Proposed serum cholesterol reference measurement procedure by gas chromatography-isotope dilution mass spectrometry

Clinical Chemistry

Volumn 57, Issue 4, 2011, Pages 614-622

  Edwards, Selvin H ^a   Kimberly, Mary M ^a   Pyatt, Susan D ^a   Stribling, Shelton L ^b   Dobbin, Kara D ^b   Myers, Gary L ^a  

^a NATIONAL CENTER FOR ENVIRONMENTAL HEALTH   (United States)

^b BATTELLE MEMORIAL INSTITUTE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

5ALPHA CHOLESTEN 7 ENE 3BETA OL; 6 OXOCHOLESTANOL; CHOLEST 5EN 3BETA OL; ERGOSTEROL; LANOSTA 8,24 DIEN 3 OL; N,O BIS(TRIMETHYLSILYL)ACETAMIDE; POTASSIUM HYDROXIDE; SITOSTEROL; STEROL; UNCLASSIFIED DRUG;

ACCURACY; ARTICLE; BLOOD SAMPLING; CALIBRATION; CHOLESTEROL BLOOD LEVEL; CHOLESTEROL SYNTHESIS; CONTROLLED STUDY; CORRELATION COEFFICIENT; FREEZE DRYING; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; HUMAN; INTERMETHOD COMPARISON; ISOTOPE DILUTION ASSAY; LIPID ANALYSIS; LIQUID LIQUID EXTRACTION; MASS FRAGMENTOGRAPHY; MEASUREMENT; PH; REFERENCE MEASUREMENT PROCEDURE; REFERENCE VALUE; STANDARD;

CALIBRATION; CHOLESTEROL; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; HUMANS; REPRODUCIBILITY OF RESULTS;

EID: 79956094196     PISSN: 00099147     EISSN: 15308561     Source Type: Journal    
DOI: 10.1373/clinchem.2010.158766     Document Type: Article

References (28)

