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note
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-1): 3430(m), 2998(w), 2909(m), 1606(s), 1583(s), 1531(s), 1435 (s), 1367 (s), 1074(w), 814(w), 766 (m), 723 (s) (Fig. S2). The result can be reproduced well in parallel experiments.
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note
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Crystal data for 1: C28H16Pb2N4O10, crystal dimensions 0.32x0.28x0.22 mm3, Mr=982.80, monoclinic, space group C2/c, T=292 K, a=34.996(7) Å, b=10.856 (2) Å, c=14.849(3) Å, β=98.00(3)° V=5586(2) Å3, Z=8, Dc=2.328 Mg/m3, μ=12.106 mm-1, F(000) =3616, 5359 reflections collected, 4365 unique (Rint=0.0317). Final GOF=1.109, R1=0.0452 for 4365 observed reflections [I>2σ(I)], wR2=0.1095 for 5359 reflections, 397 parameters, 0 restraints. Single-crystal X-ray diffraction data for complex 1 were recorded on a Rigaku RAXIS-RAPID diffractometer with graphite-monochromated Mo Kα radiation (λ=0.71073 Å) using the ω scan technique. All the structures were solved by direct methods using the program SHELXS-97 (G. M. Sheldrick, SHELXS-97, Programs for X-ray Crystal Structure Solution, University of Göttingen, Germany, 1997.) and refined by fullmatrix least-squares techniques against F2 using the SHELXTL-97 crystallographic software package(G. M. Sheldrick, SHELXL-97, Programs for X-ray Crystal Structure Refinement, University of Göttingen, Germany, 1997).
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