The role of external and internal mass transfer in the process of Cu2+ removal by natural mineral sorbents

Environmental Technology

Volumn 32, Issue 9, 2011, Pages 933-943

  Sljivic M ^a   Smiciklas I ^a   Plecas I ^a   Pejanovic S ^b  

^a UNIVERSITY OF BELGRADE   (Serbia)

^b UNIVERSITY OF BELGRADE   (Serbia)

Author keywords

clay; diatomite; mass transfer; zeolite

Indexed keywords

CLAY MINERALS; SORPTION;

CATION CONCENTRATIONS; DIATOMITE; DIMENSIONLESS NUMBER; EXTERNAL MASS TRANSFER COEFFICIENT; INTERNAL DIFFUSIVITY; INTERNAL MASS TRANSFER; INTRA-PARTICLE DIFFUSION; MASS TRANSFER PHENOMENA; METAL CONCENTRATIONS; NATURAL MINERALS; RATE-LIMITING STEPS; RESISTANCE MODELS; SHERWOOD; THEORETICAL MODELS; ZEOLITE PARTICLES;

MASS TRANSFER;

COPPER ION; INFUSORIAL EARTH; SORBENT; ZEOLITE;

CLAY; DIATOMITE; DIFFUSION; DIMENSIONLESS NUMBER; ION EXCHANGE; MASS TRANSFER; REACTION KINETICS; SORPTION; ZEOLITE;

ADSORPTION KINETICS; ARTICLE; BIOFILM REACTOR; CATION TRANSPORT; CHEMICAL PHENOMENA; CLAY; CONCENTRATION (PARAMETERS); MASS TRANFER PHENOMENA; MEMBRANE TRANSPORT; METAL METABOLISM; PARTICLE SIZE; THEORETICAL MODEL; WASTE COMPONENT REMOVAL;

EID: 79959415198     PISSN: 09593330     EISSN: 1479487X     Source Type: Journal    
DOI: 10.1080/09593330.2010.521952     Document Type: Article

References (47)

