Enantiotopic discrimination in the deuterium NMR spectrum of solutes with S4 symmetry in chiral liquid crystals

Journal of Chemical Physics

Volumn 134, Issue 13, 2011, Pages

  Aroulanda, Christie ^a   Zimmermann, Herbert ^b   Luz, Zeev ^c   Lesot, Philippe ^a  

^a UNIVERSITÉ PARIS SUD   (France)

^b MAX PLANCK INSTITUTE FOR MEDICAL RESEARCH   (Germany)

^c WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

ANTI-SYMMETRIC; CHIRAL LIQUID CRYSTALS; CHIRAL NEMATICS; COSOLVENTS; DEUTERIUM NMR; FOUR-CORE; L-GLUTAMATE; LEAST SQUARES; LYOTROPIC MESOPHASES; MATRIX; METHYLENE GROUPS; MOLECULAR GEOMETRIES; NMR SPECTRUM; ORDER PARAMETER; ORDERING MECHANISM; PHYSICAL MEANINGS; PROTON DECOUPLING; QUADRUPOLES; RACEMIC MIXTURES; SPLITTINGS; SYMMETRY CONSIDERATION;

COMPLEXATION; CRYSTALS; DEUTERIUM; LIQUID CRYSTALS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLVENTS;

CRYSTAL SYMMETRY;

DEUTERIUM; DRUG DERIVATIVE; POLY GAMMA BENZYL GLUTAMATE; POLY-GAMMA-BENZYL-L-GLUTAMATE; POLYGLUTAMIC ACID; PYRIDINE; PYRIDINE DERIVATIVE;

ARTICLE; CHEMISTRY; LIQUID CRYSTAL; METHODOLOGY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM;

DEUTERIUM; LIQUID CRYSTALS; MAGNETIC RESONANCE SPECTROSCOPY; POLYGLUTAMIC ACID; PYRIDINES; STEREOISOMERISM;

EID: 79954558642     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3554640     Document Type: Article

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28. See supplementary material at http://dx.doi.org/10.1063/1.3554640 E-JCPSA6-134-031106 for an access to i) data relative to molecular modeling of 1, ii) the director cosines for the various independent CH directions, iii) the isotropic NMR experiments, and iv) all NMR spectra recorded in oriented solvents and data discussed but not reported in the main text.