Experimental determination of NA-CA distribution between tourmaline and fluid in the system CaO-Na2O-MgO-Al2O3-SiO 2-B2O3-H2O

Canadian Mineralogist

Volumn 49, Issue 1, 2011, Pages 137-152

  Von Goerne, Gabriela ^a   Franz, Gerhard ^a   Van Hinsberg, Vincent J ^b  

^a LEIBNIZ INSTITUT FÜR KATALYSE E V AN DER UNIVERSITÄT ROSTOCK   (Germany)

^b MCGILL UNIVERSITY   (Canada)

Author keywords

Deprotonation; Dravite; Fluid tourmaline equilibrium; Hydrothermal experiments; Na Ca distribution; Uvite

Indexed keywords

CA SUBSTITUTION; DRAVITE; ENDMEMBERS; EXPERIMENTAL DETERMINATION; FLUID COMPOSITION; HYDROTHERMAL EXPERIMENTS; MINERAL PARAGENESIS; MOLARITY; NA-CA DISTRIBUTION; NATURAL SYSTEMS; SITE OCCUPANCY; STARTING MATERIALS; SYNTHESIS EXPERIMENT; UNIT-CELL PARAMETERS; UVITE;

ALUMINUM; CALCIUM; CALCIUM CHLORIDE; EXPERIMENTS; FELDSPAR; FLUIDS; QUARTZ; RIETVELD METHOD; RIETVELD REFINEMENT; SILICON COMPOUNDS; SODIUM; SODIUM CHLORIDE;

SILICATE MINERALS;

DRAVITE; EXPERIMENTAL MINERALOGY; FLUID COMPOSITION; HYDROTHERMAL SYSTEM; PLAGIOCLASE; PRESSURE EFFECT; TEMPERATURE EFFECT; TOURMALINE;

EID: 79954527702     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: 10.3749/canmin.49.1.137     Document Type: Article

References (40)

