Hydrogen permeation through the Pd-Nb-Pd composite membrane: Surface effects and thermal degradation

International Journal of Hydrogen Energy

Volumn 36, Issue 13, 2011, Pages 7737-7746

  Alimov, Vasily N ^a   Hatano, Yuji ^b   Busnyuk, Andrei O ^a   Livshits, Daniil A ^c   Notkin, Mikhail E ^a   Livshits, Alexander I ^a  

^a Bonch Bruyevich University   (Russian Federation)

^b UNIVERSITY OF TOYAMA   (Japan)

^c INNOLUME GMBH   (Germany)

Author keywords

Composite membranes; Hydrogen separation; Niobium; Palladium

Indexed keywords

CLEAN SURFACES; CRITICAL ISSUES; DEGRADATION MECHANISM; HYDROGEN ENERGY; HYDROGEN ISOTOPE; HYDROGEN PERMEATION; HYDROGEN SEPARATION; INFINITE SELECTIVITY; LOWER PRESSURES; ORDERS OF MAGNITUDE; PERMEATION BEHAVIOR; PERMEATION EXPERIMENTS; PRESSURE RANGES; SURFACE CONTAMINATIONS; SURFACE EFFECT; THERMAL DEGRADATIONS; THERMAL STABILITY;

BEHAVIORAL RESEARCH; CHEMICAL STABILITY; COMPOSITE MEMBRANES; DEGRADATION; HYDROGEN; ISOTOPES; MEMBRANES; NIOBIUM; PALLADIUM; REACTION KINETICS;

PERMEATION;

EID: 79957598878     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.04.016     Document Type: Article

References (27)

1. 2S J Membr Sci 254 2005 49 62
2. T.A. Peters, M. Stange, H. Klette, and R. Bredesen High pressure performance of thin Pd-23%Ag/stainless steel composite membranes in water gas shift gas mixtures; influence of dilution, mass transfer and surface effects on the hydrogen flux J Membr Sci 316 2008 119 127 (Pubitemid 351614959)
3. T.A. Peters, W.M. Tucho, A. Ramachandran, M. Stange, J.C. Walmsleyc, and R. Holmestad Thin Pd-23%Ag/stainless steel composite membranes: long-term stability, life-time estimation and post-process characterization J Membr Sci 326 2009 572 581
4. A.I. Livshits, and M.E. Notkin Superpermeability of a niobium membrane with respect to hydrogen atoms and ions Sov Tech Phys Lett 7 1981 605 608
5. A.I. Livshits, M.E. Notkin, and A.A. Samartsev Physico-chemical origin of superpermeability - large-scale effects of surface chemistry on "hot" hydrogen permeation and absorption in metals J Nucl Mater 170 1990 74 94
6. 2 on the absorption and permeation in Nb of energetic hydrogen particles J Nucl Mater 178 1991 1 18
7. A.I. Livshits, F. Sube, M.E. Notkin, M.N. Soloviev, and M. Bacal Plasma driven suprerpermeation of hydrogen through group Va metals J Appl Phys 84 1998 2558 2564 (Pubitemid 128588866)
8. E. Fromm, and E. Gebhardt Gase und Kohlenstoff in Metallen 1976 Springer Berlin
9. A.A. Skovoroda, V.S. Svishchov, A.V. Spitsyn, V.L. Stolyarov, Yu.M. Pustovoit, and V.D. Borman Plasma-driven superpermeation of hydrogen through Nb membranes: bulk effects J Nucl Mater 306 2002 232 240 (Pubitemid 35437407)
10. Livshits AI, Yuchimchuk AA, Musyaev RK, Hatano Y, Samartsev AA, Busnyuk AO, et al. Selective pumping of D/T in fusion device exhausts by superpermeable membranes, 8th int. proceedings of conference on tritium science and technology; 2007 Sep 16-21; Rochester, USA.
11. T.S. Moss, N.M. Peachey, R.C. Show, and R.C. Dye Multilayer metal membranes for hydrogen separation Int J Hydrogen Energy 23 2 1998 99 106 (Pubitemid 128393365)
12. J.Y. Yang, C. Nishimura, and M. Komaki Preparation and characterization of Pd-Cu/V-15Ni composite membrane for hydrogen permeation J Alloys Compounds 431 2007 180 184 (Pubitemid 46330020)
13. T. Ozaki, Yi Zhang, M. Komaki, and C. Nishimura Preparation of palladium-coated V and V-15Ni membranes for hydrogen purification by electroless plating technique Int J Hydrogen Energy 28 2003 297 302 (Pubitemid 35465889)
14. 2C J Alloys Compounds 446-447 2007 539 542 (Pubitemid 47539037)
15. 2C intermediate layer Int J Hydrogen Energy 32 2007 615 619 (Pubitemid 46330625)
16. S.N. Paglieri, D.R. Pesirit, R.C. Dye, C.R. Tewell, R.C. Snow, and F.M. Smith Influence of surface coating on the performance of V-Cu, V-Ti, and Ta membranes for hydrogen separation F.T. Akin, Y.S. Lin, Proceedings of 8th international conference on inorganic membranes, 2004 July 18-22; Cincinnati, Ohio July 2004 Adams Press Chicago
17. T. Nozaki, Y. Hatano, E. Yamakawa, A. Hachikawa, and K. Ichinose Improvement of high temperature stability of Pd coating on Ta by HfN intermediate layer Int J Hydrogen Energy 35 22 2010 12454 12460
18. A.I. Livshits, and A.A. Samartsev Attaining of the extreme values of the adhesion and permeation probabilities in the system of hydrogen and a palladium membrane Sov Phys Tech Phys 49 1979 1365 1369
19. A.I. Livshits Interaction of a deuterium atomic beam with a palladium membrane Sov Phys Tech Phys 21 1976 848 854
20. A.I. Livshits Superpermeability of solid membranes and gas evacuation. Part I. theory Vacuum 29 1979 103 112
21. Y. Hatano, K. Watanabe, A.I. Livshits, A.O. Busnyuk, and V.N. Alimov Effects of bulk impurity concentration on the reactivity of metal surface: sticking of hydrogen molecules and atoms to polycrystalline Nb containing oxygen J Chem Phys 127 2007 204707 1-13
22. A.O. Busnyuk, M.E. Notkin, I.P. Grigoriadi, V.N. Alimov, and A.I. Lifshitz Thermal degradation of a palladium coating on hydrogen-tight niobium membranes Tech Phys 55 2010 117 124
23. Y. Murakami, and H. Othtsuka Possibility of palladium-alloy membrane pumps for thermonuclear fusion devices Vacuum 28 5 1978 235 240 (Pubitemid 8628140)
24. A.A. Samartsev Permeation of hydrogen through metal membranes in the low pressure range Kinet Catal 26 1985 703 712 (Pubitemid 16508514)
25. M.W. Roberts, and C.S. McKee Chemistry of the metal-gas interface 1978 Clarendon Press Oxford
26. A. Balovnev Yu Hydrogen diffusion in palladium at low pressures Zhurnal fizicheskoi khimii 43 10 1969 2461 2464
27. D.J. Edlund, and J. McCarthy The relationship between intermetallic diffusion and flux decline in composite-metal membranes: implications for achieving long membrane lifetime J Membr Sci 107 1995 147 153