Iron(III) extraction from Phosphoric Acid solutions by cyanex 301

Solvent Extraction and Ion Exchange

Volumn 29, Issue 3, 2011, Pages 337-362

  Ocio, A ^a   Elizalde, M P ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

Activity coefficients; Bis(244 trimethylpentyl)dithiophosphinic acid; Iron; Phosphoric acid

Indexed keywords

ACID CONCENTRATIONS; AQUEOUS SPECIES; BIS(244-TRIMETHYLPENTYL)DITHIOPHOSPHINIC ACID; CYANEX-301; EXPERIMENTAL DATA; EXTRACTION CONSTANTS; INFINITE DILUTION; NUMERICAL TREATMENTS;

EQUILIBRIUM CONSTANTS; IONIC STRENGTH; IRON COMPOUNDS; STOICHIOMETRY; TOLUENE;

PHOSPHORIC ACID;

EID: 79957865131     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366299.2011.573431     Document Type: Article

References (55)

1. Hurst, F. J.; Crouse, D. J. Recovery of uranium from wet-process phosphoric acid by extraction with octylphenylphosphoric acid. Ind. Eng. Chem., Process Des. Develop. 1974, 13(3), 286-291.
2. Bock, J.; Valint, P. L. Uranium extraction from wet process phosphoric acid. A liquid membrane approach. Ind. Eng. Chem. Fundam. 1982, 21, 417-422.
3. Silem, A.; Boualia, A.; Mellah, A. The effect of raw and sulfonated kerosene-type diluent on the solvent extraction of uranium and coextractable impurities from solutions. Part 2. Industrial phosphoric acid. Hydrometallurgy 1990, 24, 11-17.
4. Hinojosa Reyes, L.; Saucedo Medina, I.; Navarro Mendoza, R.; Revilla Vázquez, J.; Ávila Rodríguez, M.; Guibal, E. Extraction of cadmium from phosphoric acid using resins impregnated with organophosphorus extractants. Ind. Eng. Chem. Res. 2001, 40, 1422-1433.
5. Haberman, N. Extraction of Iron(III) from concentrated phosphoric acid. Anal. Chem. 1964, 36, 1876-1877.
6. Sato, T.; Nakamura, T. Extraction of Iron(III) from sulphuric and hydrochloric acid solutions by di-(2-ethylhexyl)phosphoric acid. In Solvent Extraction, Proceedings of the International Solvent Extraction Conference; Gregory, J.G., Ed.; pp 238-248.
7. Islam, F.; Rahman, H.; Ali, M. Solvent extraction separation study of Ti(IV) Fe(III) and Fe(II) from aqueous solutions with di-2- ethylhexylphosphoric acid in benzene. J. Inorg. Nucl. Chem. 1979, 41, 217-221.
8. Martínez, M.; Miralles, N.; Sastre, A. M.; Herranz, C. Comparative study of mono(n-octyl)phosphinic and di(n-octyl)phosphinic acids as metal extractants. Hydrometallurgy 1993, 33, 95-106.
9. Nagaosa, Y.; Binghua, Y. Extraction equilibria of some transition metal ions by bis(2-ethylhexyl)phosphinic acid. Talanta 1997, 44, 327-337.
10. Miralles, N.; Sastre, A.M.; Figuerola, E.; Martínez, M. Solvent extraction of Iron(III) by bis(2, 4, 4-trimethylpentyl)phosphinic acid: Experimental equilibrium study. Hydrometallurgy 1992, 31, 1-12.
11. 3+. Ind. Eng. Chem. Res. 2007, 46, 5707-5714.
12. Biswas, R. K.; Habib, M. A.; Karmakar, A. K. Kinetics of solvent extraction of Iron(III) from sulphate medium by purified Cyanex 272 using a Lewis cell. Solvent Extr. Ion Exch. 2007, 25, 79-98.
13. Facon, S.; Ávila Rodríguez, M.; Cote, G.; Bauer, D. General properties of bis(2, 4, 4-trimethylpentyl)dithiophosphinic acid (CYANEX 301) in acidic liquid-liquid extraction systems, Proceedings of the International Solvent Extraction Conference ISEC 1993; Logsdail, D.H.; Slater, M.J. Eds.; pp 557-564.
14. Panesar, K. S.; Singh, O. V.; Tandon, S. N. Liquid-liquid extraction and reversed phase chromatographic behavior of some 3d metal ions using bis(2, 4, 4-trimethylpentyl)dithiophosphinic acid (CYANEX 301). Talanta 1994, 41(8), 1341-1344.
15. Wang, C.; Li, D. Solvent extraction of Sc(III), Zr(IV), Th(IV), Fe(III) and Lu(III) with thiosubstituted organophosphinic acid extractants. Solvent Extr. Ion Exch. 1995, 13(3), 503-523.
