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The bond-forming reaction we detect, which forms NH H N cannot proceed via a N2H2 intermediate, as the reaction via N2H2 must involve the formation of an H atom. A contribution to reactions (4) and (5) from decay of an N2H2 intermediate is excluded by the strong forward scattering exhibited by these channels clearly showing that these reactions proceed by simple dissociative electron transfer.
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This reaction cross section is likely to be a lower limit because the assumed linear decrease in the cross section for forming N2 with collision energy probably results in an underestimate of the cross section for N2 formation at our collision energies.
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The incident dications, which are produced by electron ionization cannot be considered to be equilibrated to a thermal temperature. Thus, as is usually the case with ion beam work, the rate coefficients derived should be considered as simply indicative for thermalised reactant ions.
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2 minimum (E = -13.6 eV, r(HN) = 1.104 Å, r(NN) = 1.073 Å) on the singlet PES, of D∞h symmetry. This minimum does not appear to readily connect to the observed products.
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2 minimum, of C2h geometry [r(H-N) = 1.108 Å, r(N-N) = 1.280 Å, <(HNN) = 125.7°, E = -7.1 eV]. This minimumdoes not appear to lie on a pathway to the observed products.
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