Aquivalence revisited - New model formulation and application to assess environmental fate of ionic pharmaceuticals in Hamilton Harbour, Lake Ontario

Environment International

Volumn 37, Issue 5, 2011, Pages 821-828

  Csiszar, Susan A ^a   Gandhi, Nilima ^a   Alexy, Radka ^b   Benny, Donald T ^c   Struger, John ^c   Marvin, Chris ^c   Diamond, Miriam L ^a  

^a UNIVERSITY OF TORONTO   (Canada)

^b UNIVERSITY OF FREIBURG   (Germany)

^c ENVIRONMENT CANADA   (Canada)

Author keywords

Activity; Aquivalence; Degradation half lives; Fugacity; Ionic compounds; Pharmaceuticals

Indexed keywords

DRUG PRODUCTS; SURFACE WATERS; THERMODYNAMIC PROPERTIES;

AQUIVALENCE; AQUIVALENCE-BASED MASS BALANCE MODELS; ENVIRONMENTAL FATE; FUGACITY; HALF LIVES; IONIC COMPOUNDS; SORPTION COEFFICIENTS; WATER CONCENTRATIONS;

LAKES;

GEMFIBROZIL; IBUPROFEN; NAPROXEN; SURFACE WATER; TRICLOSAN;

DEGRADATION; DRUG; ENVIRONMENTAL FATE; FUGACITY; HALF LIFE; MASS BALANCE; ORGANIC COMPOUND;

ANALYTIC METHOD; AQUIVALENCE; ARTICLE; BIODEGRADATION; CANADA; CONCENTRATION RESPONSE; CONTROLLED STUDY; DRUG HALF LIFE; ENVIRONMENTAL MONITORING; IONIC STRENGTH; MATHEMATICAL MODEL; PH; PHOTODEGRADATION; PRIORITY JOURNAL; SEASONAL VARIATION; SPRING; SUMMER;

CANADA; HAMILTON HARBOR; ONTARIO [CANADA];

EID: 79955572346     PISSN: 01604120     EISSN: 18736750     Source Type: Journal    
DOI: 10.1016/j.envint.2011.02.001     Document Type: Article

References (34)

