Photofunctional ternary rare earth (Eu3+, Tb3+, and Sm3+) hybrid xerogels with hexafluoroacetylacetonate derived building block and bis(2-methoxyethyl)ether through coordination bonds

Inorganic Chemistry Communications

Volumn 14, Issue 6, 2011, Pages 910-912

  Yan, Bing ^a   Li, Yan Yan ^a   Guo, Lei ^a  

^a TONGJI UNIVERSITY   (China)

Author keywords

bis(2 methoxyethyl)ether; Hexafluoroacetylacetonate building block; Photoluminescence; Ternary rare earth hybrid xerogel

Indexed keywords

EID: 79955876604     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.03.028     Document Type: Article

References (24)

1. N. Sabbatini, M. Guardigli, J.M. Lehn, Luminescent rare earth complexes as photochemical supramolecular devices, Coord. Chem. Rev. 123 (1993) 201-228.
2. T. Justel, H. Nikol, C. Ronda, New developments in the field of luminescent materials for lighting and displays, Angew. Chem. Inter. Edi. 37 (1998) 3085-3103.
3. D. Parker, R.S. Dickins, H. Puschmann, C. Crossland, J.A.K. Howard, Being excited by rare earth coordination complexes: aqua species, chirality, excited-state chemistry, and exchange dynamics, Chem. Rev. 102 (2002) 1977-2010. (Pubitemid 35381653)
4. Z.G. Chen, H.L. Chen, H. Hu, M.X. Yu, F.Y. Li, Q. Zhang, Z.G. Zhou, T. Yi, C.H. Huang, Versatile synthesis strategy for carboxylic acid-functionalized upconverting nanophosphors as biological labels, J. Am. Chem. Soc. 130 (2008) 3023-3029. (Pubitemid 351455973)
5. J. Kido, Y. Okamoto, Organo rare earth metal complexes for electroluminescent materials, Chem. Rev. 102 (2002) 2357-2368.
6. J. Silver, R. Withnall, Probes of structural and electronic environments of phosphor activators: Mossbauer and Raman spectroscopy, Chem. Rev. 104 (2004) 2833-2855.
7. 3+- 4,4,5,5,5-pentafluoro-1-(naphthalen-2-yl)pentane-1,3- dione complexes: synthesis, crystal structure and photophysical properties, Inorg. Chem. 47 (2008) 8091-8100.
8. 3+ luminescence, Cryst. Growth Des. 9 (2009) 3562-3569.
9. A. Valore, E. Cariati, S. Righetto, D. Roberto, F. Tessore, R. Ugo, I.L. Fragala, M.E. Fragala, G. Malandrino, F. De Angelis, L. Belpassi, I. Ledoux-Rak, K.H. Thi, J. Zyss, Fluorinated beta-diketonate diglyme rare earth complexes as new second-order nonlinear optical chromophores: the role of f electrons in the dipolar and octupolar contribution to quadratic hyperpolarizability, J. Am. Chem. Soc. 132 (2010) 4966-4970.
10. B. Yan, H.J. Zhang, S.B. Wang, J.Z. Ni, Luminescence properties of the ternary rare earth complexes with β-diketones and 1,10-phenanthroline incorporated in silica matrix by a sol-gel method, Mater. Chem. Phys. 51 (1997) 92-96.
11. V. Bekiari, G. Pistolis, P. Lianos, Intensely luminescent materials obtained by combining rare earth ions, 2,2′-bipyridine, and poly(ethylene glycol) in various fluid or solid environments, Chem. Mater. 11 (1999) 3189-3194.
12. A.C. Franville, D. Zambon, R. Mahiou, Y. Troin, Luminescence behavior of sol- gel-derived hybrid materials resulting from covalent grafting of a chromophore unit to different organically modified alkoxysilanes, Chem. Mater. 12 (2000) 428-435.
13. H.R. Li, J. Lin, H.J. Zhang, H.C. Li, L.S. Fu, Q.G. Meng, Novel covalently bonded hybrid materials of europium (terbium) complexes with silica, Chem. Commun. (2001) 1212-1213.
14. Q.M. Wang, B. Yan, Novel luminescent terbium molecular-based hybrids with modified meta aminobenzoic acid covalently bonded with silica, J. Mater. Chem. 13 (2004) 2450-2455.
15. L.D. Carlos, R.A.S. Ferreira, V.D. Bermudez, J.L.S. Ribeiro, Rare earth-containing light-emitting organic-inorganic hybrids: a bet on the future, Adv. Mater. 21 (2009) 509-534.
16. K. Binnemans, Rare earth-based luminescent hybrid materials, Chem. Rev. 109 (2009) 4283-4374.
17. B. Yan, Q.M. Wang, First two luminescent molecular hybrids composed of bridged Eu(III)-β-diketone chelates covalently trapped in silica and titanate gels, Cryst. Growth Des. 6 (2008) 1484-1489.
18. Y. Li, B. Yan, H. Yang, Construction, characterization and photoluminescence of mesoporous hybrids containing europium (Ø) complexes covalently bonded to SBA-15 directly functionalized by modified β-diketone, J. Phys. Chem. C 112 (2008) 3959-3968.
19. W.S. Kim, M.G. Kim, J.H. Ahn, B.S. Bae, C.B. Park, Protein micro-patterning on bifunctional organic-inorganic sol-gel hybrid materials, Langmuir 23 (2007) 4732-4736. (Pubitemid 46731948)
20. S. Sato, W. Mada, Relations between intramolecular energy transfer efficiencies and triplet state energies in rare earth β-diketone chelates, Bull. Chem. Soc. Jap. 43 (1970) 2403-2410.
21. 3+ ions, J. Alloy. Compds. 207 (1994) 112-114.
22. K. Nakamoto, Infrared and Raman spectra of inorganic and coordination compounds, Part A Theory and Applications in Inorganic Chemistry, sixth ed, Wiley-Interscience, 2009.
23. 2 composite film, Mater. Chem. Phys. 92 (2005) 10-15.
24. B. Yan, F.F. Wang, Molecular design and photophysics of quaternary hybrid terbium centered systems with novel functional di-urea linkages of strong chemical bonds through hydrogen transfer addition, J. Organomet. Chem. 692 (2007) 2395-2401.