Spectroscopic and electronic structure studies of a dimethyl sulfoxide reductase catalytic intermediate: Implications for electron- and atom-transfer reactivity

Journal of the American Chemical Society

Volumn 133, Issue 25, 2011, Pages 9762-9774

  Mtei, Regina P ^a   Lyashenko, Ganna ^b   Stein, Benjamin ^a   Rubie, Nick ^a   Hille, Russ ^b   Kirk, Martin L ^a  

^a UNIVERSITY OF NEW MEXICO   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATOM-TRANSFER; CATALYTIC INTERMEDIATES; COORDINATION GEOMETRY; COVALENCIES; DITHIOLENE; ELECTRON-TRANSFER; ELECTRONIC ABSORPTION; ELECTRONIC ABSORPTION BANDS; ELECTRONIC STRUCTURE CALCULATIONS; EPR SPECTROSCOPY; MAGNETIC CIRCULAR DICHROISM SPECTROSCOPY; METAL-LIGAND BONDING; REACTION COORDINATES; SINGLY OCCUPIED MOLECULAR ORBITALS; SPECTROSCOPIC DATA;

ABSORPTION; ABSORPTION SPECTROSCOPY; ATOMIC SPECTROSCOPY; DENSITY FUNCTIONAL THEORY; DICHROISM; DIMETHYL SULFOXIDE; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC PROPERTIES; ELECTRONIC STRUCTURE; EXCITED STATES; GEOMETRY; MOLECULAR ORBITALS; MOLYBDENUM; PARAMAGNETIC MATERIALS; PARAMAGNETIC RESONANCE; PARAMAGNETISM; VANADIUM;

REACTION INTERMEDIATES;

DIMETHYL SULFOXIDE REDUCTASE;

ARTICLE; ATOM; CATALYSIS; CHEMICAL BINDING; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; ELECTRONIC ABSORPTION SPECTROSCOPY; MAGNETIC CIRCULAR DICHROISM SPECTROSCOPY; SPECTROSCOPY;

BIOCATALYSIS; ELECTRONS; IRON-SULFUR PROTEINS; MOLECULAR STRUCTURE; OXIDOREDUCTASES; SPECTRUM ANALYSIS;

EID: 79959508404     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja109178q     Document Type: Article

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