Kinetics behavior of esterification of acetic acid with methanol over Amberlyst 36

Chemical Engineering Journal

Volumn 171, Issue 3, 2011, Pages 1367-1372

  Tsai, Yu Ting ^a   Lin, Ho mu ^a   Lee, Ming Jer ^a  

^a NATIONAL TAIWAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Taiwan)

Author keywords

Acetic acid; Amberlyst 36; Esterification; Kinetics; Methanol

Indexed keywords

ADSORPTION STRENGTH; AMBERLYST; BINARY ADSORPTION; CATION EXCHANGE RESINS; EQUILIBRIUM CONVERSION; EXPERIMENTAL CONDITIONS; FEED STREAMS; HEAT EFFECT; KINETIC BEHAVIOR; KINETIC DATA; KINETIC EXPERIMENT; METHYL ACETATES; MOLAR RATIO; PACKED BED REACTOR; REACTING SPECIES; REACTION TEMPERATURE;

ADSORPTION; ESTERIFICATION; ESTERS; EXPERIMENTS; KINETICS; METHANOL; PACKED BEDS; PH; REACTION RATES;

ACETIC ACID;

EID: 79959920260     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2011.05.049     Document Type: Article

References (22)

1. Tang Y.T., Chen Y.W., Huang H.P., Yu C.C., Hung S.B., Lee M.J. Design of reactive distillations for acetic acid esterification with different alcohols. AIChE J. 2005, 51:1683-1699.
2. Hung W.J., Lai I.K., Chen Y.W., Hung S.B., Huang H.P., Lee M.J., Yu C.C. Process chemistry and design alternatives for converting dilute acetic acid to esters in reactive distillation. Ind. Eng. Chem. Res. 2006, 45:1722-1733.
3. Hung S.B., Lee M.J., Tang Y.T., Chen Y.W., Lai I.K., Hung W.J., Huang H.P., Yu C.C. Control of different reactive distillation configurations. AIChE J. 2006, 52:1423-1440.
4. Lai I.K., Hung S.B., Hung W.J., Yu C.C., Lee M.J., Huang H.P. Design and control of reactive distillation for ethyl and isopropyl acetates production with azeotropic feeds. Chem. Eng. Sci. 2007, 62:878-898.
5. Hung S.B., Lai I.K., Huang H.P., Lee M.J., Yu C.C. Reactive distillation for two-stage reaction systems: adipic acid and glutaric acid esterifications. Ind. Eng. Chem. Res. 2008, 47:3076-3087.
6. Lai I.K., Liu Y.C., Yu C.C., Lee M.J., Huang H.P. Production of high-purity ethyl acetate using reactive distillation: experimental and start-up procedure. Chem. Eng. Process. 2008, 47:1831-1843.
7. Hung S.B., Chen J.H., Lin Y.D., Huang H.P., Lee M.J., Ward J.D., Yu C.C. Control of plantwide reactive distillation processes: hydrolysis, transesterification and two-stage esterification. J. Taiwan Inst. Chem. Eng. 2010, 41:382-402.
8. Xu Z.P., Chuang K.T. Kinetics of acetic acid esterification over ion exchange catalyst. Can. J. Chem. Eng. 1996, 74:493-500.
9. Song W., Venimadhavan G., Manning J.M., Malone M.F., Doherty M.F. Measurement of residue curve maps and heterogeneous kinetics in methyl propionate synthesis. Ind. Eng. Chem. Res. 1998, 37:1917-1928.
10. Pöpken T., Götze L., Gmehling J. Reaction kinetics and chemical equilibrium of homogeneously and heterogeneously catalyzed acetic acid esterification with methanol and methyl acetate hydrolysis. Ind. Eng. Chem. Res. 2000, 39:2601-2611.
11. Kirbaslar S.I., Terzioglu H.Z., Dramur U. Catalytic esterification of methyl alcohol with acetic acid. Chin. J. Chem. Eng. 2001, 9:90-96.
12. Lilja J., Aumo J., Salmi T., Murzin D.Yu., Mäki-Arvela P., Sundell M., Ekman K., Peltonen R., Vainio H. Kinetics of esterification of propanoic acid with methanol over a fibrous polymer-supported sulphonic acid catalyst. Appl. Catal. A: Gen. 2002, 228:253-267.
13. Liu Y., Lotero E., Goodwin J.G. A Comparison of the esterification of acetic acid with methanol using heterogeneous acid catalysis. J. Catal. 2006, 242:278-286.
14. Ali S.H. Kinetics of catalytic esterification of propionic acid with different alcohols over Amberlyst 15. Int. J. Chem. Kinet. 2009, 41:432-448.
15. Tsai Y.T., Lin H.M., Lee M.J. Kinetics of catalytic esterification of propionic acid with methanol over Amberlyst 36. Ind. Eng. Chem. Res. 2011, 50:1171-1176.
16. Renon H., Prausnitz J.M. Local compositions in thermodynamic excess function for liquid mixtures. AIChE J. 1968, 14:135-144.
17. Lee M.J., Wu H.T., Kang C.H., Lin H.M. Kinetic behavior of amyl propionate synthesis catalyzed by acidic cation exchange resin. J. Chin. Inst. Chem. Eng. 1999, 30:117-122.
18. Kipling J.J. Adsorption from Solutions of Non-Electrolytes 1965, Academic Press, New York.
19. Bernatova S., Aim K., Wichterle I. Isothermal vapour-liquid equilibrium with chemical reaction in the quaternary water+methanol+acetic acid+methyl acetate system, and in five binary subsystems. Fluid Phase Equilib. 2006, 247:96-101.
20. Gmehling J., Onken U. Vapor-Liquid Equilibrium Data Collection. Chemistry Data Series, Part 1 1979, vol. 1. DECHEMA, Frankfurt, Germany, p. 116.
21. Blanco A.M., Ortega J. Isobaric vapor-liquid equilibria of methanol+methyl ethanoate+methyl propanoate, and +methyl butanoate at 141.3kPa. J. Chem. Eng. Data 1996, 41:566-570.
22. Gmehling J., Onken U. Vapor-Liquid Equilibrium Data Collection. Chemistry Data Series, Part 1 1979, vol. 1. DECHEMA, Frankfurt, Germany, p. 60.