First 13C/12C isotopic characterisation of volcanic plume CO2

Bulletin of Volcanology

Volumn 73, Issue 5, 2011, Pages 531-542

  Chiodini, Giovanni ^a   Caliro, Stefano ^a   Aiuppa, Alessandro ^b,c   Avino, Rosario ^a   Granieri, Domenico ^d   Moretti, Roberto ^a   Parello, Francesco ^b  

^a ISTITUTO NAZIONALE DI GEOFISICA E VULCANOLOGIA   (Italy)

^b UNIVERSITY OF PALERMO   (Italy)

^c SEZIONE DI PALERMO   (Italy)

^d SEZIONE DI PISA   (Italy)

Author keywords

Carbon isotope; Etna; Magmatic degassing; Volcanic plume

Indexed keywords

CARBON DIOXIDE; CARBON ISOTOPE; CONFIDENCE INTERVAL; DEGASSING; FUMAROLE; ISOTOPIC ANALYSIS; ISOTOPIC COMPOSITION; ISOTOPIC FRACTIONATION; MAGMA CHEMISTRY; TEMPORAL VARIATION; TREND ANALYSIS; UNCERTAINTY ANALYSIS; VOLCANIC GAS;

CAMPANIA [ITALY]; CATANIA [SICILY]; ETNA; ITALY; LIPARI ISLANDS; MESSINA [SICILY]; NAPOLI [CAMPANIA]; SICILY; SOLFATARA; VULCANO;

EID: 79959198442     PISSN: 02588900     EISSN: 14320819     Source Type: Journal    
DOI: 10.1007/s00445-010-0423-2     Document Type: Article

References (74)

