Prediction of the overall enthalpy of CO2 absorption in aqueous amine systems from experimentally determined reaction enthalpies

Energy Procedia

Volumn 4, Issue , 2011, Pages 1542-1549

  McCann, Nichola ^a   Maeder, Marcel ^b   Hasse, Hans ^a  

^a Rheinland Pfälzische Technische Universität Kaiserslautern Landau   (Germany)

^b UNIVERSITY OF NEWCASTLE   (Australia)

Author keywords

Carbamate formation enthalpy

Indexed keywords

ENTHALPY; GREENHOUSE GASES;

AMINE SYSTEM; FORMATION ENTHALPY; MEASURED VALUES; REACTION ENTHALPIES;

CARBON DIOXIDE;

EID: 79955380027     PISSN: 18766102     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.1016/j.egypro.2011.02.023     Document Type: Conference Paper

References (33)

1. Metz, B., O. Davidson, H.C. de Coninck, M. Loos, and M.L. A, editors. IPCC Special Report on Carbon Dioxide Capture and Storage. Prepared by Working Group III of the Intergovernmental Panel on Climate Change. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA. 2005.
2. Stern, N. The Economics of Climate Change: The Stern Review. Cambridge, UK: Cambridge University Press. 2007.
3. Wise, M.A. and J.J. Dooley. The Value of Post-Combustion Carbon Dioxide Capture and Storage Technologies in a World with Uncertain Greenhouse Gas Emissions Constraints. Int. J. Greenhouse Gas Control 2009. 3: 39-48.
4. Notz, R., N. Asprion, I. Clausen, and H. Hasse. Selection and Pilot Plant Tests of New Absorbents for Post- Combustion Carbon Dioxide Capture. Chem. Eng. Res. Des. 2007. 85: 510-5. (Pubitemid 46672014) (Pubitemid 46672014)
5. Schäfer, B., A.E. Mather, and K.N. Marsh. Enthalpies of Solution of Carbon Dioxide in Mixed Solvents. Fluid Phase Equilib. 2002. 194: 929-35. (Pubitemid 34242616) (Pubitemid 34242616)
6. Aroua, M.K., A. Benamor, and M.Z. Haji-Sulaiman. Equilibrium Constant for Carbamate Formation from Monoethanolamine and Its Relationship with Temperature. J. Chem. Eng. Data 1999. 44: 887-91.
7. Park, S.H., K.B. Lee, J.C. Hyun, and S.H. Kim. Correlation and Prediction of the Solubility of Carbon Dioxide in Aqueous Alkanolamine and Mixed Alkanolamine Solutions. Ind. Eng. Chem. Res. 2002. 41: 1658-65. (Pubitemid 34225930) (Pubitemid 34225930)
8. 2 in a 30-Mass-Percent Monoethanolamine Solution. Can. J. Chem. Eng. 1995. 73: 140-7.
9. 2O-Alkanolamine Systems: An NMR Study. Ind. Eng. Chem. Res. 2005. 44: 9894-903. (Pubitemid 43060127) (Pubitemid 43060127)
10. Barth, D., P. Rubini, and J.J. Delpuech. Determination of Thermodynamic Parameters for the Formation of Amino-Alcohol Carbamates in Aqueous Solutions by C13 Nuclear Magnetic Resonance Spectroscopy. Bull. Soc. Chim. Fr. 1984: 227-30.
11. Aroua, M.K., A. Benamor, and M.Z. Haji-Sulaiman. Temperature Dependency of the Equilibrium Constant for the Formation of Carbamate from Diethanolamine. J. Chem. Eng. Data 1997. 42: 692-6. (Pubitemid 127649393) (Pubitemid 127649393)
12. Barth, D., P. Rubini, and J.J. Delpuech. Study on the Formation of Diethanolamine Carbamate by C13 Nuclear Magnetic Resonance. New J. Chem. 1983. 7: 563-7.
13. 2. Fluid Phase Equilib. 2008. 263: 131-43.
