The poisoning level of Pt/C catalysts used in PEM fuel cells by the hydrogen feed gas impurities: The bonding strength

International Journal of Hydrogen Energy

Volumn 36, Issue 11, 2011, Pages 6817-6825

  Postole, Georgeta ^a   Auroux, Aline ^a  

^a INST DE RECHERCHES SUR LA CATALYSE   (France)

Author keywords

Anode poisoning; CO; Differential heats of adsorption; NH3; PEMFC; Platinum

Indexed keywords

ACTIVE SITE; ADSORBED MOLECULES; ADSORPTION PROCESS; ANODE FEED; BONDING STRENGTH; CO; CO ADSORPTION; DIFFERENTIAL HEAT; HYDROGEN ADSORPTION; HYDROGEN FEED; MICRO-CALORIMETRY; NH3; PEM FUEL CELL; PEMFC; POISONING EFFECTS; PRIMARY SOURCES; PT LOADING; SUPPORTED PLATINUM CATALYSTS; PROTON EXCHANGE MEMBRANE FUEL CELL (PEMFCS);

AMMONIA; CARBON MONOXIDE; CATALYST ACTIVITY; CATALYST POISONING; HYDROGEN; PLATINUM; PLATINUM ALLOYS; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); CARBON; COBALT; ELECTRODES; GAS ADSORPTION;

GAS ADSORPTION; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC);

EID: 79955681951     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.03.018     Document Type: Article

References (44)

