Extraction and stripping of rare earths using mixtures of acidic phosphorus-based reagents

Journal of Rare Earths

Volumn 29, Issue 5, 2011, Pages 413-415

  Wang, Xianglan ^a   Li, Wei ^b   Li, Deqian ^c  

^a Wuhan University of Bioengineering   (China)

^b LIAONING SHIHUA UNIVERSITY   (China)

^c CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

Author keywords

extraction characters; mixtures of acidic phosphorus based reagents; trivalent rare earths

Indexed keywords

CHLORINE COMPOUNDS; ESTERIFICATION; ESTERS; PHOSPHORUS; RARE EARTHS; SOLVENT EXTRACTION; YTTERBIUM;

CHLORIDE SOLUTIONS; CYANEX 272; CYANEX 302; CYANEX-301; EXTRACTANTS; PHOSPHINIC ACID; SEPARATION FACTORS; TRIVALENT RARE EARTHS;

PHOSPHORIC ACID;

EID: 79958831506     PISSN: 10020721     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1002-0721(10)60470-X     Document Type: Article

References (19)

1. Peppard DF, Ferraro JR The preparation and infra-red absorption spectra of several complexes of bis-(2-ethylhexyl)- phosphoric acid J. Inorg. Nucl. Chem. 10 1959 275
2. Mason GW, Lewey S, Peppard DF Extraction of metallic cations by mono-acidic orthophosphate esters in a monomerizing diluent J. Inorg. Nucl. Chem. 26 1964 2271
3. Li DQ, Wan X, Lin DZ, Xie YF, Lin SX, Wang ZH, Li H, Ji EY Extraction separation of rare earth elements, scandium and thorium with 2-ethylhexyl-phosphonic acid mono-2- ethylhexyl ester Proc. ISEC'80 Liege Belgium 3 1980 80
4. Cyanex 272, Cyanex 302, Cyanex 301. Technical Brochures. Cytec Industries, Inc. West Paterson, New Jersey.
5. Komatsu Y, Freiser H Extraction separation of tervalent lanthanide metals with bis(2,4,4-trimethylpentyl)phosphinic acid Anal. Chim. Acta 227 1989 397
6. Zhang XF, Li DQ Extraction of rare earth ions(III) with bis(2,4,4-trimethylpentyl)phosphinic acid Chin. J. Appl. Chem. 10 4 1993 72
7. Xu GX Rare earths: Vol. 1 (2nd Ed., in Chin.) 1995 Metallurgy Industry Press Beijing 525
8. Lu J. Ph.D. Thesis, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 1998.
9. Wang XL, Li W, Meng SL, Li DQ The extraction of rare earths using mixtures of acidic phosphorus-based reagents or their thio-analogues J. Chem. Technol. Biotechnol. 81 2006 761
10. Jensen MP, Bond AH Influence of aggregation on the extraction of trivalent lanthanide and actinide cations by purified Cyanex272, Cyanex301, and Cyanex302 Radiochim. Acta 90 2002 205
11. Tian GX, Kimura T, Yoshida Z, Zhu YJ, Rao LF Fluorescence and IR studies on the hydration state of lanthanides(III) and curium(III) in the complexes extracted with purifiedCyanex301, Cyanex302 and Cyanex272 Radiochim. Acta. 92 2004 495
12. 3+ from different aqueous media by bis(2,4,4-trimethyl) dithio phosphinic acid J. Nucl. Radiochem. 28 2006 178
13. Law JD, Peterman DR, Todd TA, Tillotson RD Separation of trivalent actinides from lanthanides in an acetate buffer solution using Cyanex301 Radiochim. Acta 94 2006 261
14. Bhattacharyya A, Mohapatra PK, Ansari SA, Raut DR, Manchanda VK Separation of trivalent actinides from lanthanides using hollow fiber supported liquid membrane containing Cyanex-301 as the carrier J. Membr. Sci. 312 2008 1
15. 3+ from nitrate medium using Cyanex (R) 301 Solven Extr. Ion Exch. 25 2007 27
16. Qiong Jia, Shanshan Tong, Zhiying Li, Weihong Zhou, Hongfei Li, Shulan Meng Solvent extraction of rare earth elements with mixtures of sec-octylphenoxy acetic acid and bis(2,4,4-trimethylpentyl) dithiophosphinic acid Separation and Purification Technology 64 2009 345
17. Sole KC, Hiskey JB Solvent extraction characteristic of thiosubstituted organophosphinic acid extractants Hydrometallurgy 30 1992 345
18. Li DQ, Luo AQ, Wang C, Yuan M Solvent extraction of trivalent lanthanides with Cyanex 302 from acidic aqueous chloride solutions, in Value Adding Through Solvent Extraction, Proc. ISEC'96. Shallcross D C, Paimin Rand Prvcic L M, Ed. University of Melbourne Vol. 1 1996 165
19. Komatsu Y, Freiser H Extraction separation of tervalent lanthanide metals with bis(2,4,4-trimethylpentyl)phosphinic acid Anal. Chim. Acta 227 1989 397