Reductive cleavage of chlorine from 6-chloronicotinic acid on mercury electrodes

Electrochimica Acta

Volumn 56, Issue 12, 2011, Pages 4631-4637

  Montoya, M Ruiz ^a   Pintado, S ^b   Mellado, J M Rodríguez ^b  

^a UNIVERSITY OF HUELVA   (Spain)

^b UNIVERSITY OF CÓRDOBA   (Spain)

Author keywords

Chlorine cleavage; Electrode kinetics; Pyridine herbicides; Reduction mechanisms

Indexed keywords

6-CHLORONICOTINIC ACID; CHLORIDE IONS; COOH GROUP; DIFFERENTIAL PULSE; DIRECT CURRENT; DISSOCIATION CONSTANT; ELECTRO REDUCTION; ELECTROCHEMICAL REACTIONS; ELECTROCHEMICAL STUDIES; ELECTRODE KINETICS; LIMITING CURRENT; MERCURY ELECTRODES; PH VALUE; PK VALUES; PYRIDINE HERBICIDES; PYRIDINIC NITROGEN; RATE DETERMINING STEP; REACTION PATHWAYS; REDUCTION MECHANISMS; REDUCTIVE CLEAVAGE; TAFEL SLOPES; UV-VIS SPECTRA; VOLTAMMETRIC;

CHLORINE; CHLORINE COMPOUNDS; DISSOCIATION; ELECTRODES; ELECTROLYTIC REDUCTION; HERBICIDES; MERCURY (METAL); PYRIDINE; WEED CONTROL;

CYCLIC VOLTAMMETRY;

EID: 79954580525     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2011.02.099     Document Type: Article

References (32)

1. M.C. Corredor, and J.M. Rodríguez Mellado J. Electroanal. Chem. 586 2006 98
2. M. Ruiz Montoya, and J.M. Rodríguez Mellado J. Electrochem. Soc. 155 2008 F190
3. J.M. Rodríguez Mellado, M.C. Corredor, L. Pospíšil, and M. Hromadová Electroanalytical 17 2005 979
4. M.C. Corredor, J.M. Rodríguez Mellado, and M. Ruiz Montoya Electrochim. Acta 51 2006 4302
5. T.R. Roberts, and D.H. Hutson Metabolic pathways of agrochemicals Herbicides and Plant Growth, Part 2 1999 Royal Society of Chemistry Great Britain
6. L.M. Bowers, C.V. Lam, Acute toxicity of 6-chloronicotinic acid (a metabolite of imidacloprid) to Chironomus tentans under static renewal conditions, Bayer Report, 1998, No. 108127.
7. R.G. Bates Determination of pH. Theory and Practice 1973 Wiley New York p. 194
8. M.C. Corredor, and J.M. Rodríguez Mellado Electrochim. Acta 49 2004 1843
9. R. Rodriguez Amaro, R. Pérez Morales, V. López, and J.J. Ruiz J. Electroanal. Chem. 278 1990 307
10. J. Koutecky Collect. Czech. Chem. Commun. 18 1953 597
11. R.C. Weast, CRC Handbook of Chemistry and Physics 81th ed. 2000 CRC Press Cleveland
12. S.G. Mairanovskii J. Electroanal. Chem. 4 1962 166
13. J. Volke, and V. Volkova Collect. Czech. Chem. Commun. 20 1955 908
14. J. Volke, and V. Volkova Collect. Czech. Chem. Commun. 20 1955 1332
15. R. Marín Galvín, and J.M. Rodríguez Mellado Coll. Czech. Chem. Commun. 57 1992 1836
16. J.M. Rodríguez Mellado Electrochem. Commun. 2 2000 612
17. E. Kirowa-Eisner, and E. Gileadi J. Electroanal. Chem. 38 1972 191
18. J.M. Rodríguez Mellado, M. Blázquez, L. Camacho, and J.J. Ruiz J. Electroanal. Chem. 190 1985 47
19. J.M. Rodríguez Mellado, and R. Marín Galvín J. Electroanal. Chem. 267 1989 221
20. M. Ruiz Montoya, J.M. Rodríguez Mellado, and R. Marín Galvín J. Electroanal. Chem. 293 1990 185
21. M.C. Corredor, J.M. Rodríguez Mellado, and M. Ruiz Montoya J. Electrochem. Soc. 153 2006 E33
22. J.M. Rodríguez Mellado, R. Marín Galvín, and M. Ruiz Montoya New Trends in Electrochemistry Research 2007 Nova Science Publishers Inc. New York and references cited therein (Chapter 7)
23. C.P. Andrieux, L. Nadjo, and J.M. Savéant J. Electroanal. Chem. 26 1970 147
24. L. Nadjo, and J.M. Savéant J. Electroanal. Chem. 48 1973 113
25. C.P. Andrieux, L. Nadjo, and J.M. Savéant J. Electroanal. Chem. 42 1973 223
26. C. Amatore, and J.M. Savéant J. Electroanal. Chem. 103 1979 303
27. L. Nadjo, and J.M. Savéant J. Electroanal. Chem. 137 1982 149
28. S.G. Mairanovski, and R.G. Baisheva Soviet Electrochem. 5 1969 832
29. R.F. Evilia, and A.J. Diefenderfer J. Electroanal. Chem. 22 1969 407
30. J. Holubek, and J. Volke Collect. Czech Chem. Commun. 27 1962 680
31. S. Kashti, and E. Kirowa-Eisner J. Electroanal. Chem. 103 1979 119
32. Experts of the European Commission, Directorate-General XI: Environment, Nuclear Safety and Civil Protection, DirectorateE-Industry and Environment. Priorisation of Substances Dangerous to the Aquatic Environment, Experts Meeting, Brussels, 1998, Room Document M0207WD3.