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79955862310
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note
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-1): 3293 s, 2367w, 1579 s, 1496 s, 1457w, 1388 s, 1244 s, 1138w, 1090 m, 1041w, 971 m, 861w, 807 s, 651 m, 604w, 534 m, 458w.
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45
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79955874940
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note
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-1, R1/wR2=0.0586/0.1398 [I>2σ(I)] and 0.0817/0.1536 (for all data), GOF=1.096; Data collections of 1 were performed on a Bruker SMART CCD Apex II diffractometer with a graphite-monochromatized MoKá radiation (λ=0.71073 Å) at 298(2) K. Multi-scan absorption corrections were applied using SADABS program. The structures were solved by direct methods and refined anisotropically by full-matrix least-squares methods on F2 using the SHELXTL program package. All of the hydrogen atoms were placed in calculated positions and refined as riding atoms with isotropic thermal factors.
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46
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2 (Ln=Eu, La; 4-pya=- trans-4-pyridylacrylate)
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Coordination polymers based on inorganic lanthanide(III) sulfate skeletons and an organic isonicotinate N-oxide connector: Segregation into three structural types by the lanthanide contraction effect
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Single-crystal structure validation with the program PLATON
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