1. S. Babel, T.A. Kurniawan Low-cost adsorbents for heavy metals uptake from contaminated water: A review J. Hazard. Mater. 97; 2003: 219-243. (Pubitemid 36169960)
2. Y.S. Ho, J.C.Y. Ng, and G. McKay, Kinetics of pollutant sorption by biosorbents: Review, Sep. Purif. Methods 29 (2000), pp. 189-232. (Pubitemid 34782411)
3. M. Suzuki, Adsorption Engineering, Kodansha Ltd., Tokyo, and Elsevier Science, Amsterdam, 1990.
4. K. Bhattacharyya and G.S.S. Gupta, Adsorptive accumulation of Cd(II), Co(II), Cu(II), Pb(II), and Ni(II) from water on montmorillonite: Influence of acid activation, J. Colloid Interface Sci. 310 (2007), pp. 411-424. (Pubitemid 46654020)
5. 2+ from aqueous solutions by adsorption on natural clinoptilolite, Appl. Clay Sci. 35 (2007), pp. 139-144. (Pubitemid 46019403)
6. B. Karagozoglu, M. Tasdemir, E. Demirbas, and M. Kobya, The adsorption of basic dye (Astrazon Blue FGRL) from aqueous solutions onto sepiolite, fly ash and apricot shell activated carbon: Kinetic and equilibrium studies, J. Hazard. Mater. 147 (2007), pp. 297-306. (Pubitemid 47088815)
7. B. Chen, W. Huang, J. Mao, and S. Lv, Enhanced sorption of naphthalene and nitroaromatic compounds to bentonite by potassium and cetyltrimethylammonium cations, J. Hazard. Mater. 158 (2008), pp. 116-123.
8. O. Hamdaoui and E. Naffrechoux, Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon. Part II. Models with more than two parameters, J. Hazard. Mater. 147 (2007), pp. 401-411. (Pubitemid 47088827)
9. E. Guibal, C. Milot, and C.J.M. Tobin, Metal anion sorption by chitosan beads: Equilibrium and kinetic studies, Ind. Eng. Chem. Res. 37 (1998), pp. 1454-1463. (Pubitemid 128497924)
10. R. Djeribi and O. Hamdaoui, Sorption of copper (II) from aqueous solutions by cedar sawdust and crushed brick, Desalination 225 (2008), pp. 95-112. (Pubitemid 351309085)
11. K.K.H. Choy, D.C.K. Ko, C.W. Cheung, J.F. Porter, and G. McKay, Film and intraparticle mass transfer during the adsorption of metal ions onto bone char, J. Colloid Interface Sci. 271 (2004), pp. 284-295. (Pubitemid 38221426)
12. F. Helfferich, Ion-exchange kinetics. V. Ion exchange accompanied by reactions, J. Phys. Chem. 69 (1965), pp. 1178-1187.
13. R. Turse and W. Rieman III, Kinetics of ion exchange in a chelating resin, J. Phys. Chem. 65 (1961), pp. 1821-1824.
14. B. Halliwell and J.M. Gutteridge, Role of free radicals and catalytic metal ions in human disease: An overview, Methods Enzymol. 186 (1990), pp. 1-85. (Pubitemid 20279941)
15. D.C.K. Ko, J.F. Porter, and G. McKay, Fixed bed studies for the sorption of metal ions onto peat, Process Saf. Environ. Protect. B 81 (2003), pp.73-86. (Pubitemid 44228955)
16. B. Chen, C.W. Hui, and G. McKay, Film-pore diffusion modeling for the sorption of metal ions from aqueous effluents onto peat, Water Res. 35 (2001), pp. 3345-3356. (Pubitemid 32727945)
17. K.K.H. Choy and G. McKay, Sorption of cadmium, copper, and zincions onto bone char using Crank diffusion model, Chemosphere 60 (2005), pp. 1141-1150. (Pubitemid 40910105)
18. K.K.H. Choy and G. McKay, Sorption of metal ions from aqueous solution using bone char, Environ. Int. 31 (2005), pp. 845-854. (Pubitemid 41020740)
19. J.P. Chen and L. Wang, Characterization of metal adsorption kinetic properties in batch and fixed-bed reactors, Chemosphere 54 (2004), pp. 397-404. (Pubitemid 38044551)
20. 2+ using modified zeolite from coal fly ash, Chem. Eng. J. 144 (2008), pp. 245-258.
21. T.S. Anirudhan and P.S. Suchithra, Synthesis and characterization of tannin-immobilized hydrotalcite as a potential adsorbent of heavy metal ions in effluent treatments, Appl. Clay Sci. 42 (2008), pp. 214-223.
22. R. Apiratikul and P. Pavasant, Batch and column studies of biosorption of heavy metals by Caulerpa lentil-lifera, Bioresour. Technol. 99 (2008), pp. 2766-2777. (Pubitemid 351208599)
23. V.J.P. Vilar, C.M.S. Botelho, and R.A.R. Boaventura, Metal biosorption by algae Gelidium derived materials from binary solutions in a continuous stirred adsorber, Chem. Eng. J. 141 (2008), pp. 42-50. (Pubitemid 351794575)