1. Aiuppa A, Federico C, Giudice G, Gurrieri S, Liuzzo M, Shinohara H, Favara R, Valenza M (2006) Rates of carbon dioxide plume degassing from Mount Etna volcano. J Geophys Res 111: B09207. doi: 10. 1029/2006JB004307.
2. Aiuppa A, Moretti R, Federico C, Giudice G, Gurrieri S, Liuzzo M, Papale P, Shinohara H, Valenza M (2007) Forecasting Etna eruption by real time evaluation of volcanic gas composition. Geology 35: 1115-1118. doi: 10. 1130/G24149A.
3. Aiuppa A, Giudice G, Gurrieri S, Liuzzo M, Burton M, Caltabiano T, McGonigle AJS, Salerno G, Shinohara H, Valenza M (2008) Total volatile flux from Mount Etna. Geophys Res Lett 35: L24302. doi: 10. 1029/2008GL035871.
4. 2 gas emissions from Stromboli volcano (Italy). Eos Trans. AGU 90(52), Fall Meet Suppl, V23H-06.
5. 2 ratio. J Volcanol Geotherm Res 182: 221-230. doi: 10. 1016/j. jvolgeores. 2008. 09. 013.
6. Allard P (1983) The origin of water, carbon, sulphur, nitrogen and rare gases in volcanic exhalations; evidence from isotope geochemistry. In: Tazieff H, Sabroux JC (eds) Forecasting volcanic events. Elsevier, Amsterdam, pp 337-386.
7. Allard P, Baubron JVC, Le Bronec J, Luongo G, Maurenas JM, Pece R, Robe MC, Tedesco D, Zettwoog P (1988) Geochemical survey of volcanic gas soil emanations and eruption forecasting: The Vesuvius case. Italy, In Proceedings of the Kagoshima International Conference on Volcanoes.
8. 2 from Mount Etna. Nature 351: 387-391.
9. Allard P, Maiorani A, Tedesco D, Cortecci G, Turi B (1991b) Isotopic study of the origin of sulfur and carbon in Solfatara fumaroles, Campi Flegrei caldera. J Volcanol Geotherm Res 48: 139-159.
10. Allard P, Carbonnelle J, Métrich N, Loyer H, Zettwoog P (1994) Sulphur output and magma degassing budget of Stromboli volcano. Nature 368: 326-330.
11. Allard P, JeanBaptiste P, Dalessandro W, Parello F, Parisi B, Flehoc C (1997) Mantle-derived helium and carbon in groundwaters and gases of Mount Etna, Italy. Earth Planet Sci Lett 148: 501-516.
12. Allard P, Behncke B, D'Amico S, Neri M, Gambino S (2006) Mount Etna 1993-2005: Anatomy of an evolving eruptive cycle. Earth Sci Rev 78: 85-114.
13. Allard P, Aiuppa A, Bani P, Parello F, Shinohara H, Gauthier PJ, Bagnato E, Bertagnini A, Mètrich N (2008) Magmatic volatile vmissions from Ambrym and Yasur volcanoes (Vanuatu arc). IAVCEI 2008, Iceland. Abstract: 35.
14. Allard P, Aiuppa A, Bani P, Metrich N, Bertagnini A, Gauthier PG, Parello F, Sawyer GM, Shinohara H, Bagnato E, Mariet C, Garaebiti E, Pelletier B (2009) Ambrym basaltic volcano (Vanuatu arc): volatile fluxes, magma degassing rate and chamber depth. Eos Trans AGU 90(52), Fall Meet Suppl, V24C-04.
15. Berner RA, Lasaga AC (1989) Modeling the geochemical carbon cycle. Am J Sci 260: 74-81.
16. Branca S, Del Carlo P (2004) Eruptions of Mt. Etna During the Past 3, 200 Years: A Revised Compilation Integrating the Historical and Stratigraphic Records. In: Bonaccorso A, Calvari S, Coltelli M, Del Negro C, Falsaperla S (eds) Etna volcano laboratory. Am Geophys Union Geophys Mon 143: 1: 29.
17. Brantley SL, Koepenick KW (1995) Measured carbon dioxide emissions from Oldoinyo Lengai and the skewed distribution of passive volcanic fluxes. Geology 23: 933-936.
18. 2O emission rates from Masaya volcano, Nicaragua. Geology 28: 915-918.
19. Caliro S, Panichi C, Stanzione D (1999) Variation in the total dissolved carbon isotope composition of thermal waters of the Island of Ischia (Italy) and its implications for volcanic surveillance. J Volcanol Geotherm Res 90: 219-240.
20. Caliro S, Chiodini G, Avino R, Cardellini C, Frondini F (2005) Volcanic degassing at Somma-Vesuvio (Italy) inferred by chemical and isotopic signatures of groundwater. Appl Geochem 20: 1060-1076. doi: 10. 1016/j. apgeochem. 2005. 02. 002.
21. Caliro S, Chiodini G, Moretti R, Avino R, Granieri D, Russo M, Fiebig J (2007) The origin of the fumaroles of La Solfatara (Campi Flegrei, South Italy). Geochim Cosmochim Acta 71: 3040-3055. doi: 10. 1016/j. gca. 2007. 04. 007.
22. Capasso G, Favara R, Inguaggiato S (1997) Chemical features and isotopic composition of gaseous manifestations on Vulcano Island, Aeolian Islands, Italy: An interpretative model of fluid circulation. Geochim Cosmochim Acta 61: 3425-3440.
