Synthesis and characterization of two isomorphous cobalt(II), nickel(II) complexes with (63)(67,83)topologies

Inorganic Chemistry Communications

Volumn 14, Issue 8, 2011, Pages 1237-1240

  Xu, Bo ^a,b   Lü, Jian ^a   Cao, Minna ^a   Han, Liwei ^a   Cao, Rong ^a  

^a FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Bipyridyl ligand; Cobalt(II) complex; Coordination polymer; Nickel(II) complex

Indexed keywords

EID: 79958830020     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.04.030     Document Type: Article

References (22)

1. D.A. Beauchamp, and S.J. Loeb Hydrogen-bonded networks through second-sphere coordination Chem. Eur. J. 8 2002 5084 5088 (Pubitemid 35398278)
2. B. Moulton, and M. Zaworotko From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids J. Chem. Rev. 101 2001 1629 1658 (Pubitemid 35377799)
3. V.A. Blatov, L. Carlucci, G. Ciani, and D.M. Proserpio Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. analysis of the cambridge structural database CrystEngComm 6 2004 377 395 (Pubitemid 40482155)
4. (d) O.K. Farha, C.D. Malliakas, M.G. Kanatzidis, J.T. Hupp, Control over catenation in metal-organic frameworks via rational design of the organic building block, J. Am. Chem. Soc. 132 (20109) 950-952;
5. S.R. Batten, and R. Robson Interpenetrating nets: ordered, periodic entanglement Angew. Chem. Int. Ed. 37 1998 1460 1494
6. S. Kitagawa, R. Kitaura, and S.I. Noro Functional porous coordination polymers Angew. Chem. Int. Ed. 43 2004 2334 2375 (Pubitemid 39257732)
7. O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, H.K. Chae, M. Essaoudi, and J. Kim Reticular synthesis and the design of new materials Nature 423 2003 705 714 (Pubitemid 36735687)
8. J.Y. Lee, O.K. Farha, J. Roberts, K.A. Scheidt, S.T. Nguyen, and J.T. Hupp Metal-organic frameworks as catalysts Chem. Soc. Rev. 38 2009 1450 1459
9. W. Eerenstein, N.D. Mathur, and J.F. Scott Multiferroic and magnetoelectric materials Nature 442 2006 759 765 (Pubitemid 44261898)
10. B. Xu, J. Lü, and R. Cao Anion-assisted structural variation of cadmium coordination polymers: from 2D → 3D inclined polycatenation to 2D → 3D polythreading Cryst. Growth Des. 9 2009 3003 3005
11. B. Xu, Z.J. Lin, L.W. Han, and R. Cao From 2D → 3Dinclined polycatenation to 2D → 3D parallel polycatenation: a central metal cationic induce strategy CrystEngComm 13 2011 440 443
12. B. Xu, H.X. Yang, J.X. Lin, X.D. Zhu, T.F. Liu, and R. Cao Crystal structures and luminescent properties of two cadmium complexes containing the N,N′- bis - (4-pyridyl-methyl) piperazine ligand J. Mol. Struct. 938 2009 316 321
13. -1): 3408 (s, br), 3244 (m), 2945 (m), 2827 (m), 1619 (vs), 1566 (s), 1420 (s), 1374 (s), 1327 (s), 1227 (m), 1134 (m), 1087 (m), 999 (m), 799 (m), 729 (w), 599 (w).
14. 2 = 0.1770. X-ray single crystal diffraction data collection of 1 was performed on a Rigaku Mercury CCD. The structure was solved by direct methods and refined with full-matrix least-squares technique (SHELXTL-97) [11]. All non-hydrogen atoms were treated anisotropically. The positions of the hydrogen atoms attached to carbon atoms were generated geometrically. The idealized positions of the H atoms of water molecules were located from Fourier difference maps and refined isotropically (O-H bond fixed at 0.85 A°). The crystal quality of 2 was very poor, and it is not suitable for X-ray single crystal diffraction data collection. The X-ray powder diffraction analysis, elemental analysis, TG and IR analysis confirm that 1 and 2 are isomorphous.
15. V.A. Blatov IUCr, Comput. Comm. Newslett 7 2006 4 see also http://www.topos.ssu.samara.ru
16. M.H. Zeng, Y.L. Zhou, M.C. Wu, H.L. Sun, and M. Du A unique cobalt(II)-based molecular magnet constructed of hydroxyl/carboxylate bridges with a 3D pillared-layer motif Inorg. Chem. 49 2010 6436 6442
17. Z.C. Zhang, and L.M. Zheng A layered cobalt phosphonate exhibiting ferrimagnetism and slow magnetic relaxation Inorg. Chem. Comm. 11 2008 1243 1245
18. O. Sengupta, and P.S. Mukherjee Mixed azide and 5-(Pyrimidy)tetrazole bridged Co(II)/Mn(II) polymers: synthesis, crystal structures, ferroelectric and magnetic behavior Inorg. Chem. 49 2010 8583 8590
19. K.C. Mondal, G.E. Kostakis, Y. Lan, C.E. Anson, and A.K. Powell Spin-canting and metamagnetic behavior in a new species from the hydrothermal Co(II)-trans-3-Pyridylacrylate system Inorg. Chem. 48 2009 9205 9213
20. Y.M. Legrand, A. Lee, N. Masquelez, P. Rabu, and M. Barboiu Temperature induced single-crystal-to-single-crystal transformations and structure directed effects on magnetic properties Inorg. Chem. 46 2007 9083 9089
21. A.M.P. Peedikakkal, Y.M. Song, R.G. Xiong, S. Gao, and J.J. Vittal Cobalt(II) coordination polymers containing trans-1,2-Bis(4-pyridyl)ethene and their magnetic properties Eur. J. Inorg. Chem. 2010 3856 3865
22. G.M. Sheldrick SHELXS-97, Program for Crystal Structure Solution and Refinement 1997 University of Göttingen Germany