Catalytic and stoichiometric reactivity of β-silylamido agostic complex of Mo: Intermediacy of a silanimine complex and applications to multicomponent coupling

Journal of the American Chemical Society

Volumn 133, Issue 18, 2011, Pages 7033-7053

  Khalimon, Andrey Y ^a   Simionescu, Razvan ^a   Nikonov, Georgii I ^a  

^a BROCK UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

[CARBONYL; AGOSTIC BONDS; ANALOGOUS REACTIONS; ASSOCIATIVE MECHANISMS; BOND METATHESIS; DEHYDROGENATIVE COUPLING; DIASTEREOMERS; HYDRIDE COMPLEXES; HYDRIDE SPECIES; IMIDO LIGAND; INTERMEDIATE FORMATION; MECHANISTIC STUDIES; MOTHER LIQUOR; MULTI-COMPONENT COUPLING; MULTINUCLEAR NMR; REACTION PATHWAYS; SILANIMINE; SILYL GROUP; SILYLATIONS; STOICHIOMETRIC REACTION; STOICHIOMETRIC REACTIVITY; VINYL SUBSTITUENTS;

ALDEHYDES; CARBONYLATION; CYANIDES; ETHYLENE; HYDROGENATION; HYDROSILYLATION; MECHANICS; PHOSPHORUS COMPOUNDS; RATE CONSTANTS; REACTION INTERMEDIATES; SILICON; STYRENE; X RAY DIFFRACTION;

MOLYBDENUM COMPOUNDS;

MOLYBDENUM COMPLEX; SILANE DERIVATIVE;

ARTICLE; CATALYSIS; INFRARED SPECTROSCOPY; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; SILYLATION; STOICHIOMETRY; X RAY DIFFRACTION;

EID: 79955679357     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja111005r     Document Type: Article

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