23. Carroll MR, Halloway JR (1994) Volatiles in magmas. Rev Mineral 30: 231-279.
24. Chacko T, Cole DR, Horita J (2001) Equilibrium oxygen, hydrogen and carbon isotope fractionation factors applicable to geologic systems. Rev Mineral 43: 1-81.
25. Chiodini G, Cioni R, Marini L (1993) Reactions governing the chemistry of crater fumaroles from Vulcano Island (Italy) and implications for volcanic surveillance. Appl Geochem 8: 357-371.
26. Chiodini G, Frondini F, Cardellini C, Parello F, Peruzzi L (2000) Rate of diffuse carbon dioxide Earth degassing estimated from carbon balance of regional aquifers; the case of central Apennine, Italy. J Geophys Res 105: 8423-8434. doi: 10. 1029/1999JB900355.
27. 2 degassing and energy release at Solfatara volcano, Campi Flegrei, Italy. J Geophys Res 106: 16213-16221.
28. 2 degassing in volcanic-hydrothermal areas. Earth Planet Sci Lett 274: 372-379. doi: 10. 1016/j. epsl. 2008. 07. 051.
29. Chiodini G, Caliro S, Cardellini C, Granieri D, Avino R, Baldini A, Donnini M, Minopoli C (2010) Long-term variations of the Campi Flegrei, Italy, volcanic system as revealed by the monitoring of hydrothermal activity. J Geophys Res 115: B03205. doi: 10. 1029/2008JB006258.
30. Clocchiatti R, Joron JL, Treuil M (1988) The role of selective alkali contamination in the evolution of recent historic lavas of Mt. Etna J Volcanol Geotherm Res 34: 241-249.
31. Corsaro RA, Métrich N, Allard P, Andronico D, Miraglia L, Fourmentraux C (2009) The 1974 flank eruption of Mount Etna: an archetype for deep dike-fed eruptions at basaltic volcanoes and a milestone in Etna's recent history. J Geophys Res 114: B07204. doi: 10. 1029/2008JB006013.
32. Craig H (1953) The geochemistry of the stable carbon isotopes. Geochim Cosmochim Acta 3: 53-92.
33. 2) from Mount Etna as indicators of degassing of shallow astenosphere. Bull Volcanol 59: 455-458.
34. Deines P, Gold DP (1973) Isotopic composition of carbonatite and kimberlite carbonates and their bearing on isotopic composition of deep-seated carbon. Geochim Cosmochim Acta 37: 1709-1733.
35. 2 lithosphere-asthenosphere degassing beneath the Western Mediterranean: An integrated model arising from petrological and geophysical data. Chem Geol 262: 108-120. doi: 10. 1016/j. chemgeo. 2009. 02. 015.
36. Gagliardi G, Restieri R, Casa G, Gianfrani L (2002) Concentration measurements and isotopic analysis using diode laser spectroscopy: applications to volcanic gas monitoring. Opt Lasers Eng 37: 131-142.
37. 2 emissions from volcanoes. EOS Trans AGU 72: 240-253.
38. Gerlach TM, Graeber EJ (1985) Volatile budget of Kilauea Volcano. Nature 313: 273-277.
39. 2 analyzer to volcanic plumes: a case study, volcano Popocatepetl, Mexico, June 7 and 10, 1995. J Geophys Res 102: 8005-8019.
40. 2: test study at Pu'u 'O'o cone, Kilauea volcano, Hawaii. Geophys Res Lett 25: 2675-2678.
41. Gerlach TM, McGee KA, Elias T, Sutton AJ, Doukas MP (2002) Carbon dioxide emission rat of Kilauea Volcano: implications for primary magma and the summit reservoir. J Geophys Res 107: 2189. doi: 10. 1029/2001JB000407.
42. Giammanco S, Inguaggiato S, Valenza M (1998) Soil and fumarole gases of Mount Etna: Geochemistry and relations with volcanic activity. J Volcanol Geotherm Res 81: 297-310.
43. Giggenbach WF (1997) Relative importance of thermodynamic and kinetic processes in governing the chemical and isotopic composition of carbon gases in high-heatflow sedimentary basins. Geochim Cosmochim Acta 61: 3763-3785.
44. 2 emissions at Popocatépetl volcano, Mexico. Chem Geol 177: 133-156.
45. 2 ratio method at Kīlauea Volcano, Hawai'i, during a period of sustained inflation. J Volcanol Geotherm Res 177: 875-882.
46. Holloway JR, Blank JG (1994) Application of experimental results to C-O-H species in natural melts. Rev Mineral 30: 187-230.
47. 2 in the dynamics of volcano degassing: The Mount Vesuvius example. Geology 37: 319-322.
48. 2. Geology 26: 375-378.
49. Kerrick DK, Connolly JAD (2001) Metamorphic devolatilization of subducted marine sediments and the transport of volatiles into the Earth's mantle. Nature 411: 293-296.
50. Kyser TK (1986) Stable isotope variations in the mantle. Rev Mineral 16: 141-164.
51. 2 flux, and temperature on Masaya volcano. Nicaragua Geophys Res Lett 30: 1817. doi: 10. 1029/2003GL017731.
