A novel phosphoric acid loaded quaternary 1,4-diazabicyclo-[2.2.2]-octane polysulfone membrane for intermediate temperature fuel cells

International Journal of Hydrogen Energy

Volumn 36, Issue 14, 2011, Pages 8550-8556

  Wang, Xu ^a   Xu, Chenxi ^a   Golding, Bernard T ^a   Sadeghi, Masih ^a   Cao, Yuancheng ^a   Scott, Keith ^a  

^a NEWCASTLE UNIVERSITY   (United Kingdom)

Author keywords

Chloromethylation; DABCO; Fuel cell; Phosphoric acid loaded membrane; Polysulfone; Quaternization

Indexed keywords

CHLOROMETHYLATION; DABCO; DEGREE OF SUBSTITUTION; DEGREES OF SUBSTITUTION; FT-IR SPECTRUM; FUEL CELL PERFORMANCE; FUEL CELL TESTS; HIGH POWER OUTPUT; INTERMEDIATE-TEMPERATURE FUEL CELLS; LOW DEGREE; POLYMER STRUCTURE; POLYSULFONE MEMBRANES; POTENTIAL APPLICATIONS; QUATERNIZATION;

ATMOSPHERIC PRESSURE; FUEL CELLS; MEMBRANES;

PHOSPHORIC ACID;

EID: 79958126272     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.03.143     Document Type: Article

References (15)

1. Q. Li, R. He, J.O. Jensen, and N.J. Bjerrum PBI-based polymer membranes for high temperature fuel cells - preparation, characterization and fuel cell demonstration Fuel Cells 4 3 2004 147 159
2. 4 composite membrane for proton-exchange membrane fuel cells operating at high temperature J Power Sources 183 1 2008 69 75
3. S. Yul Oh, T. Yoshida, G. Kawamura, H. Muto, M. Sakai, and A. Matsuda Inorganic-organic composite electrolytes consisting of polybenzimidazole and Cs-substituted heteropoly acids and their application for medium temperature fuel cells J Mater Chem 20 2010 6359 6366
4. J. Lobato, Pablo Cãnizares, Manuel A. Rodrigo, Diego Ubeda, and F. Javier Pinar A novel titanium PBI-based composite membrane for high temperature PEMFCs J Membr Sci 369 2011 105 111
5. S.M.J. Zaidi, S.D. Mikhailenko, G.P. Robertson, M.D. Guiver, and S. Kaliaguine Proton conducting composite membranes from polyether ether ketone and heteropolyacids for fuel cell applications J Membr Sci 173 1 2000 17 34 (Pubitemid 30229834)
6. D. Xing, and J. Kerres Improvement of synthesis procedure and characterization of sulfonated poly(arylene ether sulfone) for proton exchange membranes J New Mater Electrochem Syst 9 1 2006 51 60 (Pubitemid 44933700)
7. D. Xing, G. He, Z. Hou, P. Ming, and S. Song Preparation and characterization of a modified montmorillonite/sulfonated polyphenylether sulfone/PTFE composite membrane Int J Hydrogen Energy 36 3 2011 2177 2183
8. 4 for high-temperature PEMFC operation Electrochem Solid-State Lett 9 2 2006 A60 A63
9. 4 composite membrane for phosphoric acid polymer electrolyte membrane fuel cells J Power Sources 194 2 2009 811 814
10. M. Li, and K. Scott A polytetrafluoroethylene/quaternized polysulfone membrane for high temperature polymer electrolyte membrane fuel cells J Power Sources 196 2010 1894 1898
11. E. Avram, E. Butuc, C. Luca, and I. Druta Polymers with pendant functional group. III. Polysulfones containing viologen group J Macromol Sci. Part A Pure Appl Chem 34 9 1997 1701 1714 (Pubitemid 127561311)
12. T. Sousa, M. Mamlouk, and K. Scott A dynamic non-isothermal model of a laboratory intermediate temperature fuel cell using PBI doped phosphoric acid membranes Int J Hydrogen Energy 35 21 2010 12065 12080
13. S. Gu, R. Cai, T. Luo, Z. Chen, M. Sun, and Y. Liu A soluble and highly conductive ionomer for high-performance hydroxide exchange membrane fuel cells Angew Chem. Int Ed 48 35 2009 6499 6502
14. B.P. Tripathi, M. Kumar, and V.K. Shahi Organic-inorganic hybrid alkaline membranes by epoxide ring opening for direct methanol fuel cell applications J Membr Sci 360 1-2 2010 90 101
15. 2 reduction on a Pt electrode covered with a thin film of solid polymer electrolyte J Electrochem Soc 144 9 1997 2973 2982 (Pubitemid 127591647)