1. Bosi, F. & LUCCHESI, S. (2004): Crystal chemistry of the schorl-dravite series. Eur. J. Mineral. 16, 335-344. (Pubitemid 38550199)
2. BURT, D.M. (1989): Vector representation of tourmaline compositions. Am. Mineral. 74, 826-839.
3. BUTTNER, S.H. (2005): Deformation-controlled cation diffusion in compositionally zoned tourmaline. Mineral. Mag. 69,471-489.
4. 12OH solid-solution series of zoisite and clinozoisite. Am. Mineral 92, 1133-1147.
5. DUTROW, B.L., FOSTER, C.T., JR. & HENRY, D.J. (1999): Tourmaline-rich pseudomorphs in sillimanite zone metapelites: demarcation of an infiltration front. Am. Mineral. 84, 794-805.
6. FOIT, F.F., JR., FUCHS, Y. & MYERS, P. (1989): Chemistry of alkali-deficient schorls from two tourmaline-dumortierite deposits. Am. Mineral. 74, 1317-1324.
7. GRICE, J.D. & ERCIT, T.S. (1993): Ordering of Fe and Mg in tourmaline: the correct formula. Neues Jahrb. Mineral, Abh. 165, 245-266.
8. GRICE, J.D., ERCIT, T.S. & HAWTHORNE, RC, (1993): Povondraite, a redefinition of the tourmaline ferridravite. Am. Mineral. 78, 433-436.
9. HAWTHORNE, F.C. (1996): Structural mechanisms for light-element variations in tourmaline. Can. Mineral. 34, 123-132.
10. HAWTHORNE, F.C. & HENRY, D.J. (1999): Classification of the minerals of the tourmaline group. Eur. J. Mineral. 11, 201-215.
11. HAWTHORNE, F.C., MACDONALD, D.J. & BURNS, P.C. (1993): Reassignment of cation site occupancies in tourmaline: Al-Mg disorder in the crystal structure of dravite. Am. Mineral. 78, 265-270.
12. HENRY, D.J. & DUTROW, B.L. (1990): Ca substitution in Lipoor aluminous tourmaline. Can. Mineral. 28, 111-124.
13. HENRY, D.J. & DUTROW, B.L. (1996): Metamorphic tourmaline and its petrologic applications. In Boron: Mineralogy, Petrology and Geochemistry (E.S. Grew & L.M. Anovitz, eds.). Rev. Mineral. 33, 503-557.
14. HENRY, D.J., NOVAK, M., HAWTHORNE, F.C., ERTL, A., DUTROW, B.L., UHER, P. & PEZZOTTA, F. (2009): The tourmaline group minerals: a consistent nomenclature. Geol. Soc. Am., Abstr. Programs 41, 100.
15. 4]B content in zoned Febearing olenite from Koralpe, Austria. Am. Mineral. 89, 447-454.
16. KROSSE, S. (1995): Hochdrucksynthese, Stabilität und Eigenschaften der Borsilikate Dravit und Korneruppin sowie Darstellung und Stabilitätsverhalten Eines Neuen MgAl-Borates. Doctoral Thesis, Ruhr-Universität, Bochum, Germany.
17. LARSON, A. & VON DREELE, R. (1996): GSAS Generalized crystal structure analysis system. Los Alamos National Laboratory, Rep. LA-UR-87-748.
18. LONDON, D. & MANNING, D.A.C. (1995): Chemical variation and significance of tourmaline from southwest England. Econ. Geol. 90,495-519.
19. 4, a new alkali-deficient tourmaline: description and crystal structure. Am. Mineral. 78, 1299-1303.
20. MACDONALD, D.J. & HAWTHORNE, F.C. (1995): The crystal chemistry of Si ⇄ Al substitution in tourmaline. Can. Mineral. 33, 849-858.
21. MORGAN, G.B., VI & LONDON, D. (1989): Experimental reactions of amphibolite with boron-bearing aqueous fluids at 200MPa: implications for tourmaline stability and partial melting in mafic rocks. Contrib. Mineral. Petrol. 102, 281-297.
22. NAJORKA, J., GOTTSCHALK, M., FRANZ.G. & HEINRICH, W. (1999): Ca-Sr distribution between amphibole, clinopyroxene and chloride-bearing solutions. Am. Mineral. 84, 596-606.
23. POUCHOU J.L. & PICHOIR F. (1985) "PAP" φ(pZ) procedure for improved quantitative microanalysis. In Microbeam Analysis (JT. Amstrong, ed.). San Francisco Press, San Francisco, California (104-106).
24. ROBERT, J.-L., LINNEN, R. & ROUER, O. (1993): The OH-F substitution in natural and synthetic tourmalines. Terra Abstr. 5,498.
25. ROSENBERG, P.E. & FOIT, F.F., JR. (1979): Synthesis and characterization of alkali-free tourmaline. Am. Mineral. 64, 180-186.
26. 2O. Am. Minerals, 1217-1223.
27. SELWAY, J.B., NOVÁK M., ČERNÝ P. & HAWTHORNE, F.C. (1999): Compositional evolution of tourmaline in lepidolite-subtype pegmatites. Eur. J. Mineral. 11,569-584.
28. TAYLOR, B.E. & SLACK, J.F. (1984): Tourmalines from Appalachian-Caledonian massive sulfide deposits: textural, chemical and isotopic relationships. Econ. Geol. 79,1703-1726.
29. VAN HINSBERG, V.J. & SCHUMACHER, J.C. (2007): Intersector element partitioning in tourmaline: a potentially powerful single crystal thermometer. Contrib. Mineral. Petrol. 153, 289-301.
30. VAN HINSBERG, V.J. & SCHUMACHER, J.C. (2009): The geothermobarometric potential of tourmaline, based on experimental and natural data. Am. Mineral. 94,761-770.
31. VAN HINSBERG, V.J., SCHUMACHER, J.C., KEARNS, S., MASON, P.R.D. & FRANZ, G. (2006): Sector zoning in metamorphic tourmaline and resultant major and trace element fractionation. Am. Mineral. 91, 717-728.
32. VELICKOV, B. (2002): Kristallchemie von Fe, Mg-Turmalinen: Synthese und spektroskopische Untersuchungen. Doctoral Thesis, Technische Universität Berlin, Germany.
33. VOLL, G. (1969): Klastische Mineralien aus den Sedimentserien der Schottischen Highlands und ihr Schiksal bei aufsteigender Regional- und Kontaktmetamorphose. Habilitation Thesis, Technische Universität Berlin, Germany.
34. 2OHCl. Mineral. Petrol. 69, 161-182.
35. 2O-HCl and the distribution of Na between tourmaline and fluid at 300 to 700°C and 200 MPa. Contrib. Mineral. Petrol. 141, 160-173.
36. VON GOERNE, G., FRANZ, G. & WIRTH, R. (1999): Hydrothermal synthesis of large dravite crystals by the chamber method. Eur. J. Mineral. 11, 1061-1077.
37. WILLIAMSON, B.J., SPRATT, J., ADAMS, JT., TINDLE, A.G. & STANLEY, C.J. (2000): Geochemical constraints from zoned hydrothermal tourmalines on fluid evolution and Sn mineralization: an example from fault breccias at Roche, SW England. J. Petrol. 41, 1439-1453.
38. 2O (NABSH). Terra Nova Abstr. 10, 68.
39. ZIMMERMANN, R., GOTTSCHALK, M. HEINRICH, W. & FRANZ, G. (1997b): Experimental Na-K-distribution between amphiboles and aqueous chloride solutions, and a mixing model along the richterite-K-richterite join. Contrib. Mineral. Petrol. 126, 252-264.
40. ZIMMERMANN, R., KNOP, E., HEINRICH, W., PEHLKE, I. & FRANZ, G. (1997a): Disequilibrium in cation exchange experiments between Na-K-Ca amphiboles (richterite-tremolite) and aqueous Na-K-Ca chloride solutions: effects of fractional crystallization. Eur. J. Mineral. 9, 97-114.