Application of bifunctional ionic liquid extractants [A336][CA-12] and [A336][CA-100] to the lanthanum extraction and separation from rare earths in the chloride medium

Industrial and Engineering Chemistry Research

Volumn 50, Issue 12, 2011, Pages 7534-7541

  Wang, Wei ^a,b   Yang, Hualing ^a,b   Cui, Hongmin ^a,b   Zhang, Dongli ^a,b   Liu, Yu ^a   Chen, Ji ^a  

^a CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS PHASE; BIFUNCTIONAL; EXTRACTANTS; EXTRACTION EFFICIENCIES; EXTRACTION MECHANISMS; EXTRACTION SYSTEMS; LANTHANUM EXTRACTION; ORGANIC PHASE; RECYCLING EXPERIMENTS; SALT CONCENTRATION; SEPARATION FACTORS; TRI-N-BUTYL PHOSPHATE;

ACETIC ACID; CHLORINE COMPOUNDS; IONIC LIQUIDS; PH EFFECTS; RARE EARTHS; RECYCLING;

EXTRACTION;

EID: 79958808107     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie2001633     Document Type: Article

References (33)

1. Maestro, P.; Huguenin, D. Industrial Applications of Rare-earths - Which Way for the End of the Century? J. Alloys Compd. 1995, 225, 520
2. Kanazawa, Y.; Kamitani, M. Rare Earth Minerals and Resources in the World J. Alloys Compd. 2006, 408, 1339
3. 3+ Waste of Oil Shale Ash (Fe-Al-OSA) Ind. Eng. Chem. Res. 2010, 49, 11645
4. Singh, D.; Singh, H.; Mathur, J. Extraction of Rare Earths and Yttrium with High Molecular Weight Carboxylic Acids Hydrometallurgy 2006, 81, 174
5. Atanassova, A.; Jordanov, V.; Dukov, I. L. Effect of the Quaternary Ammonium Salt Aliquat 336 on the Solvent Extraction of Lanthanoid (III) Ions with Thenoyltrifluoroacetone Hydrometallurgy 2002, 63, 41
6. Cheng, C. Y. Purification of Synthetic Laterite Leach Solution by Solvent Extraction using D2EHPA Hydrometallurgy 2000, 56, 369
7. Wu, D. B.; Li, W.; Li, D. Q.; Xiong, Y. The Extraction and Separation of Ho, Y, and Er(III) with the Mixtures of Cyanex 302 and another Organic Extractant Sep. Sci. Technol. 2007, 42, 847
8. Zhang, X.; Yin, G.; Hu, Z. Extraction and Separation of Gallium, Indium and Thallium with Several Carboxylic Acids from Chloride Media Talanta 2003, 59, 905
9. Ohto, K.; Nakagawa, H.; Furutsuka, H.; Shinohara, T.; Nakamura, T.; Oshima, T.; Inoue, K. Solvent Extraction of Rare Earths with a Novel Phosphonate Extractant Providing a Narrow Coordination Site Solvent Extr. Res. Dev., Jpn. 2004, 11, 121
10. Li, W.; Wang, X.; Meng, S.; Li, D. Q.; Xiong, Y. Extraction and Separation of Yttrium from the Rare Earths with Sec-octylphenoxy Acetic Acid in Chloride Media Sep. Purif. Technol. 2007, 54, 164
11. Xu, G. Rare Earths; Metallurgical Industry Press: Beijing, 1995.
12. Tundo, P.; Esposito, V. Green Chemical Reactions. In An Introduction to Green Chemistry; Black, D.; St., C., Eds.; Springer: Dordrecht, 2006.
13. Luo, H.; Dai, S.; Bonnesen, P.; Buchananiii, A. Separation of Fission Products Based on Ionic Liquids: Task-specific Ionic Liquids Containing an Aza-crown Ether Fragment J. Alloys Compd. 2006, 418, 195
14. + Based on Room-temperature Ionic Liquids Containing Monoaza-substituted Crown Ethers Anal. Chem. 2004, 76, 2773
15. Visser, A. E.; Swatloski, R. P.; Reichert, W. M.; Davis, J. H., Jr; Rogers, R. D.; Mayton, R.; Sheff, S.; Wierzbicki, A. Task-specific Ionic Liquids for the Extraction of Metal Ions from Aqueous Solutions Chem. Commun. 2001, 135