14. McCann, N., M. Maeder, and H. Hasse. Calorimetric Study of Carbamate Formation. In Preparation 2010.
15. Maeder, M. and Y.-M. Neuhold. Practical Data Analysis in Chemistry. Amsterdam: Elsevier. 2007.
16. Christensson, F., H.C.S. Koefoed, A.C. Petersen, and K. Rasmussen. Equilibrium Constants in the Ammonium Carbonate-Carbaminate System. The Acid Dissociation Constant of Carbamic Acid. Acta Chem. Scand., Ser. A 1978. A32: 15-7.
17. Harris, D.C. Quantitative Chemical Analysis. 6th ed. New York: W.H. Freeman and Company. 2003.
18. Barner, H.E. and R.V. Scheuerman. Handbook of Thermochemical Data for Compounds and Aqueous Species. New York: John Wiley & Sons, Inc. 1978.
19. 2O in Aqueous Monoethanolamine and 2-(2-Aminoethyl- Amino)Ethanol Solutions from 298 to 343 K. Energy Procedia 2009. 1: 837-43.
20. Tsai, T.C., J.J. Ko, H.M. Wang, C.Y. Lin, and M.H. Li. Solubility of Nitrous Oxide in Alkanolamine Aqueous Solutions. J. Chem. Eng. Data 2000. 45: 341-7.
21. Al-Ghawas, H.A., D.P. Hagewiesche, G. Ruiz-Ibanez, and O.C. Sandall. Physicochemical Properties Important for Carbon-Dioxide Absorption in Aqueous Methyldiethanolamine. J. Chem. Eng. Data 1989. 34: 385-91. (Pubitemid 20643643) (Pubitemid 20643643)
22. 2) in Monoethanolamine (MEA) and 2-(Aminoethyl)Ethanolamine (AEEA) Solutions. Ind. Eng. Chem. Res. 2007. 46: 5803-9. (Pubitemid 47326299) (Pubitemid 47326299)
23. 2 in Aqueous Monoethanolamine Solutions. Ind. Eng. Chem. Res. 1998. 37: 4136-41.
24. Carson, J.K., K.N. Marsh, and A.E. Mather. Enthalpy of Solution of Carbon Dioxide in (Water Plus Monoethanolamine, or Diethanolamine, or N-Methyldiethanolamine) and (Water Plus Monoethanolamine Plus N-Methyldiethanolamine) at T=298.15 K. J. Chem. Thermodynamics 2000. 32: 1285-96.
25. 2 in Aqueous Solutions of Methyldiethanolamine. Fluid Phase Equilib. 1997. 140: 171-82.
26. 2 in Aqueous Solutions of 2-Amino-2- Methyl-1-Propanol. J. Chem. Thermodynamics 2007. 39: 878-87. (Pubitemid 46617544) (Pubitemid 46617544)
27. 3 - from 0°C to 50°C. J. Am. Chem. Soc. 1941. 63: 1706-9.
28. Harned, H.S. and F.T. Bonner. The 1st Ionization of Carbonic Acid in Aqueous Solutions of Sodium Chloride. J. Am. Chem. Soc. 1945. 67: 1026-31.
29. Vanderzee, C.F. and J.A. Swanson. Heat of Ionization of Water. J. Phys. Chem. 1963. 67: 2608-12.
30. Bates, R.G. and G.D. Pinching. Acidic Dissociation Constant and Related Thermodynamic Quantities for Monoethanolammonium Ion in Water from 0°C to 50°C. J. Res. Nat. Bur. Stand. 1951. 46: 349-52.
31. Bower, V.E., R.A. Robinson, and R.G. Bates. Acid Dissociation Constant and Related Thermodynamic Quantities for Diethanolammonium Ion in Water from 0 to 50°C. J. Res. Nat. Bur. Stand. 1962. 66A: 71-5.
32. Oscarson, J.L., G. Wu, P.W. Faux, R.M. Izatt, and J.J. Christensen. Thermodynamics of Protonation of Alkanolamines in Aqueous-Solution to 325°C. Thermochim. Acta 1989. 154: 119-27.
33. Hamborg, E.S. and G.F. Versteeg. Dissociation Constants and Thermodynamic Properties of Amines and Alkanolamines from (293 to 353) K. J. Chem. Eng. Data 2009. 54: 1318-28.