Thermodynamics of dilution and the Hofmeister series in aqueous solutions of aliphatic ionenes with halide counterions

Journal of Chemical and Engineering Data

Volumn 56, Issue 4, 2011, Pages 1282-1292

  Čebašek, Sašo ^a   Lukšič, Miha ^a   Pohar, Ciril ^a   Vlachy, Vojko ^a  

^a UNIVERSITY OF LJUBLJANA   (Slovenia)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SOLUTIONS; CONCENTRATION RANGES; COUNTERIONS; CYLINDRICAL CELLS; DENSITY EFFECTS; ENDOTHERMIC EFFECTS; ENTHALPIES OF DILUTION; ENTHALPY OF DILUTION; ENTROPY CHANGES; FLUORIDE ION; HOFMEISTER SERIES; LOW CONCENTRATIONS; MEASURED DATA; POISSON-BOLTZMANN; THEORETICAL PREDICTION; THEORETICAL RESULT;

BOLTZMANN EQUATION; BROMINE COMPOUNDS; CHLORINE COMPOUNDS; CYLINDERS (SHAPES); ENTHALPY; ENTROPY; FLUORINE COMPOUNDS; FREE ENERGY; GIBBS FREE ENERGY; POISSON EQUATION; SOLUTIONS; THERMODYNAMICS;

DILUTION;

EID: 79954620345     PISSN: 00219568     EISSN: 15205134     Source Type: Journal    
DOI: 10.1021/je101136a     Document Type: Article

References (50)

