Chain-length-dependent termination in radical polymerization of acrylates

Macromolecular Chemistry and Physics

Volumn 212, Issue 13, 2011, Pages 1366-1378

  Barth, Johannes ^a   Buback, Michael ^a   Russell, Gregory T ^b   Smolne, Sebastian ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

^b UNIVERSITY OF CANTERBURY   (New Zealand)

Author keywords

acrylates; ESR EPR; kinetics (polym.); radical polymerization; termination

Indexed keywords

ACRYLATES; ALKYL ACRYLATES; CHAIN-LENGTH-DEPENDENT TERMINATIONS; ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY; ESR/EPR; KINETICS (POLYM.); LONG CHAINS; LOW TEMPERATURES; METHYL ACRYLATES; MID-CHAIN RADICALS; N-BUTYL ACRYLATE; PARAMETER VALUES; PHYSICAL MEANINGS; RATE COEFFICIENTS; REASONABLE VALUE; SHORT CHAIN LENGTHS; SINGLE-PULSE PULSED-LASER POLYMERIZATIONS; STOKES EINSTEIN EQUATIONS; TERMINATION; TERMINATION RATE COEFFICIENTS; TOLUENE SOLUTION;

ACRYLICS; ATOM TRANSFER RADICAL POLYMERIZATION; CHAIN LENGTH; ELECTRON SPIN RESONANCE SPECTROSCOPY; FREE RADICAL POLYMERIZATION; PARAMAGNETIC RESONANCE; PARAMAGNETISM; POLYMERS; TOLUENE;

SALTS;

EID: 79959716849     PISSN: 10221352     EISSN: 15213935     Source Type: Journal    
DOI: 10.1002/macp.201000781     Document Type: Article

References (54)

