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Volumn 2, Issue 1, 2011, Pages 150-156

The formation of NH+ following the reaction of N22+ with H2

Author keywords

[No Author keywords available]

Indexed keywords

BOND FORMING; CENTRE OF MASS; COINCIDENCE TECHNIQUES; COLLISION ENERGIES; COMPUTATIONAL INVESTIGATION; DICATIONS; ENCOUNTER COMPLEX; EXCITED ELECTRONIC STATE; MONOCATIONS; POSITION SENSITIVE; RATE COEFFICIENTS; REACTION CROSS-SECTIONS; SATURN'S MOONS; SINGLE ELECTRON TRANSFER; STATIONARY POINTS; TITAN'S ATMOSPHERE;

EID: 79955644293     PISSN: 20416520     EISSN: 20416539     Source Type: Journal    
DOI: 10.1039/c0sc00344a     Document Type: Article
Times cited : (13)

References (60)
  • 3
    • 0742320156 scopus 로고    scopus 로고
    • D. Mathur, Phys. Rep., 2004, 391, 1-118.
    • (2004) Phys. Rep , vol.391 , pp. 1-118
    • Mathur, D.1
  • 7
    • 0001199596 scopus 로고
    • D. Mathur, Phys. Rep., 1993, 225, 193-272.
    • (1993) Phys. Rep , vol.225 , pp. 193-272
    • Mathur, D.1
  • 37
    • 79955673192 scopus 로고    scopus 로고
    • Notes
    • The bond-forming reaction we detect, which forms NH H N cannot proceed via a N2H2 intermediate, as the reaction via N2H2 must involve the formation of an H atom. A contribution to reactions (4) and (5) from decay of an N2H2 intermediate is excluded by the strong forward scattering exhibited by these channels clearly showing that these reactions proceed by simple dissociative electron transfer.
  • 39
    • 79955674739 scopus 로고    scopus 로고
    • Notes
    • This reaction cross section is likely to be a lower limit because the assumed linear decrease in the cross section for forming N2 with collision energy probably results in an underestimate of the cross section for N2 formation at our collision energies.
  • 42
    • 79955664417 scopus 로고    scopus 로고
    • Notes
    • The incident dications, which are produced by electron ionization cannot be considered to be equilibrated to a thermal temperature. Thus, as is usually the case with ion beam work, the rate coefficients derived should be considered as simply indicative for thermalised reactant ions.
  • 51
    • 79955645543 scopus 로고    scopus 로고
    • Notes
    • NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg MD, 20899 (http://webbook.nist.gov), 2003.
  • 58
    • 79955658284 scopus 로고    scopus 로고
    • Notes
    • 2 minimum (E = -13.6 eV, r(HN) = 1.104 Å, r(NN) = 1.073 Å) on the singlet PES, of D∞h symmetry. This minimum does not appear to readily connect to the observed products.
  • 60
    • 79955662228 scopus 로고    scopus 로고
    • Notes
    • 2 minimum, of C2h geometry [r(H-N) = 1.108 Å, r(N-N) = 1.280 Å, <(HNN) = 125.7°, E = -7.1 eV]. This minimumdoes not appear to lie on a pathway to the observed products.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.