Square-wave adsorptive voltammetry of dexamethasone: Redox mechanism, kinetic properties, and electroanalytical determinations in multicomponent formulations

Analytical Biochemistry

Volumn 413, Issue 2, 2011, Pages 148-156

  Oliveira, Thiago Mielle B F ^a   Ribeiro, Francisco Wirley P ^a   Soares, Janete E S ^a   De Lima Neto, Pedro ^a   Correia, Adriana N ^a  

^a FEDERAL UNIVERSITY OF CEARÁ   (Brazil)

Author keywords

Dexamethasone; Electroanalytical determination; Pharmaceuticals; Square wave adsorptive voltammetry

Indexed keywords

DROPS; ELECTROLYTIC REDUCTION; VOLTAMMETRY;

ADSORPTIVE VOLTAMMETRY; BRITTON-ROBINSON BUFFER; DEXAMETHASONES; ELECTROANALYTICAL DETERMINATION; ELECTROCHEMICAL REDUCTIONS; HANGING MERCURY DROP ELECTRODES; MULTICOMPONENT FORMULATION; RELATIVE STANDARD DEVIATIONS;

DRUG PRODUCTS;

DEXAMETHASONE; MERCURY;

ACCURACY; ACTION POTENTIAL; ARTICLE; CATHODE RAY TUBE; CHEMICAL REACTION KINETICS; DRUG DETERMINATION; ELECTROCHEMICAL ANALYSIS; ELECTRODE; OXIDATION REDUCTION REACTION; PH; POTENTIOMETRY; PRIORITY JOURNAL; REACTION ANALYSIS; SQUARE WAVE ADSORPTIVE VOLTAMMETRY;

EID: 79955476684     PISSN: 00032697     EISSN: 10960309     Source Type: Journal    
DOI: 10.1016/j.ab.2011.02.033     Document Type: Article

References (46)

