Catalytic behavior of carbon supported Ni-B, Co-B and Co-Ni-B in hydrogen generation by hydrolysis of KBH4

Fuel Processing Technology

Volumn 92, Issue 8, 2011, Pages 1606-1610

  Xu, Dongyan ^a   Wang, Haizhen ^a   Guo, Qingjie ^a   Ji, Shengfu ^b  

^a QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^b BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY   (China)

Author keywords

Cobalt; Hydrogen generation; Hydrolysis; Nickel; Potassium borohydride

Indexed keywords

ALLOY FORMATION; BASIC MEDIUM; BOROHYDRIDES; CATALYTIC ACTIVITY; CATALYTIC BEHAVIOR; COMMERCIAL ACTIVATED CARBONS; HYDROGEN GENERATION; HYDROGEN GENERATIONS; MASS RATIO; METAL SALT; NAOH CONCENTRATION; NI METAL; NICKEL SALTS; REACTION PARAMETERS; REACTION TEMPERATURE; ROOM TEMPERATURE; SEM; SODIUM BOROHYDRIDES; XRD;

ACTIVATED CARBON; BORIDES; CATALYST ACTIVITY; COBALT; HYDROGEN; HYDROGEN PRODUCTION; HYDROLYSIS; INDUCTIVELY COUPLED PLASMA;

CATALYST SUPPORTS;

EID: 79956364550     PISSN: 03783820     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuproc.2011.04.006     Document Type: Article

References (31)

