C1-symmetric Rh/Phebox-catalyzed asymmetric alkynylation of α-ketoesters

Angewandte Chemie - International Edition

Volumn 50, Issue 28, 2011, Pages 6296-6300

  Ohshima, Takashi ^a   Kawabata, Takahito ^b   Takeuchi, Yosuke ^b   Kakinuma, Takahiro ^b   Iwasaki, Takanori ^b   Yonezawa, Takayuki ^b   Murakami, Hajime ^b   Nishiyama, Hisao ^c   Mashima, Kazushi ^b  

^a KYUSHU UNIVERSITY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

^c NAGOYA UNIVERSITY   (Japan)

Author keywords

alkynylation; asymmetric catalysis; chemoselectivity; ketones; rhodium

Indexed keywords

ALKYNYLATIONS; ASYMMETRIC CATALYSIS; CHEMO-SELECTIVITY; KETOESTER; PROPARGYLIC ALCOHOLS; TERMINAL ALKYNE; TRIMETHYLSILYL;

ACETYLENE; ALCOHOLS; CATALYSIS; KETONES; RHODIUM;

ALKYLATION;

ALKYNE; COORDINATION COMPOUND; ESTER; KETONE; OXOACID; RHODIUM;

ARTICLE; CATALYSIS; CHEMISTRY;

ALKYNES; CATALYSIS; COORDINATION COMPLEXES; ESTERS; KETO ACIDS; KETONES; RHODIUM;

EID: 79959949398     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201100252     Document Type: Article

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