Diastereomer ratio of products as a mechanistic probe in epimerization and ligand exchange of chiral-at-metal [CpFe(Prophos)NCMe]X (X = I, PF6)

Organometallics

Volumn 30, Issue 13, 2011, Pages 3666-3676

  Brunner, Henri ^a   Ike, Hayato ^b   Muschiol, Manfred ^a   Tsuno, Takashi ^b   Koyama, Kazuhiro ^b   Kurosawa, Takaki ^b   Zabel, Manfred ^a  

^a UNIVERSITY OF REGENSBURG   (Germany)

^b NIHON UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BIMOLECULAR REACTION; CHELATE RING; CONE ANGLE; CONFIGURATIONALLY; COORDINATION SITES; COUPLING CONSTANTS; DIASTEREOMERIC RATIOS; DIASTEREOMERS; ENERGY DIAGRAM; EPIMERIZATION; EXCHANGE REACTION; FIRST ORDER REACTIONS; HALF LIVES; HEXAFLUOROPHOSPHATES; LIGAND EXCHANGES; MECHANISTIC PROBES; METAL ATOMS; NEW CORRELATIONS; PHOSPHITE LIGANDS; UNIMOLECULAR;

ACETONITRILE; PHOSPHORUS COMPOUNDS; REACTION INTERMEDIATES;

LIGANDS;

EID: 79959952650     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om2003893     Document Type: Article

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