52. Lyon GL, Hulston JR (1984) Carbon and hydrogen isotopic compositions of New-Zealand geothermal gases. Geochim Cosmochim Acta 48: 1161-1171.
53. Martelli M, Caracausi A, Paonita A, Rizzo A (2008) Geochemical variations of air-free crater fumaroles at Mt. Etna: New inferences for forecasting shallow volcanic activity. Geophys Res Lett 35: L21302. doi: 10. 1029/2008GL035118.
54. Mattey DP (1991) Carbon dioxide solubility and carbon isotope fractionation in basaltic melt. Geochim Cosmochim Acta 55: 3467-3473.
55. Métrich N, Allard P, Spilliaert N, Andronico D, Burton M (2004) 2001 flank eruption of the alkali- and volatile-rich primitive basalt responsible for Mount Etna's evolution in the last three decades. Earth Planet Sci Lett 228: 1-17.
56. Oppenheimer C, Kyle PR (2008) Probing the magma plumbing of Erebus volcano, Antarctica, by open-path FTIR spectroscopy of gas emissions. J Volcanol Geotherm Res 177: 743-754.
57. Oppenheimer C, Bani P, Calkins JA, Burton MR, SG M (2006) Rapid FTIR sensing of volcanic gases released by Strombolian explosions at Yasur volcano, Vanuatu. Appl Phys B 85: 2-3. doi: 10. 1007/s00340-006-2353-4.
58. Orsi G, de Vita S, di Vito M (1996) The restless, resurgent Campi Flegrei nested caldera (Italy); constraints on its evolution and configuration. J Volcanol Geotherm Res 74: 179-214.
59. Pecoraino G, Giammanco S (2005) Geochemical characterization and temporal changes in parietal gas emissions at Mt. Etna (Italy) during the period July 2000-July 2003. Terr Atmos Ocean Sci 16: 805-841.
60. Press WH, Teukolsky SA, Vetterling WT, Flannery BP (2001) Numerical recipes in Fortran 77: the art of scientific computing. Cambridge Univ Press, Cambridge.
61. Rosi M, Sbrana A (eds) (1987) Phlegraean fields. Quaderni de "La Ricerca Scientifica" 114(9) CNR, Roma.
62. Sano Y, Marty B (1995) Origin of carbon in fumarolic gas from island arcs. Chem Geol 119: 265-274.
63. Sawyer GM, Oppenheimer C, Tsanev VI, Yirgu G (2008a) Magmatic degassing at Erta 'Ale volcano, Ethiopia. J Volcanol Geotherm Res 178: 837-846.
64. Sawyer GM, Carn SA, Tsanev VI, Oppenheimer C, Burton MR (2008b) Investigation into magma degassing at Nyiragongo volcano. Democratic Republic of the Congo. Geochem Geophys Geosyst 9: Q02017. doi: 10. 1029/2007GC001829.
65. Schiano P, Clocchiatti R, Ottolini L, Busa' T (2001) Transition of Mount Etna lavas from a mantle-plume to an island-arc magmatic source. Nature 412: 900-904.
66. Shinohara H, Witter JB (2005) Volcanic gases emitted during mild Strombolian activity of Villarica volcano Chile. Geophys Res Lett 32: L20308. doi: 10. 1029/2005GL024131.
67. Shinohara H, Fukui K, Kazahaya K, Saito G (2003) Degassing process of Miyakejima volcano: Implications of gas emission rate and melt inclusion data. In: De Vivo B, Bodnar B (eds) Melt inclusions in volcanic systems. Elsevier, New York, pp 147-161.
68. Spilliaert N, Allard P, Métrich N, Sobolev AV (2006) Melt inclusion record of the conditions of ascent, degassing, and extrusion of volatile-rich alkali basalt during the powerful 2002 flank eruption of Mount Etna (Italy). J Geophys Res 111: B04203. doi: 10. 1029/2005JB003934.
69. Symonds RB, Gerlach TM, Reed MH (2001) Magmatic gas scrubbing; implications for volcano monitoring. J Volcanol Geotherm Res 108: 303-341.
70. Tonarini S, Armienti P, D'Orazio M, Innocenti F (2001) Subduction-like fluids in the genesis of Mt. Etna magmas: evidence from boron isotopes and fluid mobile elements. Earth Planet Sci Lett 192: 471-483.
71. Wallace PJ (2005) Volatiles in subduction zone magmas: concentrations and fluxes based on melt inclusion and volcanic gas data. J Volcanol Geotherm Res 140: 217-240.
72. Wardell LJ, Kylea PR, Dunbar N, Christenson B (2001) White Island volcano, New Zealand: carbon dioxide and sulfur dioxide emission rates and melt inclusion studies. Chem Geol 177: 187-200.
73. Wardell LJ, Kyle PR, Chaffin C (2004) Carbon dioxide and carbon monoxide emission rates from and alkaline intra-plate volcano: Mt. Erebus, Antarctica. J Volcanol Geotherm Res 131: 109-121.
74. Witt MLI, Mather TA, Pyle DM, Aiuppa A, Bagnato E, Tsanev VI (2008) Mercury and halogen emissions from Masaya and Telica volcanoes Nicaragua. J Geophys Res 113: B06203. doi: 10. 1029/2007JB005401.