Ethylene polyamine influence on the transition metal thiogermanates: Solvothermal syntheses and characterizations of [Ni(trien)2] 2Ge4S10 and [{Ni(tepa)}2(μ- Ge2S6)]

Inorganic Chemistry Communications

Volumn 14, Issue 6, 2011, Pages 1023-1026

  Liang, Jing Jing ^a   Zhao, Jing ^a   Tang, Wei Wei ^a   Zhang, Yong ^a   Jia, Ding Xian ^a  

^a SOOCHOW UNIVERSITY   (China)

Author keywords

Crystal structure; Ethylene polyamine; Nickle; Solvothermal synthesis; Thiogermanates

Indexed keywords

EID: 79955838558     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.03.062     Document Type: Article

References (26)

1. W.S. Sheldrick, M. Wachhold, Chalcogenidometalates of the heavier Group 14 and 15 elements, Coord. Chem. Rev. 176 (1998) 211-322. (Pubitemid 128452183)
2. M. Yuan, D.B. Mitzi, Solvent properties of hydrazine in the preparation of metal chalcogenide bulk materials and films, Dalton Trans. (2009) 6078-6088.
3. 4- units: Surfactant templated three-dimensional disordered frameworks perforated with worm holes, J. Solid State Chem. 152 (2000) 21-36.
4. 4- clusters with trivalent metal ions and cetylpyridinium surfactant, J. Am. Chem. Soc. 122 (2000) 10230-10231.
5. 4- adamantane clusters, J. Am. Chem. Soc. 124 (2002) 2604-2613.
6. 10 with a high cubic cell volume. Ab initio structure determination from conventional X-ray powder diffraction, Chem. Mater. 6 (1994) 827-830.
7. O.M. Yaghi, Z. Sun, D.A. Richardson, T.L. Groy, Directed transformation of molecules to solids: synthesis of a microporous sulfide from molecular germanium sulfide cages, J. Am. Chem. Soc. 116 (1994) 807-808. (Pubitemid 24980520)
8. 10 (DABCO-AgGS-SB2): knitting sulfide metal clusters to form frameworks, Chem. Commun. (1996) 1687-1688.
9. 2O: a novel sulfide framework analogous to zeolite Li-A(BW), Chem. Mater. 9 (1997) 807-811.
10. 4- anion: synthesis and properties, Chem. Mater. 10 (1998) 1153-1159.
11. M.J. MacLachlan, N. Coombs, R.L. Bedard, S. White, L.K. Thompson, G.A. Ozin, Mesostructured metal germanium sulfides, J. Am. Chem. Soc. 121 (1999) 12005-12017.
12. 4- anions, Chem. Mater. 12 (2000) 2914-2923.
13. 10, Chem. Mater. 8 (1996) 2147-2152.
14. 6 from germanium dioxide and sulfur powder, J. Solid State Chem. 178 (2005) 874-881.
15. 6, Monatsh. Chem. 138 (2007) 191-197.
16. 7. Z. Anorg. Allg. Chem. 631 (2005) 2123.
17. 6)] (M = Mn, Fe) (tepa = tetraethylenepentamine), Z. Anorg. Allg. Chem. 636 (2010) 230-235.
18. 6)Mn] cores, Z. Anorg. Allg. Chem. 634 (2008) 1005-1010.
19. -1) of 2: 3182 (br, w), 3110 (m), 2908 (w), 2863 (m), 1566 (s), 1451 (m), 1389 (w), 1358 (m), 1312 (s), 1181 (w), 1119 (w), 1065 (m), 1003 (s), 942 (s), 918 (m), 886 (s), 818 (s), 787 (s), 610 (s), 578 (m), 530 (s), 476 (s).
20. w = 0.1249 (for all data), GOF = 1.125
21. J.J. Liang, J.F. Chen, J. Zhao, Y.L. Pan, Y. Zhang, D.X. Jia, Solvothermal syntheses, crystal structures and thermal properties of the first example of selenidostannates with mixed ethylene polyamine coordinated transition metal complexes as counterions, Z. Anorg. Allg. Chem. 637 (2011) 445-449.
22. 6, Z. Anorg. Allg. Chem. 629 (2003) 1367-1373.
23. W.W. Wendlandt, H.G. Hecht, Reflectance Spectroscopy, Interscience Publishers, New York, 1966.
24. X. Bu, N. Zheng, X. Wang, B. Wang, P. Feng, Three-dimensional frameworks of gallium selenide supertetrahedral clusters, Angew. Chem. Int. Ed. 43 (2004) 1502-1505. (Pubitemid 39257884)
25. G.M. Sheldrick, SHELXS-97, Program for structure solution, Universität of Göttingen, Germany, 1997.
26. G.M. Sheldrick, SHELXL-97, Program for structure refinement, Universität of Göttingen, Germany, 1997.