1. T. Junkers, C. Barner-Kowollik, J. Polym. Sci. Polym. Chem. 2008, 46, 7585.
2. G. E. Scott, E. Senogles, J. Macromol. Sci.-Chem. 1970, A 4, 1105.
3. G. E. Scott, E. Senogles, J. Macromol. Sci. Rev. Macromol. Chem. Phys. 1973, C9, 49.
4. G. E. Scott, E. Senogles, J. Macromol. Sci.-Chem. 1974, A8, 753.
5. S. Beuermann, D. A. Paquet, J. H. McMinn, R. A. Hutchinson, Macromolecules 1996, 29, 4206.
6. J. M. Asua, S. Beuermann, M. Buback, P. Castignolles, B. Charleux, R. G. Gilbert, R. A. Hutchinson, J. R. Leiza, A. N. Nikitin, J. P. Vairon, A. M. van Herk, Macromol. Chem. Phys. 2004, 205, 2151.
7. R. X. E. Willemse, A. M. van Herk, E. Panchenko, T. Junkers, M. Buback, Macromolecules 2005, 38, 5098.
8. A. N. Nikitin, R. A. Hutchinson, Macromolecules 2005, 38, 1581.
9. A. Kajiwara, ACS Symp. Ser. 2006, 944, 111.
10. A. Kajiwara, A. K. Nanda, K. Matyjaszewski, Macromolecules 2004, 37, 1378.
11. A. Kajiwara, M. Kamachi, ASC Symposium Ser. 2003, 854, 86.
12. J. Barth, M. Buback, P. Hesse, T. Sergeeva, Macromol. Rapid Commun. 2009, 30, 1969.
13. J. Barth, M. Buback, P. Hesse, T. Sergeeva, Macromolecules 2010, 43, 4023.
14. C. Barner-Kowollik, F. Gunzler, T. Junkers, Macromolecules 2008, 41, 8971.
15. K. F. O'Driscoll, H. K. Mahabadi, J. Polym. Sci. Polym. Chem. 1976, 14, 869.
16. A. N. Nikitin, R. A. Hutchinson, M. Buback, P. Hesse, Macromolecules 2007, 40, 8631.
17. C. Barner-Kowollik, M. Buback, M. Egorov, T. Fukuda, A. Goto, O. F. Olaj, G. T. Russell, P. Vana, B. Yamada, P. B. Zetterlund, Prog. Polym. Sci. 2005, 30, 605.
18. C. Barner-Kowollik, G. T. Russell, Prog. Polym. Sci. 2009, 34, 1211.
19. M. Buback, M. Egorov, T. Junkers, E. Panchenko, Macromol. Chem. Phys. 2005, 206, 333.
20. O. F. Olaj, P. Vana, A. Kornherr, G. Zifferer, Macromol. Chem. Phys. 1999, 200, 2031.
21. M. Buback, T. Junkers, Macromol. Chem. Phys. 2006, 207, 1640.
22. T. Junkers, A. Theis, M. Buback, T. P. Davis, M. H. Stenzel, P. Vana, C. Barner-Kowollik, Macromolecules 2005, 38, 9497.
23. G. B. Smith, G. T. Russell, J. P. A. Heuts, Macromol. Theory Simul. 2003, 12, 299.
24. B. Friedman, B. Oshaughnessy, Macromolecules 1993, 26, 5726.
25. O. F. Olaj, P. Vana, Macromol. Rapid Commun. 1998, 19, 533.
26. O. F. Olaj, P. Vana, Macromol. Rapid Commun. 1998, 19, 433.
27. H. Fischer, H. Paul, Acc. Chem. Res. 1987, 20, 200.
28. G. T. Russell, R. G. Gilbert, D. H. Napper, Macromolecules 1993, 26, 3538.
29. J. Barth, M. Buback, Macromol. React. Eng. 2010, 4, 288.
30. J. Barth, M. Buback, Macromol. Rapid Commun. 2009, 30, 1805.
31. M. C. Griffiths, J. Strauch, M. J. Monteiro, R. G. Gilbert, Macromolecules 1998, 31, 7835.
32. M. C. Piton, R. G. Gilbert, B. E. Chapman, P. W. Kuchel, Macromolecules 1993, 26, 4472.
33. A. Theis, A. Feldermann, N. Charton, T. P. Davis, M. H. Stenzel, C. Barner-Kowollik, Polymer 2005, 46, 6797.
34. M. Buback, P. Hesse, T. Junkers, T. Theis, P. Vana, Aust. J. Chem. 2007, 60, 779.
35. A. Theis, A. Feldermann, N. Charton, M. H. Stenzel, T. P. Davis, C. Barner-Kowollik, Macromolecules 2005, 38, 2595.
36. J. Barth, M. Buback, P. Hesse, T. Sergeeva, Macromolecules 2009, 42, 481.
37. M. Buback, E. Muller, G. T. Russell, J. Phys. Chem. A 2006, 110, 3222.
38. M. Buback, M. Egorov, T. Junkers, E. Panchenko, Macromol. Rapid Commun. 2004, 25, 1004.
39. G. B. Smith, G. T. Russell, Z. Phys. Chem. (Munich) 2005, 219, 295.
40. M. Buback, C. H. Kurz, C. Schmaltz, Macromol. Chem. Phys. 1998, 199, 1721.
41. S. Beuermann, M. Buback, C. Schmaltz, Macromolecules 1998, 31, 8069.
42. M. Buback, Macromol. Symp. 2009, 275-276, 90.
43. L. Couvreur, G. Piteau, P. Castignolles, M. Tonge, B. Coutin, B. Charleux, J. P. Vairon, Macromol. Symp. 2001, 174, 197.
44. S. Beuermann, M. Buback, T. P. Davis, R. G. Gilbert, R. A. Hutchinson, A. Kajiwara, B. Klumperman, G. T. Russell, Macromol. Chem. Phys. 2000, 201, 1355.
45. G. Johnston-Hall, A. Theis, M. J. Monteiro, T. P. Davis, M. H. Stenzel, C. Barner-Kowollik, Macromol. Chem. Phys. 2005, 206, 2047.
46. P. J. Flory, Principles of Polymer Chemistry, Ithaca, NY 1953.
47. J. Strauch, J. McDonald, B. E. Chapman, P. W. Kuchel, B. S. Hawkett, G. E. Roberts, M. P. Tonge, R. G. Gilbert, J. Polym. Sci. Polym. Chem. 2003, 41, 2491.
48. G. Johnston-Hall, M. J. Monteiro, J. Polym. Sci. Polym. Chem. 2008, 46, 3155.
49. M. G. Fröhlich, P. Vana, G. Zifferer, J. Chem. Phys. 2007, 127, 164906.
50. M. G. Fröhlich, P. Vana, G. Zifferer, Macromol. Theory Simul. 2007, 16, 610.
51. H. A. Schneider, Polymer 2005, 46, 2230.
52. N. M. Ahmad, F. Heatley, P. A. Lovell, Macromolecules 1998, 31, 2822.
53. S. Beuermann, M. Buback, Prog. Polym. Sci. 2002, 27, 191.
54. K. R. Harris, J. Chem. Eng. Data 2000, 45, 893.