메뉴 건너뛰기




Volumn 76, Issue 10, 2011, Pages 4205-4209

Asymmetric synthesis of cis -2-aminocyclopropanols by intramolecular mannich addition of silyloxy benzyl carbanions

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC SYNTHESIS; BROOK REARRANGEMENT; CARBON-CARBON BOND FORMATION; DIASTEREOSELECTIVE; KETIMINES; MANNICH REACTIONS; NUCLEOPHILIC ADDITIONS; TANDEM PROCESS;

EID: 79956088541     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo200585r     Document Type: Article
Times cited : (21)

References (31)
  • 7
    • 79956066576 scopus 로고    scopus 로고
    • For functionalization of N-tert -butanesulfinyl imines via metalloenamine intermediates, including the 1,2-addition of metalloenamines derived from N-tert -butanesulfinyl ketimines to aldehydes, trifluoromethyl ketones, aldimines, and azodicarboxylates, see part 3.2 of ref 6
    • For functionalization of N-tert -butanesulfinyl imines via metalloenamine intermediates, including the 1,2-addition of metalloenamines derived from N-tert -butanesulfinyl ketimines to aldehydes, trifluoromethyl ketones, aldimines, and azodicarboxylates, see part 3.2 of ref 6.
  • 22
    • 79956160057 scopus 로고    scopus 로고
    • See the Supporting Information for the results of single-crystal structural analysis of 3a
    • See the Supporting Information for the results of single-crystal structural analysis of 3a.
  • 23
    • 79956157775 scopus 로고    scopus 로고
    • note
    • For the stereospecific retro-Brook rearrangement of silyloxy carbanions bearing aryl substituents at the anionic carbon atoms with inversion of configuration at the benzyl carbanion center, see ref 24 and 25. For retro-Brook rearrangement of silyoxy carbanions bearing alkyl substituents with retention of configuration at the carbanion center, see ref 26.
  • 27
    • 57649120956 scopus 로고    scopus 로고
    • For α-oxybenzyl anion and its nucleophilic behaviors, including inversion of configuration
    • For α-oxybenzyl anion and its nucleophilic behaviors, including inversion of configuration, see: Stymiest, J. L.; Bagutski, V.; French, R. M.; Aggarwal, V. K. Nature 2008, 456, 778
    • (2008) Nature , vol.456 , pp. 778
    • Stymiest, J.L.1    Bagutski, V.2    French, R.M.3    Aggarwal, V.K.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.