메뉴 건너뛰기




Volumn 50, Issue 13, 2011, Pages 6107-6113

Construction of functionalized metallosupramolecular tetragonal prisms via multicomponent coordination-driven self-assembly

Author keywords

[No Author keywords available]

Indexed keywords

PLATINUM; PLATINUM COMPLEX;

EID: 79959714142     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic2002157     Document Type: Article
Times cited : (43)

References (50)
  • 46
    • 79959706256 scopus 로고    scopus 로고
    • note
    • 1H NMR spectra of the reaction mixtures display sharp, well-resolved peaks which superficially suggests single product formation. However, the possibility exists that the spatial separation between pillars is too great to impart any significant changes in chemical shifts between isomers. Considered separately, each pillar has one Pt on the same side of the functionality and one more distant. Thus, the symmetry between isomers is only broken when considering the relative arrangement of a second functionality on a distant pillar, either 28 or 29 bonds away, depending on up, up or up, down orientations. As a result, the ESI-MS and NMR data are not sufficient to confidently support or rule out the formation of a single isomer over a product mixture.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.