1. S. Görög Drug safety, drug quality, drug analysis J. Pharm. Biomed. Anal. 48 2008 247 253
2. J.M.L. Gallego, and J.P. Arroyo Simultaneous determination of dexamethasone and trimethoprim by liquid chromatography J. Pharm. Biomed. Anal. 30 2002 1255 1261
3. Y.V. Heyden, A. Nijhuis, J. Smeyers-Verbeke, B.G.M. Vandeginste, and D.L. Massart Guidance for robustness/ruggedness tests in method validation J. Pharm. Biomed. Anal. 24 2001 723 753 (Pubitemid 32209131)
4. D. Guillarme, D.T.T. Nguyen, S. Rudaz, and J. Veuthey Method transfer for fast liquid chromatography in pharmaceutical analysis: application to short columns packed with small particles - I. Isocratic separation Eur. J. Pharm. Biopharm. 66 2007 475 482 (Pubitemid 46756226)
5. F.W.P. Ribeiro, A.S. Cardoso, R.R. Portela, J.E.S. Lima, S.A.S. Machado, P. De Lima-Neto, D. de Souza, and A.N.C. Correia Electroanalytical determination of promethazine hydrochloride in pharmaceutical formulations on highly boron-doped diamond electrodes using square-wave adsorptive voltammetry Electroanalysis 20 2008 2031 2039
6. P. de Lima-Neto, A.N. Correia, R.R. Portela, M. da S. Juliao, G.F. Linhares-Junior, and J.E.S. de Lima Square wave voltammetric determination of nitrofurantoin in pharmaceutical formulations on highly boron-doped diamond electrodes at different boron-doping contents Talanta 80 2010 1730 1736
7. Q. Chen, D. Zielinski, J. Chen, A. Koski, D. Werst, and S. Nowak A validated, stability-indicating HPLC method for the determination of dexamethasone-related substances on dexamethasone-coated drug-eluting stents J. Pharm. Biomed. Anal. 48 2008 732 738
8. M. Spangler, and E. Mularz A validated, stability-indicating method for the assay of dexamethasone in drug substance and drug product analyses, and the assay of preservatives in drug product Chromatographia 54 2001 329 334 (Pubitemid 32911584)
9. D.M. Gentile, E.A. Tomlinson, J.L. Maggs, B.K. Park, and D.J. Back Dexamethasone metabolism by human liver in vitro: metabolite identification and inhibition of 6-hydroxylation J. Pharmacol. Exp. Ther. 277 1996 105 112 (Pubitemid 27169049)
10. Council of Europe, European Pharmacopoeia, fourth ed., Council of Europe, Strasbourg, France, 2002.
11. U.S. Pharmacopeial Convention, U.S. Pharmacopeia, 25th ed., U.S. Pharmacopeial Convention, Rockville, MD, 2002.
12. Society of Japanese Pharmacopoeia, The Japanese Pharmacopoeia, 13th ed., Society of Japanese Pharmacopoeia, Tokyo, 1996.
13. V.K. Gupta, R. Jain, K. Radhapyari, N. Jadon, and S. Agarwal Voltammetric techniques for the assay of pharmaceuticals: a review Anal. Biochem. 408 2011 179 196
14. K. Liu, S. Wu, H. Kou, and H. Wu High-performance liquid chromatographic determination of betamethasone and dexamethasone J. Chromatogr. A 676 1994 455 460 (Pubitemid 24249020)
15. J.W. Thorpe, and J. Warkentin Stereochemical and steric effects in nucleophilic substitution of α-halo ketones Can. J. Chem. 51 1973 927 935
16. F. Caloni, C. Belloli, G. Crescenzo, P. Ormas, and P. Archimbault Determination of dexamethasone in milk of dairy cows by immuno-enzymatic assay Vet. Hum. Toxicol. 42 2000 345 348
17. J. Wang Electroanalytical Techniques in Clinical Chemistry and Laboratory Medicine 1988 VCH New York
18. 1,4-3-ketosteroids Anal. Chim. Acta 130 1981 111 132 (Pubitemid 11023673)
19. K. Balaji, G.V.R. Reddy, M. Reddy, and S.J. Reddy Determination of prednisolone, dexamethasone, and hydrocortisone in pharmaceutical formulations and biological fluids sample by voltammetric techniques using β-cyclodextrin modified carbon paste electrode Afr. J. Pharm. Pharmacol. 2 2008 157 166
20. C. Jeyaseelan, and A.P. Joshi Trace determination of dexamethasone sodium phosphate in pharmaceutical formulations by differential pulse polarography Anal. Bioanal. Chem. 373 2002 772 776 (Pubitemid 34994815)
21. X. Yu, P. Zhao, W. Zhang, L. Zhang, and Y. Zhang Screening of phage displayed human liver cDNA library against dexamethasone J. Pharm. Biomed. Anal. 45 2007 701 705 (Pubitemid 350087565)
22. H.T.S. Britton, and R.A. Robinson Universal buffer solutions and the dissociation constant of veronal J. Chem. Soc. 458 1931 1456 1462