24. V.J.P. Vilar, C.M.S. Botelho, and R.A.R. Boaventura, Kinetics modelling of biosorption by algal biomass from binary metal solutions using batch contactors, Biochem. Eng. J. 38 (2008), pp. 319-325. (Pubitemid 351191797)
25. S.K. Papageorgiou, F.K. Katsaros, E.P. Kouvelos, J.W. Nolan, H. Le Deit, and N.K. Kanellopoulos, Heavy metal sorption by calcium alginate beads from Laminaria digitata, J. Hazard. Mater. 137 (2008), pp. 1765-1772. (Pubitemid 44462721)
26. J.-P. Chen, W.-R. Chen, and R.-C. Hsu, Biosorption of copper from aqueous solutions by plant root tissues, J. Ferment. Bioeng. 81 (1996), pp. 458-463. (Pubitemid 26202173)
27. 2+ adsorption on a zeolite, a clay and a diatomite from Serbia, Appl. Clay Sci. 43 (2009), pp. 33-40.
28. A.P. Mathews and W.J. Weber Jr, Effects of external mass transfer and intraparticle diffusion on adsorption rates in slurry reactors, Am. Inst. Chem. Eng. Symp. Ser. 73 (1977), pp. 91-107.
29. T. Furusawa and J.M. Smith, Fluid-particle and intraparticle mass transport rates in slurries, Ind. Eng. Chem. Fundam. 12 (1973), pp. 197-203.
30. G.E. Boyd, A.E. Adamson, and L.S. Meyers, The exchange adsorption of ions from aqueous solutions by organic zeolites. II. Kinetics, J. Am. Chem. Soc. 69 (1947), pp. 2836-2848.
31. R.H. Perry and D.W. Green, Perry's Chemical Engineers' Handbook, 7th ed., McGraw-Hill, New York, 1997.
32. T. Vermeulen, Separation by adsorption methods, Adv. Chem. Eng. 2 (1958), pp. 147-208.
33. J. Vuceta and J. Morgan, Hydrolysis of Cu(II), Limnol. Oceanogr. 22 (1977), pp. 742-746.
34. K.V. Kumar and S. Sivanesan, Surface mass transfer during the sorption of basic dye onto boiler bottom ash, Pol. J. Environ. Stud. 13 (2004), pp. 443-445. (Pubitemid 39026740)
35. K. Porkodi and K.V. Kumar, Equilibrium, kinetics and mechanism modeling and simulation of basic and acid dyes sorption onto jute fiber carbon: Eosin yellow, malachite green and crystal violet single component systems, J. Hazard. Mater. 143 (2007), pp. 311-327. (Pubitemid 46560226)
36. M.L. Schlegel, L. Charlet, and A. Manceau, Sorption of metal ions on clay minerals: II. Mechanism of co sorption on hectorite at high and low ionic strength and impact on the sorbent stability, J. Colloid Interface Sci. 220 (1999), pp. 392-405. (Pubitemid 30045787)
37. Y. Saî and Y. Aktay, Mass transfer and equilibrium studies for the sorption of chromium ions onto chitin, Process Biochem. 36 (2000), pp. 157-173.
38. W.H. Cheung, Y.S. Szeto, and G. McKay, Intraparticle diffusion processes during acid dye adsorption onto chitosan, Bioresour. Technol. 98 (2007), pp. 2897-2904. (Pubitemid 46601969)
39. O. Hamdaouia, F. Saoudi, M. Chiha, and E. Naffre-choux, Sorption of malachite green by a novel sorbent, dead leaves of plane tree: Equilibrium and kinetic modeling, Chem. Eng. J. 143 (2008), pp. 73-84.
40. 2+ ions, Chem. Eng. J. 148 (2009), pp. 80-88.
41. M. Jansson-Charrier, E. Guibal, J. Roussy, B. Delanghe, and P. Le Cloirec, Vanadium (IV) sorption by chitosan: Kinetics and equilibrium, Water Res. 30 (1996), pp. 465-475. (Pubitemid 26007280)
42. A.E. Ofomaja, Kinetics and mechanism of methylene blue sorption onto palm kernel fibre, Process Biochem. 42 (2007), pp. 16-24. (Pubitemid 44755359)
43. C.W. Cheung, C.K. Chan, J.F. Porter, and G. McKay, Combined diffusion model for the sorption of cadmium, copper, and zincions onto bone char, Environ. Sci. Technol. 35 (2001), pp. 1511-1522. (Pubitemid 32862525)
44. J. Barthel, H. Krienke, W. Kunz, H. Baumgartel, and E.U. Franck, Physical Chemistry of Electrolyte Solutions: Modern Aspects, Springer, Berlin, and Steinkopf, Darmstadt, 1998.
45. V.J. Inglezakis and H.P. Grigoropoulou, Applicability of simplified models for the estimation of ion exchange diffusion coefficients in zeolites, J. Colloid Interface Sci. 234 (2001), pp. 434-441. (Pubitemid 32547773)
46. M. Benamor, Z. Bouariche, T. Belaid, and M.T. Draa, Kinetic studies on cadmium ions by Amberlite XAD7 impregnated resins containing di(2-ethylhexyl) phosphoric acid as extractant, Sep. Purif. Technol. 59 (2008), pp. 74-84. (Pubitemid 350298963)
47. G. McKay, Solution to the homogeneous surface diffusion model for batch adsorption systems using orthogonal collocation, Chem. Eng. J. 81 (2001), pp. 213-221.