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3 solution) was measured to be 76 ppb via ICP-MS. Other metal impurities found in low concentrations include: Al (25 ppb), Ba (1 ppb), and Pb (1 ppb)
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3 solution) was measured to be 76 ppb via ICP-MS. Other metal impurities found in low concentrations include: Al (25 ppb), Ba (1 ppb), and Pb (1 ppb).
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79957462289
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1H NMR spectroscopy revealed the presence of cis-stilbene, trans-stilbene (7%), a small amount of benzaldehyde (4%) and benzoic acid (<2%) as by-products
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1H NMR spectroscopy revealed the presence of cis-stilbene, trans-stilbene (7%), a small amount of benzaldehyde (4%) and benzoic acid (<2%) as by-products.
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43
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79957456966
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trans-Stilbene was found to be unreactive under the conditions described herein
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trans-Stilbene was found to be unreactive under the conditions described herein.
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44
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79957507125
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Under these conditions, we surmise that the increased yields of unfunctionalized stilbenes may be due to side reactions of GO with the functional groups present on the derivatives of cis-stilbene. The use of lower GO loadings or lower temperatures may minimize these side reactions, though such variations have not been exhaustively explored
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Under these conditions, we surmise that the increased yields of unfunctionalized stilbenes may be due to side reactions of GO with the functional groups present on the derivatives of cis-stilbene. The use of lower GO loadings or lower temperatures may minimize these side reactions, though such variations have not been exhaustively explored.
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47
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79957468959
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GO loadings of less than 200 wt % were found to be ineffective in the oxidation of the hydrocarbons bearing methyl or methylene groups shown in Table 4
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GO loadings of less than 200 wt % were found to be ineffective in the oxidation of the hydrocarbons bearing methyl or methylene groups shown in Table 4.
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48
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79957448571
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11
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11
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49
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79957450061
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23,26
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23,26
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50
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79957447058
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27 indicating the functionalized surface intrinsic to GO was necessary for the oxidation reaction to occur
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27 indicating the functionalized surface intrinsic to GO was necessary for the oxidation reaction to occur.
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28 in contrast to the 1,4 relationship in anthracene. Moreover, dehydrogenation of anthracene may be followed by the addition of water to the aromatized species, forming a dihydroxyl intermediate, which may then be oxidized to the dione
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28 in contrast to the 1,4 relationship in anthracene. Moreover, dehydrogenation of anthracene may be followed by the addition of water to the aromatized species, forming a dihydroxyl intermediate, which may then be oxidized to the dione.
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For examples of selenium(IV) oxide and zinc dichromate used in stilbene oxidations, see Ref. 18. For examples of manganese-containing species and cerium salts used in diarylmethylene oxidations, see
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