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Volumn 50, Issue 9, 2011, Pages 5862-5865

Poly(ethylene glycol) embedded potassium tribromide (PEG.KBr3) as a recyclable catalyst for oxidation of alcohols

Author keywords

[No Author keywords available]

Indexed keywords

DIKETONES; HOSTGUEST CHEMISTRY; OXIDATION OF ALCOHOLS; RECYCLABLE CATALYST;

EID: 79955545323     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie101748w     Document Type: Article
Times cited : (5)

References (31)
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    • Preparation of PEG.KBr3 1: In a round-bottomed flask (100 mL) equipped with a magnetic stirrer, KBr (0.95 g, 8 mmol) was added to a solution of PEG400 (2 g, 5 mmol) in water (30 mL) and the mixture stirred for 4 h at room temperature. In the next step, bromine (0.8 g, 5 mmol) was added to the solution and continued the reaction under stirring for next 2-3 h. After completion, the obtained residue was extracted with dichloromethane and the combined organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The dark red viscous oil was obtained which has been used as catalyst for oxidation
    • Preparation of PEG.KBr3 1: In a round-bottomed flask (100 mL) equipped with a magnetic stirrer, KBr (0.95 g, 8 mmol) was added to a solution of PEG400 (2 g, 5 mmol) in water (30 mL) and the mixture stirred for 4 h at room temperature. In the next step, bromine (0.8 g, 5 mmol) was added to the solution and continued the reaction under stirring for next 2-3 h. After completion, the obtained residue was extracted with dichloromethane and the combined organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The dark red viscous oil was obtained which has been used as catalyst for oxidation.
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    • General procedure for the oxidation of alcohols: In to the mixture containing substrate (1 mmol) and {[K+PEG].Br3 -} (10 mol %) was added hydrogen peroxide (2 mmol) by a syringe and the resulting mixture heated at 80°C. The reaction progress was monitored by TLC using ethyl acetate: hexane (6:4) as eluent. After completion, the product was extracted with diethyl ether and the residual aqueous layer was treated with bromine to regenerate the catalyst. The combined ether layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to give the oxidized products
    • General procedure for the oxidation of alcohols: In to the mixture containing substrate (1 mmol) and {[K+PEG].Br3 -} (10 mol %) was added hydrogen peroxide (2 mmol) by a syringe and the resulting mixture heated at 80°C. The reaction progress was monitored by TLC using ethyl acetate: hexane (6:4) as eluent. After completion, the product was extracted with diethyl ether and the residual aqueous layer was treated with bromine to regenerate the catalyst. The combined ether layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to give the oxidized products.
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