1. Abell LL, Levy BB, Brodie BB, Kendall FE. A simplified method for the estimation of total cholesterol in serum and demonstration of its specificity. J Biol Chem 1952;195:357-66.
2. Current status of blood cholesterol measurement in clinical laboratories in the United States: a report from the Laboratory Standardization Panel of the National Cholesterol Education Program. Clin Chem 1988;34:193-201.
3. Ellerbe P, Myers GL, Cooper GR, Hertz HS, Sniegoski LT, Welch MJ, White E. A comparison of results for cholesterol in human serum obtained by the reference method and by the definitive method of the National Reference System for cholesterol. Clin Chem 1990;36:370-5.
4. Wise SA, Watters RL. NIST certificate of analysis: standard reference material 1951b, lipids in frozen serum. https://www-s.nist.gov/srmors/view-cert. cfm?srm=1951B (Accessed October 2010).
5. Wise SA, Watters RL. NIST certificate of analysis: standard reference material 909b; lipids in frozen serum. https://www-s.nist.gov/srmors/view-cert. cfm?srm=909B (Accessed October 2010).
6. Bernert JT Jr, Akins JR, Cooper GR, Poulose AK, Myers GL, Sampson EJ. Factors influencing the accuracy of the national reference system total cholesterol reference method. Clin Chem 1991;37:2053-61. (Pubitemid 21925900)
7. Panteghini M. Traceability, reference systems and result comparability. Clin Biochem Rev 2007;28:97-104.
8. Tate J, Panteghini M. Standardisation: the theory and the practice. Clin Biochem Rev 2007;28:93-6.
9. Cohen A, Hertz HS, Mandel J, Paule RC, Schaffer R, Sniegoski LT, et al. Total serum cholesterol by isotope dilution/mass spectrometry: a candidate definitive method. Clin Chem 1980;26:854-60. (Pubitemid 11239393)
10. Ellerbe P, Meiselman S, Sniegoski LT, Welch MJ, White E. Determination of serum cholesterol by a modification of the isotope dilution mass spectrometric definitive method. Anal Chem 1989;61:1718-23. (Pubitemid 19204555)
11. Pelletier O, Wright LA, Breckenridge WC. Isotopedilution mass-spectrometry of serum-cholesterol with [3,4-C-13]cholesterol: proposed definitive method. Clin Chem 1987;33:1403-11.
12. Thienpont LM, Deleenheer AP, Stockl D, Reinauer H. Candidate reference methods for determining target values for cholesterol, creatinine, uric-acid, and glucose in external quality assessment and internal accuracy control. 2. Method transfer. Clin Chem 1993;39:1001-6.
13. Derks HJ, van Heiningen A, Koedam HC. Gas-chromatographic determination of cholesterol in serum: candidate reference method. Clin Chem 1985;31:691-4. (Pubitemid 16185945)
14. Chen WX, Li PY, Wang S, Dong J, Li JZ. Serum cholesterol determined by liquid chromatography with 6-chlorostigmasterol as internal standard. Clin Chem 1993;39:1602-7. (Pubitemid 23245987)
15. Siekmann L. Reference methods for total cholesterol and total glycerol. Eur J Clin Chem Clin Biochem 1991;29:277-9.
16. Siekmann L, Huskes KP, Breuer H. Determination of cholesterol in serum using mass fragmentography: a reference method in clinical chemistry. Z Anal Chem 1976;279:145-6.
17. Geistanger A, Arends S, Berding C, Hoshino T, Jeppsson JO, Little R, et al. Statistical methods for monitoring the relationship between the IFCC reference measurement procedure for hemoglobin A1c and the designated comparison methods in the United States, Japan, and Sweden. Clin Chem 2008;54:1379-85.
18. Weykamp C, John WG, Mosca A, Hoshino T, Little R, Jeppsson JO, et al. The IFCC reference measurement system for HbA1c: a 6-year progress report. Clin Chem 2008;54:240-8. (Pubitemid 351302616)
19. NCCLS. Preparation and validation of commutable frozen serum pools as secondary reference materials for cholesterol measurement procedures; approved guidelines. NCCLS document C37A, Wayne (PA): NCCLS; 1999.
20. IFCC. RELA: IFCC External Quality Assessment Scheme for Reference Laboratories in Laboratory Medicine. http://www.dgkl-rfb.de:81/ (Accessed December 2010).
21. Siekmann L. Determination of steroid hormones by the use of isotope dilution-mass spectrometry: a definitive method in clinical chemistry. J Steroid Biochem 1979;11:117-23. (Pubitemid 9234951)
22. Cooper GR, Smith SJ, Duncan IW, Mather A, Fellows WD, Foley T, et al. Interlaboratory testing of the transferability of a candidate reference method for total cholesterol in serum. Clin Chem 1986;32:921-9. (Pubitemid 17021149)
23. Ahmida HSM, Bertucci P, Franzo L, Massoud R, Cortese C, Lala A, Federici G. Simultaneous determination of plasmatic phytosterols and cholesterol precursors using gas chromatography-mass spectrometry (GC-MS) with selective ion monitoring (SIM). J Chromatogr B 2006;842:43-7. (Pubitemid 44311090)
24. Holick MF. Vitamin D deficiency. N Engl J Med 2007;357:266-81.
25. Miettinen TA, Tilvis RS, Kesaniemi YA. Serum plant sterols and cholesterol precursors reflect cholesterol absorption and synthesis in volunteers of a randomly selected male population. Am J Epidemiol 1990;131:20-31. (Pubitemid 20014696)
26. Hoelzel W, Weykamp C, Jeppsson JO, Miedema K, Barr JR, Goodall I, et al. IFCC reference system for measurement of hemoglobin A1c in human blood and the national standardization schemes in the United States, Japan, and Sweden: a method-comparison study. Clin Chem 2004;50:166-74. (Pubitemid 38125714)
27. EURACHEM/CITAC Guide CG 4: quantifying uncertainty in analytical measurement, 2nd ed. Ellison SLR, Rosslein M, Williams A. http://www. measurementuncertainty.org/pdf/QUAM2000-1.pdf (Accessed December 2010).
28. NCCLS. Method comparison and bias estimation using patient samples; approved guidelines, 2nd ed. NCCLS document EP9-A. Wayne (PA): NCCLS; 1995.