Variant luminescence from an organic-inorganic hybrid structure with an isolated 4-ring zinc phosphate tecton

Angewandte Chemie - International Edition

Volumn 50, Issue 23, 2011, Pages 5319-5322

  Huang, Shu Hao ^a   Wang, Sue Lein ^a  

^a NATIONAL TSING HUA UNIVERSITY   (Taiwan)

Author keywords

luminescence; organic inorganic hybrid composites; phosphorus; structure activity relationships; zinc

Indexed keywords

ORGANIC-INORGANIC HYBRID; ORGANIC-INORGANIC HYBRID COMPOSITES; STRUCTURE ACTIVITY RELATIONSHIPS; ZINC PHOSPHATES;

HYBRID MATERIALS; PHOSPHORUS; ZINC; ZINC COMPOUNDS;

LUMINESCENCE;

EID: 79957515396     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201008230     Document Type: Article

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24. 4(btec)was separated out as a solid precipitate.
25. 2 was obtained by evaporating water.
26. After 10a was produced, we placed the crystals together with the filtrate into an acid digestion bomb and heated them hydrothermally at 200°C for one day. This treatment can transform 10a into 10d. Prolonged reaction time for 10a at 120°C or heating 10a in solvent or in the solid state at 200°C did not result in this transformation.
27. The results from quantum yield measurements indicated that 10d was the highest and 10c the second (ca. 7%).