of monomer molecules. These crystal structures are ordered such that the reactive nitroso groups have no other nitroso groups in immediate neighbourhood. For p-iodonitrosobenzene see:
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V. imunić-Menarić E. Metrović V. Tomiić M. gela D. Vikić-Topić H. iak P. Novak H. Vanik Croat. Chem. Acta 2005 78 511
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Vanik, H.8
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41
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0000812971
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and for p-methoxynitrosobenzene see:
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D. A. Fletcher B. G. Gowenlock K. G. Orrell V. ik D. E. Hibbs M. B. Hursthouse K. M. A. Malik J. Chem. Soc., Perkin Trans. 2 (1972-1999) 1996 191
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45
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0041837397
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Authorhouse, No dissolution of the sample in glycerol could be visually observed even after a few weeks of standing. Also, glycerol does not wet the nitrosobenzene monomer crystals. Glycerol is a highly viscous liquid and even if monomer molecules detach from the surface, they will diffuse extremely slowly. If paraffin oil is used instead, the monomer crystals start dissolving and the sample is turned white in only few minutes Analogy between solid-state reactions and transformations can be expected because a solid-state transformation can be considered as the simplest solid-state reaction where the reactant and product molecules are the same Molecular motion, even on the nanometre scale, on the crystal surfaces during some photochemical reactions was found by AFM.
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Y. Mnyukh, Fundamentals of Solid State Phase Transformations, Ferromagnetism and Ferroelectricity, Authorhouse, 2001
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Fundamentals of Solid State Phase Transformations, Ferromagnetism and Ferroelectricity
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Mnyukh, Y.1
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