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Volumn 133, Issue 26, 2011, Pages 9984-9987

Stepwise synthesis of metal - Organic frameworks: Replacement of structural organic linkers

Author keywords

[No Author keywords available]

Indexed keywords

3D TRANSFORMATIONS; LATERAL MOVEMENT; ORGANIC LINKERS; PADDLE WHEELS; STEPWISE SYNTHESIS; SYNTHETIC METHODS; TEMPLATING EFFECTS; TRANSFORMATION METHODS;

EID: 79959906535     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja201911v     Document Type: Article
Times cited : (290)

References (47)
  • 15
    • 79959867145 scopus 로고    scopus 로고
    • In contrast, discrete molecules and organometallic species have been manipulated for decades by organic and inorganic chemists via step-by-step synthetic strategies.
    • In contrast, discrete molecules and organometallic species have been manipulated for decades by organic and inorganic chemists via step-by-step synthetic strategies.
  • 18
    • 65349143171 scopus 로고    scopus 로고
    • For reviews of postsynthetic modification, see
    • For reviews of postsynthetic modification, see: Wang, Z.; Cohen, S. M. Chem. Soc. Rev. 2009, 38, 1315
    • (2009) Chem. Soc. Rev. , vol.38 , pp. 1315
    • Wang, Z.1    Cohen, S.M.2
  • 35
    • 79959861240 scopus 로고    scopus 로고
    • The binding energies for Zn - N and Zn - O were estimated to be 150 and 360 kJ/mol, respectively (see ref 1a).
    • The binding energies for Zn - N and Zn - O were estimated to be 150 and 360 kJ/mol, respectively (see ref 1a).
  • 36
    • 79959887003 scopus 로고    scopus 로고
    • For crystallographic data for PPF-27, see the SI.
    • For crystallographic data for PPF-27, see the SI.
  • 42
    • 79959910133 scopus 로고    scopus 로고
    • Lateral movement of a paddlewheel framework was previously observed by Kitagawa and co-workers. (12)
    • Lateral movement of a paddlewheel framework was previously observed by Kitagawa and co-workers. (12)
  • 43
    • 33748795337 scopus 로고    scopus 로고
    • - anions in the remaining layers (see:) This report, however, provided only PXRD data to support their discussion. The use of MOFs has enabled us to report single-crystal information on this phenomenon. Herein we have reported transformations in which a longer linker is replaced with a shorter linker, resulting in a contraction between layers. Interestingly, O'Hare's report indicates that similar transformations involving replacement of a shorter linker with a longer linker could happen, as seen from the replacement of the shorter succinate and tartrate anions with the longer adipate anion.
    • - anions in the remaining layers (see: Feng, Y. J.; Williams, G. R.; Lerous, F.; Taviot-Gueho, C.; O'Hare, D. Chem. Mater. 2006, 18, 4312) This report, however, provided only PXRD data to support their discussion. The use of MOFs has enabled us to report single-crystal information on this phenomenon. Herein we have reported transformations in which a longer linker is replaced with a shorter linker, resulting in a contraction between layers. Interestingly, O'Hare's report indicates that similar transformations involving replacement of a shorter linker with a longer linker could happen, as seen from the replacement of the shorter succinate and tartrate anions with the longer adipate anion.
    • (2006) Chem. Mater. , vol.18 , pp. 4312
    • Feng, Y.J.1    Williams, G.R.2    Lerous, F.3    Taviot-Gueho, C.4    O'Hare, D.5
  • 44
    • 33644787213 scopus 로고    scopus 로고
    • Porosity is conventionally defined by two parameters: demonstration of permeability and retention of structure upon guest removal/exchange (see:) The observation of pillar molecules moving into solution during the transformation indicates the permeability of the structure, similar to reports in which porosity was proved by inclusion of dye molecules into the crystal, as demonstrated by Lin (see:; J. Am. Chem. Soc. 2008, 13834) The 2D square-grid layers retained their structure during the transformation, as exemplified by the templating effect. Had the structure fully dissolved and recrystallized, contamination by either 2D or 3D species would be evident in the PXRD pattern.
    • Porosity is conventionally defined by two parameters: demonstration of permeability and retention of structure upon guest removal/exchange (see: Barbour, L. J. Chem. Commun. 2006, 1163) The observation of pillar molecules moving into solution during the transformation indicates the permeability of the structure, similar to reports in which porosity was proved by inclusion of dye molecules into the crystal, as demonstrated by Lin (see: Ma, L.; Lin, W. J. Am. Chem. Soc. 2008, 130, 13834) The 2D square-grid layers retained their structure during the transformation, as exemplified by the templating effect. Had the structure fully dissolved and recrystallized, contamination by either 2D or 3D species would be evident in the PXRD pattern.
    • (2006) Chem. Commun. , vol.130 , pp. 1163
    • Barbour, L.J.1    Ma, L.2    Lin, W.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.