1. Alexandrowicz, Z.; Katchalsky, A. Colligative Properties of Polyelectrolyte Solutions in Excess of Salt J. Polym. Sci., Part A 1963, 1, 3231-3260
2. Manning, G. S. Limiting Laws and Counterion Condensation in Polyelectrolyte Solutions. I. Colligative Properties J. Chem. Phys. 1969, 51, 924-933
3. Manning, G. S. Limiting Laws and Counterion Condensation in Polyelectrolyte Solutions. II. Self-Diffusion of the Small Ions J. Chem. Phys. 1969, 51, 934-938
4. Katchalsky, A. Polyelectrolytes Pure Appl. Chem. 1971, 26, 327-373
5. Dolar, D. Thermodynamic Properties of Polyelectrolyte Solutions. Polyelectrolytes; Selegny, E., Mandel, M.; Strauss, U. P., Eds.; D. Reidel Publ. Co.: Dordrecht-Holland, 1974; pp 97 - 113.
6. Dautzenberg, H.; Jaeger, W.; Kötz, J.; Philipp, B.; Seidel, C.; Stscherbina, D. Polyelectrolytes. Formation, Characterization and Application; Hanser: Munich, 1994.
7. Schmitz, K. S. Macroions in Solution and Colloidal Suspension; VCH: New York, 1993.
8. Forster, S.; Schmidt, M. Physical Properties of Polymers Adv. Polym. Sci. 1995, 120, 51-133
9. Vlachy, V.; Hribar Lee, B.; Reščič, J.; Kalyuzhnyi, Yu. V. Ionic Soft Matter: Modern Trends in Theory and Applications, NATO Science Series II: Mathematics, Physics and Chemistry; Henderson, D.; Holovko, M.; Trokhymchuk, A., Eds.; Springer: New York, 2005; Vol. 206.
10. Rembaum, A.; Naguchi, H. Reactions of N, N, N ′, N ′-Tetramethyl-a,w-diaminoalkanes with a,w-Dihaloalkanes. II. x-y Reactions Macromolecules 1972, 5, 261-269
11. Williams, S. R.; Long, T. E. Recent Advances in the Synthesis and Structure-Property Relationships of Ammonium Ionenes Prog. Polym. Sci. 2009, 34, 762-782
12. Layman, J. M.; Borgerding, E. M.; Williams, S. R.; Heath, W. H.; Long, T. E. Synthesis and Characterization of Aliphatic Ammonium Ionenes: Aqueous Size Exclusion Chromatography for Absolute Molecular Weight Characterization Macromolecules 2008, 41, 4635-4641
13. Zelikin, A. N.; Akritskaya, N. I.; Izumrudov, V. A. Modified Aliphatic Ionenes. Influence of Charge Density and Length of the Chains on Complex Formation with Poly(methacrylic acid) Macromol. Chem. Phys. 2001, 202, 3018-3026
14. Zelikin, A. N.; Davydova, O. V.; Akritskaya, N. I.; Kargov, S. I.; Izumrudov, V. A. Conformation of Polyelectrolyte Chains in Dilute Aqueous Solutions Investigated by Conductometry. 4. Influence of Molecular Mass and Charge Density of the Chains on Conformation of Symmetrical Aliphatic Ionene Bromides J. Phys. Chem. B 2004, 108, 490-495
15. Casson, D.; Rembaum, A. Solution Properties of Novel Polyelectrolytes Macromolecules 1972, 5, 75-81
16. Nagaya, J.; Minakata, A.; Tanioka, A. Conductance and Counterion Activity of Ionene Solutions Langmuir 1999, 15, 4129-4134
17. Nagaya, J.; Minakata, A.; Tanioka, A. Effects of the Charge Density and Counterion Species on the Conductance of Ionene Solutions Colloids Surf., A 1999, 148, 163-169 (Pubitemid 29076624)
18. Arh, K.; Pohar, C. Enthalpies of Dilution of Aqueous Ionene Solutions Acta Chim. Slov. 2001, 48, 385-394
19. Arh, K.; Pohar, C.; Vlachy, V. Osmotic Properties of Aqueous Ionene Solutions J. Phys. Chem. B 2002, 106, 9967-9973 (Pubitemid 35382757)
20. Lukšič, M.; Buchner, R.; Hribar-Lee, B.; Vlachy, V. Dielectric Relaxation Spectroscopy of Aliphatic Ionene Bromides and Fluorides in Water: The Role of the Polyion's Charge Density and the Nature of the Counterions Macromolecules 2009, 42, 4337-4342
21. Lukšič, M.; Buchner, R.; Hribar-Lee, B.; Vlachy, V. Modelling Fast Mode Dielectric Relaxation of Counterions in Aqueous Solutions of Ionene Bromides and Fluorides Phys. Chem. Chem. Phys. 2009, 11, 10053-10058
22. Lukšič, M.; Hribar-Lee, B.; Vlachy, V. Interplay of Ion-Specific and Charge-Density Effects in Aqueous Solutions of Weakly Charged Ionenes as Revealed by Electric-Transport Measurements J. Phys. Chem. B 2010, 114, 10401-10408
23. Druchok, M.; Hribar Lee, B.; Krienke, H.; Vlachy, V. A Molecular Dynamics Study of Short-Chain Polyelectrolytes in Explicit Water: Toward the origin of ion-specific effects Chem. Phys. Lett. 2008, 450, 281-285
24. Druchok, M.; Vlachy, V.; Dill, K. A. An Explicit-Water Molecular Dynamics Study of a Short-Chain 3,3-Ionene in Solution with Sodium Halides J. Chem. Phys. 2009, 130, 134903-1-134903-8