1. ACD/Labs ACD/Labs Software V814 for Solaris Toronto, ON 1994-2009, Advanced Chemistry Development, Inc.
2. Appelo C.A.J., Postma D. A consistent model for surface complexation on birnessite (-MnO2) and its application to a column experiment. Geochim et Cosmochim Acta 1999, 63:3039-3048.
3. Aranami K., Readman J.W. Photolytic degradation of triclosan in freshwater and seawater. Chemosphere 2007, 66:1052-1056.
4. Bhavsar S.P., Diamond M.L., Evans L.J., Gandhi N., Nilsen J., Antunes P. Development of a coupled metal speciation-fate model for surface aquatic systems. Environ Toxicol Chem 2004, 23:1376-1385.
5. Boreen A.L., Arnold W.A., McNeill K. Photodegradation of pharmaceuticals in the aquatic environment: a review. Aquat Sci 2003, 65:320-341.
6. Buser H.R., Poiger T., Muller M.D. Occurrence and environmental behavior of the chiral pharmaceutical drug ibuprofen in surface waters and in wastewater. Environ Sci Technol 1999, 33:2529-2535.
7. Cahill T.M., Cousins I., Mackay D. General fugacity-based model to predict the environmental fate of multiple chemical species. Environ Toxicol Chem 2003, 22:483-493.
8. Cahill T.M., Mackay D. A high-resolution model for estimating the environmental fate of multi-species chemicals: application to malathion and pentachlorophenol. Chemosphere 2003, 53:571-581.
9. Diamond M.L., Mackay D., Welbourn P.M. Models of multimedia partitioning of multispecies chemicals-the fugacity equivalence approach. Chemosphere 1992, 25:1907-1921.
10. Fenner K., Scheringer M., Hungerbuhler K. Persistence of parent compounds and transformation products in a level IV multimedia model. Environ Sci Technol 2000, 34:3809-3817.
11. Fono L.J., Kolodziej E.P., Sedlak D.L. Attenuation of wastewater-derived contaminants in an effluent-dominated river. Environ Sci Technol 2006, 40:7257-7262.
12. Franco A., Trapp S. Estimation of the soil-water partition coefficient normalized to organic carbon for ionizable organic chemicals. Environ Toxicol Chem 2008, 27:1995-2004.
13. Gandhi N., Bhavsar S.P., Diamond M.L., Kuwabara J.S., Marvin-Dipasquale M., Krabbenhoft D.P. Development of a mercury speciation, fate, and biotic uptake (BIOTRANSPEC) model: application to Lahontan Reservoir (Nevada, USA). Environ Toxicol Chem 2007, 26:2260-2273.
14. Kagle J., Porter A.W., Murdoch R.W., Rivera-Cancel G., Hay A.G. Biodegradation of pharmaceutical and personal care products. Advances in Applied Mircobiology 2009, Vol 67. Elsevier Academic Press Inc, San Diego.
15. Latch D.E., Packer J.L., Stender B.L., VanOverbeke J., Arnold W.A., McNeill K. Aqueous photochemistry of triclosan: formation of 2, 4-dichlorophenol, 2, 8-dichlorodibenzo-p-dioxin, and oligomerization products. Environ Toxicol Chem 2005, 24:517-525.
16. Lee H.B., Peart T.E., Carron J.M., Tse H. Chemical derivatization analysis of pesticide-residues .11. An improved method for the determination and conformation of acidic herbicides in water. J Assoc Off Anal Chem 1991, 74:835-842.
17. Lewis G.N. The osmotic pressure of concentrated solutions, and the laws of the perfect solution. J Am Chem Soc 1908, 30:668-683.
18. Lin A.Y.C., Plumlee M.H., Reinhard M. Natural attenuation of pharmaceuticals and alkylphenol polyethoxylate metabolites during river transport: Photochemical and biological transformation. Environ Toxicol Chem 2006, 25:1458-1464.
19. Lin A.Y.C., Reinhard M. Photodegradation of common environmental pharmaceuticals and estrogens in river water. Environ Toxicol Chem 2005, 24:1303-1309.
20. Lindstrom A., Buerge I.J., Poiger T., Bergqvist P.A., Muller M.D., Buser H.R. Occurrence and environmental behavior of the bactericide triclosan and its methyl derivative in surface waters and in wastewater. Environ Sci Technol 2002, 36:2322-2329.
21. Ling H., Diamond M., Mackay D. Application of the QWASI fugacity aquivalence model to assessing sources and fate of contaminants in Hamilton Harbour. J Gt Lakes Res 1993, 19:582-602.
22. Mackay D., Diamond M. Application of the QWASI (Quantitative Water Air Sediment Interaction) fugacity model to the dynamics of organic and inorganic chemicals in lakes. Chemosphere 1989, 18:1343-1365.
23. Mackay D., Joy M., Paterson S. A quantitative water, air, sediment interaction (QWASI) fugacity model for describing the fate of chemicals in lakes. Chemosphere 1983, 12:981-997.
24. Monteiro S.C., Boxall A.B.A. Occurrence and fate of human pharmaceuticals in the environment. Reviews of Environmental Contamination and Toxicology 2010, Vol 202. Springer, New York.
25. Nikolaou A., Meric S., Fatta D. Occurrence patterns of pharmaceuticals in water and wastewater environments. Anal Bioanal Chem 2007, 387:1225-1234.
26. Packer J.L., Werner J.J., Latch D.E., McNeill K., Arnold W.A. Photochemical fate of pharmaceuticals in the environment: naproxen, diclofenac, clofibric acid, and ibuprofen. Aquat Sci 2003, 65:342-351.
27. Radke M., Ulrich H., Wurm C., Kunkel U. Dynamics and attenuation of acidic pharmaceuticals along a river stretch. Environ Sci Technol 2010, 44:2968-2974.
28. Singer H., Muller S., Tixier C., Pillonel L. Triclosan: occurrence and fate of a widely used biocide in the aquatic environment: field measurements in wastewater treatment plants, surface waters, and lake sediments. Environ Sci Technol 2002, 36:4998-5004.
29. Tixier C., Singer H.P., Canonica S., Muller S.R. Phototransformation of triclosan in surface waters: a relevant elimination process for this widely used biocide-laboratory studies, field measurements, and modeling. Environ Sci Technol 2002, 36:3482-3489.
30. Tixier C., Singer H.P., Oellers S., Muller S.R. Occurrence and fate of carbamazepine, clofibric acid, diclofenac, ibuprofen, ketoprofen, and naproxen in surface waters. Environ Sci Technol 2003, 37:1061-1068.
31. Trapp S., Franco A., Mackay D. Activity-Based Concept for Transport and Partitioning of Ionizing Organics. Environ Sci Technol 2010, 44:6123-6129.
32. Wilson B., Zhu J., Cantwell M., Olsen C.R. Short-term dynamics and retention of Triclosan in the lower Hudson River Estuary. Mar Pollut Bull 2008, 56:1230-1233.
33. Yamamoto H., Nakamura Y., Moriguchi S., Honda Y., Tamura I., Hirata Y., et al. Persistence and partitioning of eight selected pharmaceuticals in the aquatic environment: laboratory photolysis, biodegradation, and sorption experiments. Water Res 2009, 43:351-362.
34. Zukowska B., Breivik K., Wania F. Evaluating the environmental fate of pharmaceuticals using a level III model based on poly-parameter linear free energy relationships. Sci Total Environ 2006, 359:177-187.