UV initiated formation of polymer monoliths in glass and polymer microreactors

Sensors and Actuators, B: Chemical

Volumn 155, Issue 1, 2011, Pages 388-396

  Deverell, Jeremy A ^a,b   Rodemann, Thomas ^c   Smith, Jason A ^b   Canty, Allan J ^b   Guijt, Rosanne M ^a  

^a UNIVERSITY OF TASMANIA   (Australia)

^b UNIVERSITY OF TASMANIA   (Australia)

^c UNIVERSITY OF TASMANIA   (Australia)

Author keywords

Heterogenous catalysis; Lab on a Chip; Microreactor; Photoinitiated polymerisation; Polymer monolith; UV LED

Indexed keywords

HETEROGENOUS CATALYSIS; LAB ON A CHIP; MICRO-REACTOR; POLYMER MONOLITH; POLYMERISATION; UV LED;

CAPILLARITY; CATALYSIS; CHEMICAL REACTORS; FUSED SILICA; GLASS; ION CHROMATOGRAPHY; LIGHT EMITTING DIODES; LIGHT SOURCES; OLEFINS; ORGANIC POLYMERS; POLYMERIZATION;

MONOLITHIC INTEGRATED CIRCUITS;

EID: 79956371603     PISSN: 09254005     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.snb.2010.11.020     Document Type: Article

References (40)

