Formation of p-cymene from OH + γ-terpinene: H-atom abstraction from the cyclohexadiene ring structure

Atmospheric Environment

Volumn 45, Issue 26, 2011, Pages 4408-4411

  Aschmann, Sara M ^a   Arey, Janet ^a   Atkinson, Roger ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Terpinene; H atom abstraction; OH radical; P Cymene

Indexed keywords

1 ,4-CYCLOHEXADIENES; CYCLOHEXADIENES; H-ATOM ABSTRACTION; MONOTERPENES; OH RADICAL; P-CYMENE; PHELLANDRENE; RING STRUCTURES; TERPINENE;

ABSTRACTING; BENZENE; FREE RADICALS; RATE CONSTANTS;

ATOMS;

1,4 CYCLOHEXADIENE; ALPHA PHELLANDRENE; GAMMA TERPINENE [1 METHYL 4 (1 METHYLETHYL)] 1,4 CYCLOHEXADIENE; HYDROGEN; HYDROXIDE; PARA CYMENE; PARA CYMENE [1 METHYL 4 (1 METHYLETHYL)]BENZENE; TERPENE; TERPINENE; UNCLASSIFIED DRUG;

AROMATIC HYDROCARBON; HYDROXYL RADICAL; LITERATURE REVIEW; TERPENE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONTROLLED STUDY; PRIORITY JOURNAL; VEGETATION;

EID: 79959898636     PISSN: 13522310     EISSN: 18732844     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2011.05.044     Document Type: Article

References (19)

1. Aschmann S.M., Arey J., Atkinson R. OH radical formation from the gas-phase reactions of O3 with a series of terpenes. Atmospheric Environment 2002, 36:4347-4355.
2. Aschmann S.M., Arey J., Atkinson R. Kinetics and products of the reactions of OH radicals with 4,4-dimethyl-1-pentene and 3,3-dimethylbutanal at 296 ± 2 K. Journal of Physical Chemistry A 2010, 114:5810-5816.
3. Atkinson R., Arey J. Atmospheric degradation of volatile organic compounds. Chemical Reviews 2003, 103:4605-4638.
4. Atkinson R., Aschmann S.M., Winer A.M., Pitts J.N. Gas phase reaction of NO2 with alkenes and dialkenes. International Journal of Chemical Kinetics 1984, 16:697-706.
5. Atkinson R., Tuazon E.C., Carter W.P.L. Extent of H-atom abstraction from the reaction of the OH radical with 1-butene under atmospheric conditions. International Journal of Chemical Kinetics 1985, 17:725-734.
6. Atkinson R., Tuazon E.C., Aschmann S.M. Products of the gas-phase reaction of the OH radical with 3-methyl-1-butene in the presence of NO. International Journal of Chemical Kinetics 1998, 30:577-587.
7. Atkinson R., Baulch D.L., Cox R.A., Crowley J.N., Hampson R.F., Hynes R.G., Jenkin M.E., Rossi M.J., Troe J. Evaluated kinetic and photochemical data for atmospheric chemistry: volume II - gas phase reactions of organic species. Atmospheric Chemistry and Physics 2006, 6:3625-4055.
8. Calvert J.G., Atkinson R., Kerr J.A., Madronich S., Moortgat G.K., Wallington T.J., Yarwood G. The Mechanisms of Atmospheric Oxidation of the Alkenes 2000, Oxford University Press, New York.
9. Corchnoy S.B., Atkinson R. Kinetics of the gas-phase reactions of OH and NO3 radicals with 2-carene, 1,8-cineole, p-cymene, and terpinolene. Environmental Science and Technology 1990, 24:1497-1502.
10. Geron C., Rasmussen R., Arnts R.R., Guenther A. A review and synthesis of monoterpene speciation from forests in the United States. Atmospheric Environment 2000, 34:1761-1781.
11. Guenther A., Hewitt C.N., Erickson D., Fall R., Geron C., Graedel T., Harley P., Klinger L., Lerdau M., McKay W.A., Pierce T., Scholes B., Steinbrecher R., Tallamraju R., Taylor J., Zimmerman P. A global model of natural volatile organic compound emissions. Journal of Geophysical Research 1995, 100:8873-8892.
12. Jenkin M.E., Sulbaek Andersen M.P., Hurley M.D., Wallington T.J., Taketani F., Matsumi Y. A kinetics and mechanistic study of the OH and NO2 initiated oxidation of cyclohexa-1,3-diene in the gas phase. Physical Chemistry Chemical Physics 2005, 7:1194-1204.
13. Nishino N., Arey J., Atkinson R. Rate constants for the gas-phase reactions of OH radicals with a series of C6-C14 alkenes at 299 ± 2 K. Journal of Physical Chemistry A 2009, 113:852-857.
14. Ohta T. Reactivity of allylic hydrogens in cyclohexadiene towards OH radicals. International Journal of Chemical Kinetics 1984, 16:1495-1503.
15. Peeters J., Vandenberk S., Piessens E., Pultau V. H-Atom abstraction in reactions of cyclic polyalkenes with OH. Chemosphere 1999, 38:1189-1195.
16. Peeters J., Vereecken L., Vandenberk S. Experimental and theoretical studies of the oxidation of VOC: OH-initiated oxidation of alkenes and biogenics. EUROTRAC-2 Annual Report 1998, Chemical Mechanism Development 1999, 78-82. International Scientific Secretariat, GSF-Forschungszentrum für Umwelt und Gesundheit GmbH, München, Germany, September.
17. Taylor W.D., Allston T.D., Moscato M.J., Fazekas G.B., Kozlowski R., Takacs G.A. Atmospheric photodissociation lifetimes for nitromethane, methyl nitrite, and methyl nitrate. International Journal of Chemical Kinetics 1980, 12:231-240.
18. Tuazon E.C., Aschmann S.M., Nguyen M.V., Atkinson R. H-Atom abstraction from selected C-H bonds in 2,3-dimethylpentanal, 1,4-cyclohexadiene, and 1,3,5-cycloheptatriene. International Journal of Chemical Kinetics 2003, 35:415-426.
19. Vereecken L., Peeters J. H-Atom abstraction by OH-radicals from (biogenic) (poly)alkenes: C-H bond strengths and abstraction rates. Chemical Physics Letters 2001, 333:162-168.