16. Ajgaonkar, H. S.; Dhadke, P. M. Solvent extraction separation of iron(III) and aluminium(III) from other elements with CYANEX 302, Talanta 1997, 44, 563-570.
17. Chen, J.; Jiao, R.; Zhu, Y. The extraction of Tc(VII), Fe(III), Ru(II), Pd(II) and Mo(VI) from nitric acid solution by bis(2,4,4- trimethylpentyl)dithiophosphinic acid (HBTMPDTP). Radiochim. Acta. 1999, 86, 151-154.
18. Bartkovska, M.; Regel-Rosocka, M.; Szymanowski, J. Extraction of Zinc(II), Iron(III) and Iron(II) with binary mixtures containing tributylphosphate and di(2-ethylhexyl)phosphoric acid or Cyanex 302. Fizykochemiczne Problemi Mineralurgii. 2002, 36, 217-224.
19. Van de Voorde, I.; Pinoy, L.; Courtijn, E.; Verpoort, F. Influence of acetate ions and the role of the diluents on the extraction of Copper(II), Nickel(II), Cobalt(II), Magnesium(II) and Iron (II, III) with different types of extractants. Hydrometallurgy 2005, 78, 92-106.
20. Almela, A.; Elizalde, M.P.; Gómez, J.M. Cadmium (II) extraction from phosphoric media by bis(2, 4, 4-trimethylpentyl)thiophosphinic acid (CYANEX 302). Fluid Phase Equilib. 1998, 145, 301-310.
21. Almela, A.; Elizalde, M.P. Correlation of the extraction constants of the system Cd(II)-H3PO4/CYANEX 302-kerosene at different ionic strengths. Fluid Phase Equilib. 1998, 153, 243-249.
22. Menoyo, B.; Elizalde, M.P.; Almela, A. Extraction of lead by CYANEX 302 from phosphoric acid media. Solvent Extr. Ion Exch. 2001, 19(4), 677-698.
23. Menoyo, B.; Elizalde, M. P. Extraction of Lead(II) by Cyanex 302 and Cyanex 301 from 2.19 M Phosphoric Acid Medium. Proceedings of the International Solvent Extraction Conference, Barcelona, Spain, 1999, pp 1227-1232.
24. Ocio, A.; Elizalde, M. P. Zinc(II) Extraction from phosphoric media by bis(2, 4, 4-trimethylpentyl)-dithiophosphinic acid (CYANEX 301). Solvent Extr. Ion Exch. 2003, 21(2), 259-271.
25. Ocio, A.; Almela, A.; Elizalde, M. P. Cadmium(II) Extraction from phosphoric media by bis(2, 4, 4-trimethylpentyl)dithiophosphinic acid (CYANEX 301). Solvent Extr. Ion Exch. 2004, 22, 961-977.
26. Ocio, A.; Elizalde, M. P. Correlation of the extraction constant values of Zn(II) and Cd(II) from phosphoric acid media by Bis(2, 4, 4 - trimethylpentyl)dithiophosphinic acid dissolved in toluene. J. Sol. Chem. (Submitted).
27. Galal-Gorchev, H.; Stumm, W. The reaction of ferric iron with orthophosphate. J. Inorg. Nucl. Chem. 1963, 25, 567-574.
28. Sidorenko, V. I.; Zhuravlev, E. F.; Gordienko, V. I.; Grineva, N. P. Amperometric study of complexing of iron(3+) ions with phosphoric acid in perchloric acid solutions. Zhurg. Neorg. Khim. 1973, 18, 1270-1273.
29. Wilhelmy, R.; Patel, R.; Matijevic, E. Thermodynamics and kinetics of aqueous ferric phosphate complex formation. Inorg. Chem. 1985, 24, 3290-3297.
30. Ciavatta, L.; Iuliano, M. On the Formation of mononuclear Iron(III)- orthophosphate complexes. Ann. Chim. (Rome) 1995, 85, 235-255.
31. Anon. CYANEX 272, CYANEX 301 and CYANEX 302. Technical Brochures. American Cyanamid Company: Wayne, NJ, 1990.
32. Menoyo, B.; Elizalde, M.P. Composition of Cyanex 301 by gas chromatography - mass spectrometry. Solvent Extr. Ion Exch. 2002, 20, 35-47.
33. Sole, K. C.; Hiskey, J. B. Solvent exraction of copper by Cyanex 272, Cyanex 302 and Cyanex 301. Hydrometallurgy 1995, 37, 129-147.
34. Cavell, R. G.; Day, E. D.; Byers, W.; Watkins, P. M. Metal complexes of substituted dithiophosphinic acids. V. Complexes of manganese, iron and cobalt. Inorg. Chem. 1971, 11, 1759-1772.
35. Mukherjee, R. N.; Shankar, S.; Vijaya, V. S.; Gogoi, P. K. Dithiophosphinates of trivalent iron, ruthenium and osmium. Polyhedron 1985, 4, 1717-1719.
