Synthesis of biosurfactants: Enzymatic esterification of diglycerol and oleic acid. 1. kinetic modeling

Industrial and Engineering Chemistry Research

Volumn 50, Issue 11, 2011, Pages 6609-6614

  Martínez, Mercedes ^a   Oliveros, Rubén ^a   Aracil, José ^a  

^a UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

BIO-SURFACTANTS; CATALYST CONCENTRATION; ENVIRONMENTALLY FRIENDLY PRODUCTS; ENZYMATIC ESTERIFICATION; EXPERIMENTAL DATA; FATTY ACID ESTERS; KINETIC MODELING; KINETIC MODELS; LANGMUIR ADSORPTION; MOLAR RATIO; POLYGLYCEROLS; PSEUDO-SECOND-ORDER KINETIC MODELS; WIDE FIELD;

ADSORPTION; CATALYSTS; ESTERIFICATION; ESTERS; KINETIC THEORY; NONIONIC SURFACTANTS; OLEIC ACID; UNSATURATED FATTY ACIDS;

KINETICS;

EID: 79959926058     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie102560b     Document Type: Article

References (13)

1. Sanchez, N.; Martínez, N.; Aracil, J. Selective esterification of glycerine to 1-glycerol monooleate. 1. kinetic modelling. Ind. Eng. Chem. Res. 1997, 36, 1524.
2. Vicente, G.; Martínez y, M.; Aracil, J. Esteres Metílicos de Girasol: Alternativa al combustible Diesel Mineral. Ing. Quím. 1999, 153.
3. Akgül, M.; Karabakan, A. Selective synthesis of monoolein with clinoptilolite. Microporous Mesoporous Mater. 2010, 131, 238.
4. Mouloungui, Z.; Rakotondrazafy, V.; Valentin, R.; Bachar, Z. Synthesis of glycerol 1-monooleate by condensation of oleic acid with glycidol catalyzed by anion-exchange resin in aqueous organic polymorphic system. Ind. Eng. Chem. Res. 2009, 48, 6949.
5. Mukesh, D.; Jadhav, S.; Sheth, D.; Banerji, A. A.; Thakkar, K.; Bevinakatti, H. S. Lipase-catalyzed esterification reactions. J. Chem. Technol. Biotechnol. 1997, 69, 179.
6. Kiriamiti, H. K.; Rascol, E.; Marty, A.; Condoret, J. S. Extraction rates of oil from high oleic sunflower seeds with supercritical carbon dioxide. Chem. Eng. Process. 2001, 41, 711.
7. Charlemagne, D.; Legoy, M. D. Enzymatic synthesis of polyglycerol- fatty acid esters in a solvent-free system. J. Am. Oil Chem. Soc. 1995, 72, 61.
8. Babayan, V. K.; McIntyre, R. T. Preparation and properties of some polyglycerol esters of short and medium chain length fatty acids. J. Am. Oil Chem. Soc. 1968, 48, 307.
9. García, E.; Ferrari, F.; García, T.; Martínez, M.; Aracil, J. A comparative study of the enzymatic esterification of diglycerol with fatty acids; 8th Mediterranean Congress of Chemical Engineering, Barcelona, Spain, 1999.
10. García, T.; Coteron, A.; Martínez, M.; Aracil, J. Esterification reactions catalyzed by immobilized lipases. Chem. Eng. Sci. 1996, 51, 2841.
11. Sanchez, N.; Coteron, A.; Martinez, M.; Aracil, J. Kineticanalysis and modelling of the esterification of oleic-acid and oleyl alcohol using cobalt chloride as catalyst. Ind. Eng. Chem. Res. 1992, 31, 1985.
12. Sanchez, N.; Martinez, M.; Aracil, J. Synthesis of oleyl oleate as a jojoba oil analog. J. Am. Oil Chem. Soc. 1992, 69, 1150.
13. Novo Nordisk Netherlands. "Novozym 435". Novo Enzymes Technical Report Novo Industri A/S. Novo Alle (Denmark), 1995.