Kinetics of 1-pentanol etherification without water removal

Industrial and Engineering Chemistry Research

Volumn 50, Issue 13, 2011, Pages 7911-7919

  Bringué, Roger ^a   Ramírez, Eliana ^a   Fité, Carles ^a   Iborra, Montserrat ^a   Tejero, Javier ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

1-PENTANOL; ACTIVE CENTER; AMBERLYST; COMPETITIVE ADSORPTION; DI-N-PENTYL ETHER; EFFECT OF WATER; ER-MODELS; INHIBITOR EFFECTS; LANGMUIR-HINSHELWOOD-HOUGEN-WATSON; LIQUID PHASE DEHYDRATIONS; WATER REMOVAL;

ACTIVATION ENERGY; ADSORPTION; CATALYST ACTIVITY; ETHERS;

DEWATERING;

EID: 79959857976     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie1025776     Document Type: Article

References (39)

1. Cunill, F.; Vila, M.; Izquierdo, J. F.; Iborra, M.; Tejero, J. Effect of Water Presence on Methyl tert -Butyl Ether and Ethyl tert -Butyl Ether Liquid Phase Syntheses Ind. Eng. Chem. Res. 1993, 32, 564-569 (Pubitemid 23670530)
2. Cruz, V. J.; Bringueí, R.; Cunill, F.; Izquierdo, J. F.; Tejero, J.; Iborra, M.; Fiteí, C. Conversion, selectivity and kinetics of the liquid-phase dimerisation of isoamylenes in the presence of C1 to C5 alcohols catalysed by a macroporous ion-exchange resin J. Catal. 2006, 238, 330-341 (Pubitemid 43220576)
3. Honkela, M.; Krause, A. O. I. Kinetic modeling of the dimerization of isobutene Ind. Eng. Chem. Res. 2004, 43, 3251-3260 (Pubitemid 38781339)
4. Talwalkar, S.; Chauhan, M.; Aghalayam, P.; Qi, Z.; Sundmacher, K.; Mahajani, S. M. Kinetic studies on the dimerization of isobutene with ion-exchange resin in the presence of water as a selective enhancer Ind. Eng. Chem. Res. 2006, 45, 1312-1323 (Pubitemid 43342587)
5. Thotla, S.; Agarwal, V.; Mahajani, S. M. Aldol condensation of acetone with reactive distillation using water as a selectivity enhancer Ind. Eng. Chem. Res. 2007, 46, 8371-8379 (Pubitemid 350279717)
6. Jerabek, K.; Onoha, J.; Setinek, K. Kinetics of the synthesis of Bisphenol A Appl. Catal. 1988, 37, 129-138
7. Gates, B.; Rodriguez, W. General and specific acid catalysis in sulfonic acid resins J. Catal. 1973, 31, 27-31
8. Reinicker, R. A.; Gates, B. C. Bisphenol A Synthesis: kinetics of the phenol-acetone condensation reaction catalyzed by sulfonic acid reaction AIChE J. 1974, 20, 933-940
9. Teo, H. T. R.; Saha, B. Heterogeneous catalysed esterification of acetic acid with isoamylalcohol: kinetic studies J. Catal. 2004, 228, 174-182
10. Aiouache, F.; Goto, S. Sorption effect on kinetics of etherification of tert-amyl alcohol and ethanol Chem. Eng. Sci. 2003, 58, 2065-2077 (Pubitemid 36610890)
11. Aragon, J. M.; Vegas, J. M. R.; Jodra, L. G. Catalytic Behavior of Macroporous Resins in Catalytic Processes with water production. Activation and inhibition effects in the kinetics of the self-condensation of cyclohexanone Ind. Eng. Chem. Res. 1993, 32, 2555-2562
12. Lee, M. J.; Wu, H. T.; Lin, H. M. Kinetics of catalytic esterification of acetic acid and amyl alcohol over Dowex Ind. Eng. Chem. Res. 2000, 39, 4094-4099
13. Liu, W. T.; Tan, C. S. Liquid-phase esterification of propionic acid with n-butanol Ind. Eng. Chem. Res. 2001, 40, 3281-3286
14. Lee, M. J.; Chiu, J. Y.; Lin, H. M. Kinetics of catalytic esterification of propionic acid and n-butanol over Amberlyst 35 Ind. Eng. Chem. Res. 2002, 41, 2882-2887
15. Kawase, M.; Inoue, Y.; Araki, T.; Hashimoto, K. The simulated moving-bed reactor for production of bisphenol A Catal. Today 1999, 48, 199-209
16. Podrebarac, G. G.; Ng, F. T. T.; Rempel, G. L. A kinetic study of the aldol condensation of acetone using an anion exchange resin catalyst Chem. Eng. Sci. 1997, 52 (17) 2991-3002 (Pubitemid 27372379)
17. Yang, B. L.; Maeda, M.; Goto, S. Kinetics of Liquid Phase Synthesis of tert -Amyl Methyl Ether from tert -Amyl Alcohol and Methanol Catalyzed by Ion Exchange Resin Int. J. Chem. Kinet. 1998, 30 (2) 137-143 (Pubitemid 128552875)
18. Limbeck, U.; Altwicker, C.; Kunz, U.; Hoffmann, U. Rate Expression for THF synthesis on acidic ion exchange resin Chem. Eng. Sci. 2001, 56, 2171-2178
