Direct observation of kinetically competent surface intermediates upon ethylene hydroformylation over Rh/Al2O3 under reaction conditions by time-resolved fourier transform infrared spectroscopy

Journal of Physical Chemistry C

Volumn 115, Issue 15, 2011, Pages 7545-7553

  Sivasankar, N ^a,b   Frei, H ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b Liquid Light Inc   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINA-SUPPORTED; CATALYTIC HYDROFORMYLATION; COMPLETE PRODUCTS; DIRECT OBSERVATION; ELEMENTARY STEPS; ETHYLENE HYDROFORMYLATION; ETHYLENE HYDROGENATION; H ABSORPTION; HYDROCARBON CONVERSION; NANOPARTICLE CATALYSTS; PROPIONALDEHYDE; RAPID SCAN; RATE-LIMITING STEPS; REACTION CONDITIONS; SINGLE COMPONENTS; SPECTRAL ASSIGNMENTS; SURFACE INTERMEDIATES; TIME CONSTANTS; TIME-RESOLVED; TIME-RESOLVED FOURIER TRANSFORM INFRARED; TIME-RESOLVED FOURIER TRANSFORM INFRARED SPECTROSCOPIES; TOTAL PRESSURE;

ALDEHYDES; ETHANE; ETHYLENE; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROCARBONS; HYDROFORMYLATION; HYDROXYLATION; NANOPARTICLES; REACTION KINETICS; RHODIUM;

HYDROGENATION;

EID: 79954621615     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp112391n     Document Type: Article

References (38)

1. Eilbracht, P.; Baerfacker, L.; Buss, C.; Hollmann, C.; Kitsos-Rzychon, B. E.; Kranemann, C. L.; Rische, T.; Roggenbuck, R.; Schmidt, A. Chem. Rev. 1999, 99, 3329
2. Xiao, F. S.; Ichikawa, M. J. Catal. 1994, 147, 578
3. Balakos, M. W.; Chuang, S. S. C. J. Catal. 1995, 151, 266
4. van Leeuwen, P. W. N. M. In Rhodium Catalyzed Hydroformylation; van Leeuwen, P. W. N. M.; Claver, C., Eds.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 2002; p 1.
5. Srinivas, G.; Chuang., S. S. C. J. Catal. 1993, 144, 131
6. Balakos, M. W.; Chuang., S. S. C. J. Catal. 1995, 151, 253
7. Ko, M. K.; Frei, H. J. Phys. Chem. B 2004, 108, 1805
8. Wasylenko, W.; Frei, H. J. Phys. Chem. B 2005, 109, 16873
9. Izumi, Y.; Asakura, K.; Iwasawa, Y. J. Catal. 1991, 127, 631
10. Davis, J. L.; Barteau, M. A. J. Am. Chem. Soc. 1989, 111, 1782
11. Wasylenko, W.; Frei, H. J. Phys. Chem. B 2005, 109, 16873
12. Ko, M. K.; Frei, H. J. Phys. Chem. B 2004, 108, 1805
13. Rioux, R. M.; Hoefelmeyer, J. D.; Grass, M.; Song, H.; Niesz, K.; Yang, P.; Somorjai, G. A. Langmuir 2008, 24, 198
14. Hwang, K. S.; Yang, M.; Zhu, J.; Grunes, J.; Somorjai, G. A. J. Mol. Catal. A 2003, 204-205, 499
15. McQuire, M. W.; Rochester, C. H.; Anderson, J. A. J. Chem. Soc., Faraday Trans. 1992, 88, 879
16. Fukushima, T.; Arakawa., H.; Ichikawa, M. J. Phys. Chem. 1985, 89, 4440
17. Anderson, J. A.; McQuire, M. W.; Rochester, C. H.; Sweeney, T. Catal. Today 1991, 9, 23
18. Chudek, J. A.; McQuire, M. W.; Rochester, C. H. J. Catal. 1992, 135, 358
19. Balakos, M. W.; Chuang., S. S. C.; Srinivas., G.; Brundage, M. A. J. Catal. 1995, 157, 51
20. Gotti, A.; Prins, R. Catal. Lett. 1996, 37, 143
21. Han, D.; Li, X.; Zhang, H.; Liu, Z.; Li, J.; Li, C. J. Catal. 2006, 243, 318
22. Vimont, A.; Thibault-Starzyk, F.; Daturi, M. Chem. Soc. Rev. 2010, 39, 4928
23. Wasylenko, W.; Frei, H. Phys. Chem. Chem. Phys. 2007, 9, 5497
24. Wasylenko, W.; Frei, H. J. Phys. Chem. C 2007, 111, 9884
25. Yeom, Y. H.; Frei, H. J. Phys. Chem. A 2002, 106, 3350
26. Sachtler, W. M. H.; Ichikawa, M. J. Phys. Chem. 1986, 90, 4752
27. McQuire, M. W.; McQuire, G. W.; Rochester, C. H. J. Chem. Soc., Faraday Trans. 1992, 88, 1203
28. Te, M.; Lowenthal., E. E.; Foley, H. C. Chem. Eng. Sci. 1994, 49, 4851
29. Koranyi., T. I.; Mihaly., J.; Pfeifer., E.; Nemeth., C.; Yuzhakova., T.; Mink., J. J. Phys. Chem. A 2006, 110, 1817
30. Prairie., M. R.; Cho., B. K.; Oh., S. H.; Shinouskis., E. J. Ind. Eng. Chem. Res. 1988, 27, 1396
31. Zhang., Z.; Kladi., A.; Verykios., X. E. J. Catal. 1995, 156, 37
32. Supporting Information.
33. Deeming, A. J.; Shaw, B. L. J. Chem. Soc. A 1969, 1, 597
34. Bennett, M. A.; Jeffery, J. C.; Robertson, G. B. Inorg. Chem. 1981, 20, 323
35. Hart-Davis, A. J.; Graham, W. A. G. Inorg. Chem. 1971, 10, 1653
36. Chutia, P.; Sarmah, B. J.; Dutta, D. K. Appl. Organometal. Chem. 2006, 20, 512
37. Bellamy, L. J. The Infrared Spectra of Complex Molecules, 3 rd ed.; Chapman and Hall: London, 1975; Vol. 1, p 176.
38. Thibault-Starzyk, F.; Seguin, E.; Thomas, S.; Daturi, M.; Arnolds, H.; King, D. A. Science 2009, 324, 1048