16. Han, X.; Armstrong, D. W. Ionic Liquids in Separations Acc. Chem. Res. 2007, 40, 1079
17. Ouadi, A.; Klimchuk, O.; Gaillard, C.; Billard, I. Solvent Extraction of U(vi) by Task Specific Ionic Liquids Bearing Phosphoryl Groups Green Chem. 2007, 9, 1160
18. Egorov, V. M.; Djigailo, D. I.; Momotenko, D. S.; Chernyshov, D. V.; Torocheshnikova, I. I.; Smirnova, S. V.; Pletnev, I. V. Task-specific Ionic Liquid Trioctylmethylammonium Salicylate as Extraction Solvent for Transition Metal Ions Talanta 2010, 80, 1177
19. Davis, H. J. J. Task-Specific Ionic Liquids Chem. Lett. 2004, 33, 1072
20. Sun, X. Q.; Ji, Y.; Liu, Y.; Chen, J.; Li, D. Q. An Engineering-Purpose Preparation Strategy for Ammonium-Type Ionic Liquid with High Purity AlChE J. 2010, 56, 989
21. Sun, X.; Ji, Y.; Hu, F.; He, B.; Chen, J.; Li, D. Q. The Inner Synergistic Effect of Bifunctional Ionic Liquid Extractant for Solvent Extraction Talanta 2010, 81, 1877
22. Mikkola, J. P.; Virtanen, P.; Sojholm, R. Aliquat 336((R)) - a Versatile and Affordable Cation Source for an Entirely New Family of Hydrophobic Ionic Liquids Green Chem. 2006, 8, 250
23. Güell, R.; Fontàs, C.; Salvadó, V.; Anticó, E. Modelling of Liquid-Liquid Extraction and Liquid Membrane Separation of Arsenic Species in Environmental Matrices Sep. Purif. Technol. 2010, 72, 319
24. Belova, V. V.; Voshkin, A. A.; Kholkin, A. I.; Payrtman, A. K. Solvent Extraction of some Lanthanides from Chloride and Nitrate Solutions by Binary Extractants Hydrometallurgy 2009, 97, 198
25. Wang, Y. G.; Xiong, Y.; Meng, S. L.; Li, D. Q. Separation of Yttrium from Heavy Lanthanide by CA-100 using the Complexing Agent Talanta 2004, 63, 239
26. Nagaosa, Y.; Yao, B. H. Recovery and Separation of Lanthanum(III), Aluminum(III), Cobalt(II), and Nickel(II) from Misch Metal by Solvent Extraction using Bis(2-ethylhexyl)phosphinic Acid Sep. Sci. Technol. 1997, 32, 1053
27. Meher, L. C.; Dharmagadda, V. S. S.; Naik, S. N. Optimization of Alkali-catalyzed Transesterification of Pongamia Pinnata Oil for Production of Biodiesel Bioresour. Technol. 2006, 97, 1392
28. Liu, Y. H.; Zhu, L. L.; Sun, X. Q.; Chen, J. Toward Greener Separations of Rare Earths: Bifunctional Ionic Liquid Extractants in Biodiesel AlChE J. 2010, 56, 2338
29. Spear, S. K.; Griffin, S. T.; Granger, K. S.; Huddleston, J. G.; Rogers, R. D. Renewable Plant-based Soybean Oil Methyl Esters as Alternatives to Organic Solvents Green Chem. 2007, 9, 1008
30. Ritcey, G. Solvent Extraction in Hydrometallurgy: Present and Future Tsinghua Sci. Technol. 2006, 11, 137
31. Syzova, N.; Eyal, A.; Vitner, A.; Hazan, B. Extraction of Carboxylic Acids by ABC Extractants: Effects of Temperature, the Polarity of the Diluent, and the Ratio Between Extractant Components Solvent Extr. Ion Exch. 2004, 22, 69
32. Dukov, I. L.; Atanassova, M. Effect of the Diluents on the Synergistic Solvent Extraction of some Lanthanides with Thenoyltrifluoroacetone and Quaternary Ammonium Salt Hydrometallurgy 2003, 68, 89
33. Shen, C. L.; Xie, Y. F.; Li, D. Q. Process for Separation of Mixed Rare-Earths by Ammoniated EHEHPA. China Patent 85102210A, 1986.