Experimental validation of in situ CO2 capture with CaO during the low temperature combustion of biomass in a fluidized bed reactor

International Journal of Greenhouse Gas Control

Volumn 5, Issue 3, 2011, Pages 512-520

  Abanades, J C ^a   Alonso, M ^a   Rodriguez, N ^a  

^a INSTITUTO NACIONAL DEL CARBÓN   (Spain)

Author keywords

Biomass combustion; Calcination; Carbonation; Fluidized beds

Indexed keywords

ATMOSPHERIC PRESSURE; ATMOSPHERIC TEMPERATURE; BIOMASS; CALCINATION; CALCITE; CALCIUM CARBONATE; CALCIUM OXIDE; CARBON DIOXIDE; CARBONATION; CHEMICAL REACTORS; COMBUSTORS; EFFICIENCY; FLUIDIZATION; FLUIDIZED BED FURNACES; FLUIDIZED BED PROCESS; FLUIDIZED BEDS; IN SITU COMBUSTION; SUPERSATURATION;

BIOMASS COMBUSTION; CIRCULATING FLUIDIZED BED REACTOR; CIRCULATING FLUIDIZED COMBUSTIONS; EXPERIMENTAL VALIDATIONS; INTERCONNECTED FLUIDIZED BED; LOW TEMPERATURE COMBUSTION; SOLIDS CIRCULATION RATES; SUPERFICIAL GAS VELOCITIES;

FLUIDIZED BED COMBUSTION;

ATMOSPHERIC PRESSURE; BIOMASS; BIOREACTOR; CARBON DIOXIDE; CARBON SEQUESTRATION; COMBUSTION; EXPERIMENTAL STUDY; LIME; LOW TEMPERATURE; STOICHIOMETRY; TESTING METHOD;

EID: 79955640395     PISSN: 17505836     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijggc.2010.01.006     Document Type: Article

References (26)

1. Abanades J.C., Alvarez D. Conversion limits in the reaction of CO2 with lime. Energy Fuels 2003, 17:308-315.
2. Abanades J.C., Anthony E.J., Lu D.Y., Salvador C., Alvarez D. Capture of CO2 from combustion gases in a fluidized bed of CaO. AIChE J. 2004, 50:1614-1622.
3. Abanades J.C., Grasa G., Alonso M., Rodriguez N., Anthony E.J., Romeo L.M. Cost structure of a postcombustion CO2 capture system using CaO. Environ. Sci. Technol. 2007, 41:5523-5527.
4. Alonso M., Rodríguez N., Grasa G., Abanades J.C. Modelling of a fluidized bed carbonator reactor to capture CO2 from a combustion flue gas. Chem. Eng. Sci. 2009, 64:883-891.
5. Alonso, M., Rodríguez, N., González, B., Grasa, G., Murillo, R., Abanades, J.C., 2009b. Carbon dioxide capture from combustion flue gases with a calcium oxide chemical loop. Experimental results and process development. Int. J. Greenhouse Gas Control. doi:10.1016/j.ijggc.2009.10.004.
6. Anthony E.J. Solid looping cycles: a new technology for coal conversion. Ind. Eng. Chem. Res. 2008, 47:1747-1754.
7. Baker E.H. The calcium oxide-calcium dioxide system in the pressure range 1-300 atmospheres. J. Chem. Soc. 1962, 464-470.
8. Bhatia S.K., Perlmutter D.D. Effect of the product layer on the kinetics of the CO2-lime reaction. AlChE J. 1983, 29:79-86.
9. Charitos A., Hawthorne C., Bidwe A.R., He L., Scheffknecht G. Design of a dual fluidised bed system for the post combustion removal of CO2 using CaO. Part II: scaled cold model investigation. Proceedings of 9th International Conference on Circulating Fluidized Beds, Hamburg, Germany 2008.
10. Charitos A., Hawthorne C., Bidwe A.R., Holz H., Pfeifer T., Schulze A., Schelegel D., Schuster A., Scheffknecht G. Parametric study on the CO2 capture efficiency of the carbonate looping process in a 10kW dual fluidized bed. Proceedings of 20th International Conference of Fluidized Bed Combustion, Xian, China 2009.
11. Curran G.P., Fink C.E., Gorin E. CO2 acceptor gasification process. Studies of acceptor properties. Adv. Chem. Ser. 1967, 69:141-161.
12. Dai J., Sokhansanj S., Grace R.J., Bi X., Lim J.C., Melin S. Overview and some issues related to co-firing biomass and coal. Canadian J. Chem. Eng. 2008, 86:367-386.
13. González B., Grasa G.S., Alonso M., Abanades J.C. Modeling of the deactivation of CaO in a carbonate loop at high temperatures of calcination. Ind. Eng. Chem. Res. 2008, 47:9256-9262.
14. Grasa G.S., Abanades J.C., Alonso M., Gonzalez B. Reactivity of highly cycled particles of CaO in a carbonation/calcination loop. Chem. Eng. J. 2008, 137:561-567.
15. Grasa G.S., Abanades J.C. CO2 capture capacity of CaO in long series of carbonation/calcination cycles. Ind. Eng. Chem. Res. 2006, 45:8846-8851.
16. Grasa G., Murillo R., Alonso M., Abanades J.C. Application of the random pore model to the carbonation cyclic reaction. AIChE J. 2009, 55:1246-1255.
17. Harrison Douglas P. Sorption-enhanced hydrogen production: a review. Ind. Eng. Chem. Res. 2008, 47:6486-6501.
18. International Panel on Climate Change (IPCC) Summary for policymakers and technical summary. Special Report on Carbon Dioxide Capture and Storage 2005, 1-16. Cambridge University Press, New York, NY (United States). B. Metz, O. Davidson, H. Coninck, M. Loos, L. Meyer (Eds.).
19. Koppatz S., Pfeifer C., Rauch R., Hofbauer H., Marquard-Moellenstedt T., Specht M. H-2 rich product gas by steam gasification of biomass with in situ CO2 absorption in a dual fluidized bed system of 8MW fuel input. Fuel Process Technol. 2009, 90:914-921.
20. Lu D.Y., Hughes R.W., Anthony E.J. Ca-based sorbent looping combustion for CO2 capture in pilot-scale dual fluidized beds. Fuel Process Technol. 2008, 89:1386-1395.
21. Obersteiner M., Azar Ch., Kauppi P., Möllersten K., Moreira J., Nilsson S., Read P., Riahi K., Schlamadinger B., Yamagata Y., Yan J., van Ypersele J.P. Managing climate risk. Science 2001, 294:786-787.
22. Pfeifer C., Puchner B., Hofbauer H. In-situ CO2-absorption in a dual fluidized bed biomass steam gasifier to produce a hydrogen rich syngas. Int. J. Chem. Reactor Eng. 2007, 5:A9.
23. Rodriguez N., Alonso M., Grasa G., Abanades J.C. Heat requirements in a calciner of CaCO3 integrated in a CO2 capture system using CaO. Chem. Eng. J. 2008, 138:148-154.
24. Wang C., Jia L., Tan Y., Anthony E.J. Carbonation of fly ash in oxy-fuel CFB combustion. Fuel 2008, 87:1108-1114.
25. Weimer T., Berger R., Hawthorne C., Abanades J.C. Lime enhanced gasification of solid fuels: examination of a process for simultaneous hydrogen production and CO2 capture. Fuel 2008, 87:1678-1686.
26. Williams R.H. Fuel decarbonization for fuel cell applications and sequestration of the separated CO2. Eco-restructuring: Implications for Sustainable Development 1998, 180-222. United Nations University Press, Tokyo. R.U. Ayres (Ed.).