23. J. Mocak, A.M. Bond, S. Mitchel, and G. Scollary A statistical overview of standard (IUPAC and ACS) and new procedures for determining the limits of detection and quantification: application to voltammetric and stripping techniques Pure Appl. Chem. 69 1997 297 328
24. Analytical Methods Committee, Recommendations for the definition, estimation, and use of the detection limit, Analyst 112 (1987) 199-204.
25. D.A. Skoog, D.M. West, and F.J. Holler Fundamentals of Analytical Chemistry seventh ed. 1996 Saunders College Philadelphia
26. H.S. De Boer, J. Den Hartigh, H.H.J.L. Ploegmakers, and W.J. Van Oort Polarographic analysis for corticosteroids: 1. The electroanalytical properties of corticosteroids Anal. Chim. Acta 102 1978 141 155 (Pubitemid 9073661)
27. A.J. Bard Chemical Equilibrium 1966 Harper & Row New York
28. M. Xu, L. Chen, and J. Song Polarographic behaviors of diclofenac sodium in the presence of dissolved oxygen and its analytical application Anal. Biochem. 329 2004 21 27 (Pubitemid 38596897)
29. C. Debnath, E. Haslinger, W. Likussar, and A. Michelitsch Determination of the antimalaria drug artemether in pharmaceutical preparations by differential pulse polarography J. Pharm. Biomed. Anal. 41 2006 638 643
30. A.N.S. Dantas, D. Souza, J.E.S. Lima, J.E.S. Lima, P. De Lima-Neto, and A.N. Correia Voltammetric determination of ketoconazole using a polished silver solid amalgam electrode Electrochim. Acta 55 2010 9083 9089
31. R.N. Goyal, S. Chatterjee, and A.R.S. Rana Effect of cetyltrimethyl ammonium bromide on electrochemical determination of dexamethasone Electroanalysis 22 2010 1 9
32. H. Derendorf, P. Rohdewald, G. Hochhaus, and H. Möllmann HPLC determination of glucocorticoid alcohols, their phosphates, and hydrocortisone in aqueous solutions and biological fluids J. Pharm. Biomed. Anal. 4 1986 197 206 (Pubitemid 16024580)
33. E.M. Ghoneim, A. El-Attar, and M.M. Ghoneim Adsorptive cathodic stripping voltammetric determination of dexamethasone in formulations and biological fluids J. AOAC Int. 92 2009 597 603
34. L. Cun, W. Yinliang, Y. Ting, and Y. Zhang Rapid simultaneous determination of dexamethasone and betamethasone in milk by liquid chromatography tandem mass spectrometry with isotope dilution J. Chromatogr. A 1217 2010 411 414
35. O. Van Den Hauve, J.C. Perez, J. Claereboudt, and C. Van Peteghem Simultaneous determination of betamethasone and dexamethasone residues in bovine liver by liquid chromatography/tandem mass spectrometry Rapid Commun. Mass Spectrom. 15 2001 857 861 (Pubitemid 32525561)
36. V. Baeyens, E. Varseio, J.-L. Veuthey, and R. Gurny Determination of dexamethasone in tears by capillary electrophoresis J. Chromatogr. B 692 1997 222 226 (Pubitemid 27208486)
37. A.J. Fry Synthetic Organic Electochemistry second ed. 1989 John Wiley New York
38. R.N. Goyal, V.K. Gupta, and S. Chatterjee A sensitive voltammetric sensor for determination of triamcinolone, a synthetic corticosteroid, abused for doping Biosens. Bioelectron. 24 2009 3562 3568
39. F.A. Carey, and R.J. Sundberg Advanced Organic Chemistry. Part A: Structure and Mechanisms fifth ed. 2007 Springer New York
40. D. de Souza, S.A.S. Machado, and L.A. Avaca Voltametria de onda quadrada: Primeira parte: Aspectos teóricos Quím. Nova 26 2003 81 89 (Pubitemid 36237650)
41. Š. Komorsky-Lovric, and M. Lovric Square-wave voltammetry of quasi-reversible surface redox reactions J. Electroanal. Chem. 384 1995 115 122
42. Š. Komorsky-Lovric Kinetics of the cinnoline surface redox reaction Electroanalysis 14 2002 888 891
43. Š. Komorsky-Lovric, and M. Lovric Kinetic measurements of a surface confined redox reaction Anal. Chim. Acta 305 1995 248 255
44. D.K. Gosser Jr. Cyclic Voltammetry: Simulation and Analysis of Reaction Mechanisms 1994 VCH New York
45. J.N. Miller, and J.C. Miller Statistics and Chemometrics for Analytical Chemistry fifth ed. 2005 Pearson Prentice Hall Harlow, UK
46. I. Taverniers, M.D. Loose, and E.V. Bockstaele Trends in quality in the analytical laboratory. II: Analytical method validation and quality assurance Trends Anal. Chem. 23 2004 535 551