25. Druchok, M.; Vlachy, V.; Dill, K. A. Computer Simulations of Ionenes, Hydrophobic Ions with Unusual Solution Thermodynamic Properties. The Ion-Specific Effects J. Phys. Chem. B 2009, 113, 14270-14276
26. Druchok, M.; Vlachy, V. Molecular Dynamics Study of the Hydrophobic 6,6-ionene Oligocation in Aqueous Solution with Sodium Halides Pure Appl. Chem. 2010, 82, 1943-1955
27. Škerjanc, J. Contributions of the Polyion and Counterions to the Internal and Free Energies of Polyelectrolyte Solutions J. Chem. Phys. 1990, 93, 6731-6737
28. Daoust, H.; Hade, A. Effect of Cation Size on Heats of Dilution of Aqueous Solutions of Alkaline Poly(styrenesu1fonates) Macromolecules 1976, 9, 608-611
29. Boyd, G. E.; Wilson, D. P. Enthalpies of Mixing of Polyelectrolytes with Simple Aqueous Electrolyte Solutions J. Phys. Chem. 1976, 80, 805-808
30. Daoust, H.; Chabot, M.-A. Effect of Cation Size and of the Presence of Hydrophobic Groups on Heats of Dilution of Aqueous Solutions of Alkali Metal and Tetramethylammonium Salts of the Polyacrylic Series Macromolecules 1980, 13, 616-619
31. Hales, P. W.; Pass, G. The Effect of Temperature on the Enthalpy of Dilution of Polyelectrolyte Solutions Eur. Polym. J. 1981, 17, 651-659
32. Vesnaver, G.; Rudež, M.; Pohar, C.; Škerjanc, J. Effect of Temperature on the Enthalpy of Dilution of Strong Polyelectrolyte Solutions J. Phys. Chem. 1984, 88, 2411-2418
33. Vesnaver, G.; Kranjc, Z.; Pohar, C.; Škerjanc, J. Free Enthalpies, Enthalpies, and Entropies of Dilution of Aqueous Solutions of Alkaline Earth Poly(styrenesulfonates) at Different Temperatures J. Phys. Chem. 1987, 91, 3845-3848
34. Vesnaver, G.; Škerjanc, J. Entropies of Dilution of Strong Polyelectrolyte Solutions J. Phys. Chem. 1986, 90, 4673-4676
35. Keller, M.; Lichtenthaler, R. N.; Heintz, A. Enthalpies of Dilution of Some Polycation Solutions and Exchange Enthalpies of Polycation Counterions Ber. Bunsenges. Phys. Chem. 1996, 100, 776-779 (Pubitemid 126752709)
36. Godec, A.; Škerjanc, J. Enthalpy Changes upon Dilution and Ionization of Poly(L-glutamic acid) in Aqueous Solutions J. Phys. Chem. B 2005, 109, 13363-13367 (Pubitemid 41048746)
37. Lipar, I.; Zalar, P.; Pohar, C.; Vlachy, V. Thermodynamic Characterization of Polyanetholesulfonic Acid and Its Alkaline Salts J. Phys. Chem. B 2007, 111, 10030-10136
38. Piñero, J.; Bhuiyan, B. L.; Reščič, J.; Vlachy, V. Thermodynamics and Structural Properties of the Model Polyelectrolyte-electrolyte Mixture Acta Chim. Slov. 2008, 55, 521-527
39. Bjerrum, N. Die Verdünnungswärme einer Ionenlösung in der Theorie von Debye und Hückel Z. Phys. Chem. 1926, 119, 145-160
40. Lyklema, J. Lyotropic sequences in colloid stability revisited Adv. Colloid Interface Sci. 2003, 100, 1-12
41. Koelsch, P.; Viswanath, P.; Motschmann, H.; Shapovalov, V. L.; Brezesinski, G.; Mohwald, H.; Horinek, D.; Netz, R. R.; Giewekemeyer, K.; Salditt, T.; Schollmeyer, H.; von Klitzing, R.; Daillant, J.; Guenoun, P. Specific Ion Effects in Physicochemical and Biological Systems: Simulations, Theory and Experiments Colloids Surf., A 2007, 303, 110-136 (Pubitemid 46810212)
42. Collins, K. D.; Neilson, G. W.; Enderby, J. E. Ions in Water: Characterizing the Forces that Control Chemical Processes and Biological Structure Biophys. Chem. 2007, 128, 95-104 (Pubitemid 46843439)
43. Kunz, W.; Neueder, R. Specific Ion Effects; Kunz, W., Ed.; Chapter 1: An Attempt of a General Overview; World Scientific Publishing Co. Pte. Ltd.: River Edge, NJ, 2009.
44. Kunz, W. Specific Ion Effects in Colloidal and Biological Systems Curr. Opin. Colloid Interface Sci. 2010, 15, 34-39
45. Lund, M.; Vrbka, L.; Jungwirth, P. Specific Ion Binding to Nonpolar Surface Patches of Proteins J. Am. Chem. Soc. 2008, 130, 11582-11583
46. Hess, B.; van der Vegt, N. F. A. Cation Specific Binding with Protein Surface Charges Proc. Natl. Acad. Sci. U.S.A. 2009, 106, 13296-13300
47. Kalcher, I.; Horinek, D.; Netz, R. R.; Dzubiella, J. Ion Specific Correlations in Bulk and at Biointerfaces J. Phys.: Condens. Matter 2009, 21, 424108
48. Rasaiah, J. C. A View of Electrolyte Solutions J. Solution Chem. 1973, 2, 301-334
49. Birch, B. J.; Hall, D. G. Heats of Dilution of Sub-micellar Aqueous Surfactant Solutions J. Chem. Soc., Faraday Trans. 1 1972, 68, 2350
50. De Lisi, R.; Ostiguy, C.; Perron, G.; Desnoyers, J. E. Complete Thermodynamic Properties of Nonyl- and Decyltrimethylammonium Bromides in Water J. Colloid Interface Sci. 1979, 71, 147-166