19. du Toit, E.; Nicol, W. The rate inhibiting effect of water as a product on reactions catalysed by cation exchange resins: formation of mesityl oxide from acetone as case study Appl. Catal., A 2004, 277, 219-225
20. Gates, B. C. Catalytic Chemistry; Wiley: New York, 1992; pp 182-253.
21. Chakrabarti, A.; Sharma, M. M. Cationic Exchange resins as catalysts React. Polym. 1993, 20 (1-2) 1-45
22. Hoek, I.; Nijhuis, T. A.; Stankiewicz, A. I.; Moulijn, J. A. Kinetics of solid acid catalyzed etherification of symmetrical primary alcohols: Zeolite BEA catalyzed etherification of 1-octanol Appl. Catal., A 2004, 266, 109-116
23. Aiouache, F.; Goto, S. Kinetic study on 2-methyl-1-butanol dehydration catalysed by ion exchange resin J. Chem. Eng. Jpn. 2002, 35, 436-442 (Pubitemid 34641755)
24. Sow, B.; Hamoudi, S.; Zahedi-Niaki, M. H.; Kaliaguine, S. 1-Butanol etherification over sulfonated mesostructured silica and organo-silica Microporous Mesoporous Mater. 2005, 79, 129-136
25. Castor Gonzaílez, J.; Fair, J. R. Preparation of tertiary amyl alcohol in a reactive distillation column. 1. Reaction kinetics, chemical equilibrium, and mass transfer issues Ind. Eng. Chem. Res. 1997, 36, 3833-3844
26. Tejero, J.; Cunill, F.; Iborra, M.; Izquierdo, J. F.; Fiteí, C. Dehydration of 1-pentanol to di-n-pentyl ether on ion-exchange resin catalysts J. Mol. Catal. A: Chem. 2002, 182-183, 541-554 (Pubitemid 34606107)
27. Bringueí, R.; Iborra, M.; Tejero, J.; Izquierdo, J. F.; Cunill, F.; Fite, C.; Cruz, V. J. Thermally stable ion-exchange resins as catalysts for the liquid-phase dehydration of 1-pentanol to di-n-pentyl ether (DNPE) J. Catal. 2006, 244, 33-42 (Pubitemid 44547932)
28. Bringueí, R.; Tejero, J.; Iborra, M.; Izquierdo, J. F.; Fiteí, C.; Cunill, F. Experimental Study of Chemical Equilibria in the Liquid-Phase Dehydration of 1-Pentanol to di-n-pentyl ether Ind. Eng. Chem. Res. 2007, 46, 6865-6872 (Pubitemid 350013732)
29. Bringueí, R.; Tejero, J.; Iborra, M.; Izquierdo, J. F.; Fiteí, C.; Cunill, F. Water effect on the kinetics of 1-pentanol dehydration to di-n-pentyl ether (DNPE) on Amberlyst 70 Top. Catal. 2007, 45 (1-4) 181-186
30. Medina, E. Study of 1-hexanol dehydration to DNHE over A70. MS Chemical Engineering Thesis. University of Barcelona, 2007.
31. Wittig, R.; Lohmann, J.; Gmehling, J. Vapor-Liquid Equilibria by UNIFAC Group Contribution. 6. Revision and Extension Ind. Eng. Chem. Res. 2003, 42, 183-188 (Pubitemid 36055388)
32. Tejero, J.; Cunill, F.; Izquierdo, J. F. Vapor-Phase Addition of Methanol to Isobutene on a Macroporous Resin. A Kinetic Study Ind. Eng. Chem. Res. 1989, 28, 1269-1277
33. Iborra, M.; Izquierdo, J. F.; Cunill, F.; Tejero, J. Application of the Response Surface Methodology to the Kinetic Study of the Gas-Phase Addition of Ethanol to Isobutene on a Sulfonated Styrene-Divinylbenzene Resin Ind. Eng. Chem. Res. 1992, 31, 1840-1848 (Pubitemid 23567623)
34. Cunill, F.; Tejero, J.; Fiteí, C.; Iborra, M.; Izquierdo, J. F. Conversion, Selectivity, and Kinetics of the Dehydration of 1-Pentanol to di-n-Pentyl ether Catalyzed by a Microporous Ion-Exchange Resin Ind. Eng. Chem. Res. 2005, 44, 318-324
35. Tejero, J.; Cunill, F.; Iborra, M.; Izquierdo, J. F.; Fiteí, C.; Bringueí, R. Liquid-phase dehydration of 1-pentanol to di-n-pentyl ether (DNPE) over medium and large pore acidic zeolites Microporous Mesoporous Mater. 2009, 117 (3) 650-660
36. Iborra, M.; Tejero, J.; Cunill, F.; Izquierdo, J. F.; Fiteí, C. Drying of Acidic Macroporous Styrene-Divinylbenzene Resins with 12-20% Crosslinking Degree Ind. Eng. Chem. Res. 2000, 39 (5) 1416-1422 (Pubitemid 30265975)
37. Ancillotti, F.; Massi Mauri, M.; Pescarollo, E. Ion exchange-resin catalysed addition of alcohol to olefins J. Catal. 1977, 46, 49-57
38. Caceci, M. S. Estimating error limits in parametric curve fitting Anal. Chem. 1989, 61, 2324-2327
39. Adamson, A. W. Physical Chemistry of Surface, 5th ed.; Wiley: New York, 1990; pp 421-426.