1. B.C.H. Steele, and A. Heinzel Materials for fuel-cell technologies Nature 414 2001 345 352 (Pubitemid 33097817)
2. X. Cheng, Z. Shi, N. Glass, L. Zhang, J. Zhang, and D. Song A review of PEM hydrogen fuel cell contamination: impacts, mechanisms, and mitigation J Power Sources 165 2007 739 756
3. S.J.C. Cleghorn, X. Ren, T.E. Springer, M.S. Wilson, C. Zawodzinski, and T.A. Zawodzinski PEM fuel cells for transportation and stationary power generation applications Int J Hydrogen Energy 22 1997 1137 1144 (Pubitemid 127403225)
4. S. Litster, and G. McLean PEM fuel cell electrodes J Power Sources 130 2004 61 76 (Pubitemid 41325892)
5. L. Carrette, K.A. Friedrich, and U. Stimming Fuel cells-fundamentals and applications Fuel Cells 1 2001 5 39
6. U.A. Paulus, T.J. Schmidt, H.A. Gasteiger, and R.J. Behm Oxygen reduction on a high-surface area Pt/Vulcan carbon catalyst: a thin-film rotating ring-disk electrode study J Electroanal Chem 495 2001 134 145 (Pubitemid 32093156)
7. 2S and CO mixtures on PEMFC performance Int J Hydrogen Energy 32 2007 4412 4417 (Pubitemid 350180220)
8. A.S. Chellappa, C.M. Fischer, and W.J. Thomson Ammonia decomposition kinetics over Ni-Pt/Al2O3 for PEM fuel cell applications Appl Catal A Gen 227 2002 231 240 (Pubitemid 34154250)
9. S.F. Yin, B.Q. Xu, X.P. Zhou, and C.T. Au A mini-review on ammonia decomposition catalysts for on-site generation of hydrogen for fuel cell applications Appl Catal A Gen 277 2004 1 9
10. J. Zhang, H. Wang, D.P. Wilkinson, D. Song, J. Shen, and Z.S. Liu Model for the contamination of fuel cell anode catalyst in the presence of fuel stream impurities J Power Sources 147 2005 58 71
11. G.A. Camara, E.A. Ticianelli, S. Mukerjee, S.J. Lee, and J. McBreen The CO poisoning mechanism of the hydrogen oxidation reaction in proton exchange membrane fuel cells J Electrochem Soc 149 2002 A748 A753
12. H. Igarashi, T. Fujino, Y. Zhu, H. Uchida, and M. Watanabe CO tolerance of Pt alloy electrocatalysts for polymer electrolyte fuel cells and the detoxification mechanism Phys Chem Chem Phys 3 2001 306 314
13. D.C. Papageorgopoulos, M. Keijzer, J.B.J. Veldhuis, and F.A. de Bruijin CO tolerance of Pd-rich platinum palladium carbon-supported electrocatalysts J Electrochem Soc 149 2002 A1400 A1404
14. A.K. Meland, and S. Kjelstrup Three steps in the anode reaction of the polymer electrolyte membrane fuel cell. Effect of CO J Electroanal Chem 610 2007 171 178 (Pubitemid 350046601)
15. N. Wagner, and M. Schulze Change of electrochemical impedance spectra during CO poisoning of the Pt and Pt-Ru anodes in a membrane fuel cell (PEFC) Electrochim Acta 48 2003 3899 3907
16. H. Hanawa, K. Kunimatsu, H. Uchida, and M. Watanabe In situ ATR-FTIR study of bulk CO oxidation on a polycrystalline Pt electrode Electrochimica Acta 54 2009 6276 6285
17. G. Postole, S. Bennici, and A. Auroux Calorimetric study of the reversibility of CO pollutant adsorption on high loaded Pt/carbon catalysts used in PEM fuel cells Appl Catal B Env 92 2009 307 317
18. A. Maroto-Valiente, I. Rodriguez-Ramos, and A. Guerrero-Ruiz Determination of the surface states of metallic clusters supported on alumina using microcalorimetry of CO adsorption Thermochim Acta 379 2001 195 199 (Pubitemid 33097723)
19. A. Guerrero-Ruiz, A. Maroto-Valiente, M. Cerro-Alarcon, B. Bachiller-Baeza, and I. Rodriguez-Ramos Determination of the surface states for metallic clusters supported on alumina using microcalorimetry of CO adsorption Top Catal 19 2002 303 311
20. 3 Thermochim Acta 434 2005 107 112 (Pubitemid 41027694)
21. R.D. Cortright, and J.A. Dumesic Microcalorimetric, spectroscopic and kinetic studies of silica-supported Pt abd Pt/Sn catalysts for isobutene dehydrogenation J Catal 148 1994 771 778
22. J. Silvestre-Albero, J.C. Serrano-Ruiz, A. Sepulveda-Escribano, and F. Rodriguez-Reinoso Modification of the catalytic behaviour of platinum by zinc in crotonaldehyde hydrogenation and iso-butane dehydrogenation Appl Catal A Gen 292 2005 244 251
23. J.C. Serrano-Ruiz, A. Lopez-Cudero, J. Solla-Gullon, A. Sepulveda-Escribano, A. Aldaz, and F. Rodriguez-Reinoso Hydrogenation of α, β unsaturated aldehydes over polycrystalline (111) and (100) preferentially oriented Pt nanoparticles supported on carbon J Catal 253 2008 159 166 (Pubitemid 350236146)
24. A. Guerrero-Ruiz, P. Badenes, and I. Rodriguez-Ramos Study of some factors affecting the Ru and Pt dispersions over high surface area graphite-supported catalysts Appl Catal A Gen 173 1998 313 321 (Pubitemid 128410404)
25. A. Auroux B. Imelik, J.C. Vedrine, Catalyst characterization: physical techniques for Solid materials 1994 Plenum Press New York 611
26. G. Bergeret, and P. Gallezot G. Ertl, H. Knozinger, F. Schuth, J. Weitkamp, Handbook of heterogeneous Catalysis vol. 2 2008 Verlag: Wiley-VCH 738
27. A. Auroux Microcalorimetry methods to study the acidity and reactivity of zeolites, pillared clays and mesoporous materials Top Catal 19 2002 205 213
28. H. Kivrak, Á Mastalir, Z. Király, and D. Uner Determination of the dispersion of supported Pt particles by gas-phase and liquid-phase measurements Catal Commun 10 2009 1002 1005 [and the references there in]
29. P. Trens, R. Durand, B. Coq, C. Coutanceau, S. Rousseau, and C. Lamby Poisoning of Pt/C catalysts by CO and its consequences over the kinetics of hydrogen chemisorptions Appl Catal B Env 92 2009 280 284
30. 2 adsorption and activation on Pt/C. Part 1: in the absence of humidity J Power Sources 195 2010 3060 3068
31. R.D. Cortright, and J.A. Dumesic Effects of potassium on silica-supported Pt and Pt/Sn catalysts for isobutane dehydrogenation J Catal 157 1995 576 583
32. S.B. Sharma, J.T. Miller, and J.A. Dumesic Microcalorimetric study of silica- and zeolite-supported platinum catalysts J Catal 148 1994 198 204
33. 2 system J Catal 104 1987 136 146
34. W.L. Griffiths, H.E. Hallam, and W.T. Thomas Infra-red study of adsorption and oxidation of ammonia on silica-supported platinum and silica Trans Faraday Soc 64 1968 3361 3369
35. 3. A method for determining metal-adsorbate interaction J Catal 29 1973 213 223
36. N. Rajalakshmi, T.T. Jayanth, and K.S. Dhathathreyan Effect of carbon dioxide and ammonia on polymer electrolyte membrane fuel stack performance Fuel Cells 3 2003 177 180
37. F.A. Uribe, S. Gottesfeld Jr., and T.A. Zawodzinski Effect of ammonia as potential fuel impurity on proton exchange membrane fuel cell performance J Electrochem Soc 149 2002 A293 A296
38. R. Alcala, J.W. Shabaker, G.W. Huber, M.A. Sanchez-Castillo, and J.A. Dumesic Experimental and DFT studies of the conversion of ethanol and acetic acid on PtSn-based catalysts J Phys Chem B 109 2005 2074 2085
39. P. Hollins The influence of surface defects on the infrared spectra of adsorbed species Surf Sci Rep 16 1992 51 94
40. S.D. Jackson, B.M. Glanville, J. Willis, G.D. McLellan, G. Webb, and R.B. Moyes Supported metal catalysts: preparation characterisation and function J Catal 139 1993 207 220
41. 3 catalyst Catal Today 68 2001 155 160
42. M. Primet, J.M. Basset, M.V. Mathieu, and M. Prettre Infrared investigation of hydrogen adsorption on alumina-supported platinum J Catal 28 1973 368 375
43. S. Jiménez, J. Soler, R.X. Valenzuela, and L. Daza Assessment of the performance of a PEMFC in the presence of CO J Power Sources 151 2005 69 73
44. C. Bonnet, L. Franck-Lacaze, S. Ronasi, S. Besse, and F. Lapicque PEM fuel cell Pt anode inhibition by carbon monoxide: non-uniform behavior of the cell caused by the finite hydrogen excess Chem Eng Sci 65 2010 3050 3058