36. Skoog, D. A.; West, D. M.; Holler, F.J. Fundamentos en Química Analítica, Vol 2; Reverté: Barcelona, 2001; p 565.
37. Menoyo, B.; Elizalde, M. P.; Almela, A. Determination of the degradation compounds formed by the oxidation of thiophosphinic acids and phosphine sulfides with nitric acid. Anal. Sci. 2002, 18, 799-804.
38. Kuchen, W.; Hertel, H. Metal complexes of thiophosphinic and selenophosphinic acids. Angew. Chem. 1969, 8(2), 89-97.
39. Calligaris, M.; Ciana, A.; Meriani, S.; Nardin, G.; Randacio, L.; Ripamonti, A. Structure and polymeric nature of Zinc(II) and Cobalt(II) phosphinotionates. J. Chem. Soc. (A). 1970, 3386-3392.
40. Tijoe, T.T.; Durville, P.F.M.; van Rosmalen, G.M. Extraction of cadmium from phosphoric acid with diorganyldithiophosphinic acids. Part I. Equilibrium data. Solvent Extr. Ion Exch. 1989, 7(3), 435-459.
41. Tait, B.K. Cobalt-Nickel separation: The extraction of Cobalt (II) and Nickel (II) by CYANEX 301, CYANEX 302 and CYANEX 272. Hydrometallurgy 1993, 32, 365-372.
42. Elmore, K. L.; Hatfield, J. D.; Dunn, R. L.; Jones, A. D. Dissociation of phosphoric acid solutions at 25◦C. The Journal of Physical Chemistry 1965, 69(10), 3520-3525.
43. Bromley, L. A. Thermodinanic properties of strong electrolytes in aqueous solutions. AIChE J. 1973, 19(2), 313-320.
44. Whitfield, M. In Activity Coefficients in Electrolyte Solutions; Pytkowicz, R. M., Ed.; CRC Press: Boca Raton, FL, 1979; Vol. 2, Chapter 3.
45. Belaustegi, Y.; Olazabal, M. A.; Madariaga, J. M. Development of a Modified Bromley's Methodology for the estimation of ionic media effects on solution equilibria. Part 4. The chemical model of Fe (III) with the halide ligands in aqueous solution at 25°C. Fluid Phase Equilib. 1999, 155, 21-31.
46. Davies, C. W. The extent of dissociation of salts in water. Part VIII. An equation for the mean ionic activity coefficient of an electrolyte in water, and a revision of the dissociation constants of some sulphates. J. Chem. Soc. 1938, 2093-2098.
47. Ocio, A.; Elizalde M. P. Correlation of the extraction constant values of Cu(II) by 5-dodecylsalicylaldoxime from phosphoric acid media. Fluid Phase Equilib. 2009, 284, 144-149.
48. Borge, G.; Etxebarria, N.; Fernández, L. A.; Olazabal, M. A.; Madariaga, J. M. Development of aModified Bromley's Methodology (MBM) for the estimation of ionic media effects on solution equilibria. Part 2. Correlation of the molar and molal interaction parameters with the charge and crystal radii of the ions. Fluid Phase Equilibria 1996, 121, 99-109.
49. Christensen, J. H.; Reed, R. B. Design and analysis data. Density of aqueous solutions of phosphoric acid measurements at 25°C. Ind. Engn. Chem. 1955, 47, 1277-1280.
50. Liem, D.H. High-speed computers as a supplement to graphical methods. Acta Chem. Scand. 1971, 25, 1521-1534.
51. Elmore, K. L.; Mason, C. M.; Christensen, J. M. Activity of orthophosphoric acid in aqueous solution at 25◦C from vapour pressure measurements. J. Am. Chem. Soc. 1946, 68, 2528-2532.
52. Pashkov, G. L.; Grigorieva, N. A.; Pavlenko, N. I.; Fleitlikh, I. Y.; Nikiforova, L. K.; Pleshkov, M. A. Nickel (II) Extraction from sulphate media with bis (2,4,4-trimethylpentyl)dithiophosphinic acid dissolved in nonane. Solvent Extr. Ion Exch. 2008, 26, 749-763.
53. Caminiti, R.; Magini, M. An x-ray diffraction study on the first and the second hydration shell of the Fe(III) ion in nitrate solutions. Chem Phys. Lett. 1979, 6, 40-44.
54. Remsugnen, T.; Rode, B. M. QM/MM molecular dynamics simulation of the structure of hydrated Fe(II) and Fe(III) ions. J. Phys. Chem. A 2003, 107, 2324-2328.
55. Brown, J. D. On the geometry of O-H O hydrogen bonds. Acta Cryst. 1976, A32, 24-31.