1. Z.T. Xia, and S.H. Chan Feasibility study of hydrogen generation from sodium borohydride solution for micro fuel cell applications J. Power Sources 152 2005 46 49
2. J.H. Wee, K.Y. Lee, and S.H. Kim Sodium borohydride as the hydrogen supplier for proton exchange membrane fuel cell systems Fuel Process. Technol. 87 2006 811 819 (Pubitemid 44131499)
3. E. Keçeli, and S. Özkar Ruthenium(III) acetylacetonate: a homogeneous catalyst in the hydrolysis of sodium borohydride J. Mol. Catal. A: Chem. 286 2008 87 91
4. 4-base hydrogen storage material using milling under low pressure hydrogen atmosphere J. Alloys Compd. 430 2007 350 355 (Pubitemid 46209704)
5. U.B. Demirci, and F. Garin Hydrogenation of unsaturated carboxylic acids on functional gel-type resin supported Pd catalysts: the effect of reactant structure J. Mol. Catal. A: Chem. 279 2008 56 72
6. S. Basu, A. Brockman, P. Gagare, Y. Zheng, P.V. Ramachandran, and W.N. Delgass Chemical kinetics of Ru-catalyzed ammonia borane hydrolysis, J.P. Gore J. Power Sources 188 2009 238 243
7. Y. Kojima, Y. Kawai, M. Kimbara, H. Nakanishi, and S. Matsumoto Hydrogen generation by hydrolysis reaction of lithium borohydride Int. J. Hydrogen Energy 29 2004 1213 1217
8. O. Akdim, U.B. Demirci, and P. Miele Acetic acid, a relatively green single-use catalyst for hydrogen generation from sodium borohydride Int. J. Hydrogen Energy 34 2009 7231 7238
9. D. Hua, Y. Hanxi, A. Xinping, and C. Chuansin Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst Int. J. Hydrogen Energy 28 2003 1095 1100
10. 4 solution Catal. Today 120 2007 305 310 (Pubitemid 46135916)
11. M. Zahmakiran, and S. Özkar Zeolite-confined ruthenium (0) nanoclusters catalyst: record catalytic activity, reusability, and lifetime in hydrogen generation from the hydrolysis of sodium borohydride Langmuir 25 2009 2667 2678
12. N. Patel, B. Patton, C. Zanchetta, R. Fernandes, G. Guella, A. Kale, and A. Miotello Pd-C powder and thin film catalysts for hydrogen production by hydrolysis of sodium borohydride Int. J. Hydrogen Energy 33 2008 287 292
13. J.C. Ingersoll, N. Mania, J.C. Thenmozhiyal, and A. Muthaiah Catalytic hydrolysis of sodium borohydride by a novel nickel-cobalt-boride catalyst J. Power Sources 173 2007 450 457 (Pubitemid 47500196)
14. B.H. Liu, and Z.P. Li A review: hydrogen generation from borohydride hydrolysis reaction J. Power Sources 187 2009 527 534
15. V.G. Minkina, S.I. Shabunya, V.I. Kalinin, V.V. Martynenko, and A.L. Smirnova Long-term stability of sodium borohydrides for hydrogen generation Int. J. Hydrogen Energy 33 2008 5629 5635
16. D.G. Tong, X. Han, W. Chu, H. Chen, and X.Y. Ji Preparation of mesoporous Co-B catalyst via self-assembled triblock copolymer templates Mater. Lett. 61 2007 4679 4682 (Pubitemid 47302489)
17. P. Krishnan, S.G. Advani, and A.K. Prasad Thin-film CoB catalyst templates for the hydrolysis of NaBH4 solution for hydrogen generation Appl. Catal. B: Environ. 86 2009 137 144
18. F.B. Su, L. Lv, F.Y. Lee, T. Liu, A.I. Cooper, and X.S. Zhao Thermally reduced ruthenium nanoparticles as a highly active heterogeneous catalyst for hydrogenation of monoaromatics J. Am. Chem. Soc. 129 2007 14213 14223 (Pubitemid 350171444)
19. J.A. Maciá-Agulló, B.C. Moore, D. Cazorla-Amorós, and A. Linares-Solano Influence of carbon fibres crystallinities on their chemical activation by KOH and NaOH Microporous Mesoporous Mater. 101 2007 397 405 (Pubitemid 46467502)
20. D.G. Tong, W. Chu, Y.Y. Luo, X.Y. Ji, and Y. He Preparation and characterization of Co-B flowers with mesoporous structure J. Mol. Catal. A: Chem. 265 2006 196 205
21. P. Kukula, V. Gabova, K. Koprivova, and P. Trtik Selective hydrogenation of unsaturated nitriles to unsaturated amines over amorphous CoB and NiB alloys doped with chromium Catal. Today 121 2007 27 38 (Pubitemid 46412215)
22. 4 solution with Cr-promoted Co-B amorphous catalyst Appl. Catal. B: Environ. 92 2009 68 74
23. 4 solution Int. J. Hydrogen Energy 32 2007 1749 1754 (Pubitemid 47260590)
24. 4 J. Mol. Catal. A: Chem. 298 2009 1 6
25. 4 solution Appl. Catal. B: Environ. 91 2009 368 379
26. B.H. Liu, Z.P. Li, and S. Suda Nickel- and cobalt-based catalysts for hydrogen generation by hydrolysis of borohydride J. Alloys Compd. 415 2006 288 293
27. L. Damjanović, S. Bennici, and A. Auroux A direct measurement of the heat evolved during the sodium and potassium borohydride catalytic hydrolysis J. Power Sources 195 2010 3284 3292
28. 4 solution using the high-performance Co-B catalyst J. Power Sources 144 2005 129 134
29. H.B. Dai, Y. Liang, L.P. Ma, and P. Wang New insights into catalytic hydrolysis kinetics of sodium borohydride from Michaelis-Menten model J. Phys. Chem. C 112 2008 15886 15892
30. Q. Zhang, Y. Wu, X. Sun, and J. Ortega Kinetics of catalytic hydrolysis of stabilized sodium borohydride solutions Ind. Eng. Chem. Res. 46 2007 1120 1124 (Pubitemid 46353286)
31. 4 solution using cobalt catalysts supported on modified activated carbon Int. J. Hydrogen Energy 33 2008 7371 7377