1. H. Becker, and C. Gartner Polymer microfabrication technologies for microfluidic systems Analytical and Bioanalytical Chemistry 390 2008 89 111
2. K. Geyer, J.D.C. Codée, and P.H. Seeberger Microreactors as tools for synthetic chemists - the chemists' round-bottomed flask of the 21st century? Chemistry - A European Journal 12 2006 8434 8442 (Pubitemid 44807869)
3. W. Ehrfeld, V. Hessel, and H. Löwe Microreactors: New Technology for Modern Chemistry 2000 Wiley-VCH
4. P. Watts, and C. Wiles Recent advances in synthetic micro reaction technology Chemical Communications 2007 443 467 (Pubitemid 46155889)
5. B.P. Mason, K.E. Price, J.L. Steinbacher, A.R. Bogdan, and D.T. McQuade Greener approaches to organic synthesis using microreactor technology Chemical Reviews 107 2007 2300 2318 (Pubitemid 47029095)
6. M. Brivio, W. Verboom, and D.N. Reinhoudt Miniaturized continuous flow reaction vessels: influence on chemical reactions Lab on a Chip 6 2006 329 344 (Pubitemid 43327558)
7. J. Kobayashi, Y. Mori, and S. Kobayashi Multiphase organic synthesis in microchannel reactors Chemistry-an Asian Journal 1 2006 22 35 (Pubitemid 44384623)
8. R.L. Hartman, and K.F. Jensen Microchemical systems for continuous-flow synthesis Lab on a Chip 9 2009 2495 2507
9. M.W. Losey, M.A. Schmidt, and K.F. Jensen Microfabricated multiphase packed-bed reactors: characterization of mass transfer and reactions Industrial & Engineering Chemistry Research 40 2001 2555 2562 (Pubitemid 33010142)
10. S.J. Haswell, B. O'Sullivan, and P. Styring Kumada-Corriu reactions in a pressure-driven microflow reactor Lab on Chip 1 2001 164 166
11. M. Baumann, I.R. Baxendale, S.V. Ley, C.D. Smith, and G.K. Tranmer Fully automated continuous flow synthesis of 4,5-disubstituted oxazoles Organic Letters 8 2006 5231 5234 (Pubitemid 44861535)
12. M.W. Losey, R.J. Jackman, S.L. Firebaugh, M.A. Schmidt, and K.F. Jensen Design and fabrication of microfluidic devices for multiphase mixing and reaction Journal of Microelectromechanics System 11 2002 709 717
13. K.F. Bolton, A.J. Canty, J.A. Deverell, R.M. Guijt, E.F. Hilder, T. Rodemann, and J.A. Smith Macroporous monolith supports for continuous flow capillary microreactors Tetrahedron Letters 47 2006 9321 9324 (Pubitemid 44779704)
14. A. Gömann, J.A. Deverell, K.F. Munting, R.C. Jones, T. Rodemann, A.J. Canty, J.A. Smith, and R.M. Guijt Palladium-mediated organic synthesis using a porous polymer monolith formed in situ as a continuous catalyst support structure for application in microfluidic devices Tetrahedron 65 2009 1450 1454
15. R.C. Jones, A.J. Canty, J.A. Deverell, M.G. Gardiner, R.M. Guijt, T. Rodemann, J.A. Smith, and V.-A. Tolhurst Supported palladium catalysis using a heteroleptic 2-methylthiomethylpyridine -N,S- donor motif for Mizoroki-Heck and Suzuki-Miyaura coupling, including continuous organic monolith in capillary microscale flow-through mode Tetrahedron 65 2009 7474 7481
16. A.J. Canty, J.A. Deverell, A. Gömann, R.M. Guijt, T. Rodemann, and J.A. Smith Microfluidic devices for flow-through supported palladium catalysis on porous organic monolith Australian Journal of Chemistry 61 2008 630 633
17. F. Svec My favorite materials: porous polymer monoliths Journal of Separation Science 32 2009 3 9
18. C. Viklund, F. Svec, J.M.J. Fréchet, and K. Irgum Monolithic, "molded", porous materials with high flow characteristics for separations, catalysis, or solid-phase chemistry: Control of porous properties during polymerization Chemical Materials 8 1996 744 750 (Pubitemid 126482382)
19. Q.C. Wang, F. Svec, and J.M.J. Fréchet Hydrophilization of porous polystyrene-based continuous rod column Analytical Chemistry 67 1995 670 674
20. S.F. Xie, F. Svec, and J.M.J. Fréchet Preparation of porous hydrophilic monoliths: effect of the polymerization conditions on the porous properties of poly(acrylamide-co-N,N′-methylenebisacrylamide) monolithic rods Journal of Polymer Science, Part A, Polymer Chemistry 35 1997 1013 1021
21. M.R. Buchmeiser Polymeric monolithic materials: syntheses, properties, functionalization and applications Polymer 48 2007 2187 2198 (Pubitemid 46486745)
22. E.G. Vlakh, and T.B. Tennikova Preparation of methacrylate monoliths Journal of Separation Science 30 2007 2801 2813 (Pubitemid 350238310)
23. C. Yu, F. Svec, and J.M.J. Frechet Towards stationary phases for chromatography on a microchip: molded porous polymer monoliths prepared in capillaries by photoinitiated in situ polymerization as separation media for electrochromatography Electrophoresis 21 2000 120 127 (Pubitemid 30032704)
24. D.A. Mair, T.R. Schwei, T.S. Dinio, F. Svec, and J.M.J. Fréchet Use of photopatterned porous polymer monoliths as passive micromixers to enhance mixing efficiency for on-chip labeling reactions Lab on Chip 9 2009 877 883
25. W. Rutsch, K. Dietliker, D. Leppard, M. Kohler, L. Misev, U. Kolczak, and G. Rist Recent developments in photoinitiators Progress in Organic Coatings 27 1996 227 239 (Pubitemid 126398082)
26. T. Rohr, C. Yu, M.H. Davey, F. Svec, and J.M.J. Fréchet Porous polymer monoliths: simple and efficient mixers prepared by direct polymerization in the channels of microfluidic chips Electrophoresis 22 2001 3959 3967 (Pubitemid 33040214)
27. C. Yu, F. Svec, and J.M.J. Fréchet Towards stationary phases for chromatography on a microchip: molded porous polymer monoliths prepared in capillaries by photoinitiated in situ polymerization as separation media for electrochromatography Electrophoresis 21 2000 120 127 (Pubitemid 30032704)
28. S. Abele, F.Q. Nie, F. Foret, B. Paull, and M. Macka UV-LED photopolymerised monoliths Analyst 133 2008 864 866
29. W. Zarah, A.L. Pavel, J. Vijay, P. Brett, S. Frantisek, and M. Mirek Visible light initiated polymerization of styrenic monolithic stationary phases using 470 nm light emitting diode arrays Journal of Separation Science 33 2010 61 66
30. N.E. Leadbeater, and M. Marco Preparation of polymer-supported ligands and metal complexes for use in catalysis Chemical Reviews 102 2002 3217 3273
31. C. Yu, M.C. Xu, F. Svec, and J.M.J. Fréchet Preparation of monolithic polymers with controlled porous properties for microfluidic chip applications using photoinitiated free-radical polymerization Journal of Polymer Science, Part A, Polymer Chemistry 40 2002 755 769 (Pubitemid 34213227)
32. Z. Walsh, S. Abele, B. Lawless, D. Heger, P. Klan, M.C. Breadmore, B. Paull, and M. Macka Photoinitiated polymerisation of monolithic stationary phases in polyimide coated capillaries using visible region LEDs Chemical Communications 2008 6504 6506
33. M.C. Breadmore, and R.M. Guijt High intensity light emitting diode array as an alternative exposure source for the fabrication of electrophoretic microfluidic devices Journal of Chromatography A 1213 2008 3 7
34. N.S. Kenning, B.A. Ficek, C.C. Hoppe, and A.B. Scranton Spatial and temporal evolution of the photoinitiation rate for thick polymer systems illuminated by polychromatic light: selection of efficient photoinitiators for LED or mercury lamps Polymer International 57 2008 1134 1140
35. D.A. Mair, E. Geiger, A.P. Pisano, J.M.J. Fréchet, and F. Svec Injection molded microfluidic chips featuring integrated interconnects Lab on Chip 6 2006 1346 1354 (Pubitemid 44744300)
36. B. Rnby, W.T. Yang, and O. Tretinnikov Surface photografting of polymer fibers, films and sheets Nuclear Instruments & Methods in Physics Research Section B-Beam Interactions with Materials and Atoms 151 1999 301 305
37. T.B. Stachowiak, T. Rohr, E.F. Hilder, D.S. Peterson, M.Q. Yi, F. Svec, and J.M.J. Fréchet Fabrication of porous polymer monoliths covalently attached to the walls of channels in plastic microdevices Electrophoresis 24 2003 3689 3693 (Pubitemid 38089172)
38. T.B. Stachowiak, D.A. Mair, T.G. Holden, L.J. Lee, F. Svec, and J.M.J. Fréchet Hydrophilic surface modification of cyclic olefin copolymer microfluidic chips using sequential photografting Journal of Separation Science 30 2007 1088 1093 (Pubitemid 46824337)
39. J. Urban, S. Eeltink, P. Jandera, and P.J. Schoenmakers Characterization of polymer-based monolithic capillary columns by inverse size-exclusion chromatography and mercury-intrusion porosimetry Journal of Chromatography A 1182 2008 161 168
40. N. Karbass, V. Sans, E. Garcia-Verdugo, M.I. Burguete, and S.V. Luis Pd(0) supported onto monolithic polymers containing IL-like moieties. Continuous flow catalysis for the Heck reaction in near-critical EtOH Chemical Communications 2006 3095 3097 (Pubitemid 44106990)