The effect of surface charge and wettability on H2O self diffusion in compacted clays

Clays and Clay Minerals

Volumn 59, Issue 1, 2011, Pages 42-57

  Schampera, Birgit ^a   Dultz, Stefan ^a  

^a LEIBNIZ UNIVERSITY HANNOVER   (Germany)

Author keywords

Bentonite; Bound H2O; Diffusive transport; Organo clays; Surface charge; Wettability

Indexed keywords

ATTENUATED TOTAL REFLECTANCE; BOUND H2O; BULK DENSITY; CATION EXCHANGE CAPACITIES; COMPACTED CLAYS; DIFFUSIVE TRANSPORT; EFFECTIVE DIFFUSION COEFFICIENTS; ENGINEERED BARRIERS; EXTERNAL SURFACES; FOURIER; FTIR; HEXADECYLPYRIDINIUM; HYDROPHOBIC SURFACES; NEGATIVE VALUES; ORDER OF MAGNITUDE; ORGANIC CATIONS; ORGANO-CLAYS; POSITIVE CHARGES; POSITIVE VALUE; RETARDATION FACTORS; SATURATED CONDITIONS; SELF-DIFFUSION; UNDER WATER; WATER SATURATIONS; WATER VOLUMES; WATER-SATURATED STATE; WETTABILITY;

ADSORPTION; BENTONITE; CHARGED PARTICLES; CLAY MINERALS; CONTACT ANGLE; HYDROPHILICITY; HYDROPHOBICITY; MONOLAYERS; POSITIVE IONS; SILICATE MINERALS; SURFACE CHARGE; SURFACE CHEMISTRY; SURFACE PROPERTIES; TRANSPORT PROPERTIES;

CURING;

ADSORPTION; BENTONITE; BULK DENSITY; CATION EXCHANGE CAPACITY; DIFFUSION; FTIR SPECTROSCOPY; HYDROPHOBICITY; MONTMORILLONITE; ORGANOCLAY; REFLECTANCE; SATURATION; WETTABILITY;

EID: 79954511889     PISSN: 00098604     EISSN: 15528367     Source Type: Journal    
DOI: 10.1346/CCMN.2011.0590107     Document Type: Article

References (53)

1. An, J.-H. and Dultz, S. (2007) Adsorption of tannic acid on chitosan-montmorillonite as a function of pH and surface charge properties. Applied Clay Science, 36, 256-264.
2. Bachmann, J., Woche, S.K., Goebel, M.-O., Kirkham, M.B., and Horton, R. (2003) Extended methodology for determining wetting properties of porous media. Water Resources Research, 39, article no. 1353.
3. Böckenhoff, K. and Fischer, W.R. (2001) Determination of electrokinetic charge with a particle-charge detector and its relationship to the total charge. Fresenius Journal of Analytical Chemistry, 371, 670-674.
4. Bors, J., Gorny, A., and Dultz, ST. (1997) Iodide, caesium and strontium adsorption by organophilic vermiculite. Clay Minerals, 32, 21-28.
5. Bors, J., Dultz, S., and Riebe, B. (2000) Organophilic bentonites as adsorbents for radionuclides I. Adsorption of ionic fission products. Applied Clay Science, 16, 1-13.
6. Bourg, I.C., Sposito, G., and Bourg, A.C.M. (2006) Tracer diffusion in compacted, water-saturated bentonite. Clays and Clay Minerals, 54, 363-374.
7. Boving, T.B. and Grathwohl, P. (2001) Tracer diffusion coefficient in sedimentary rocks: correlation to porosity and hydraulic conductivity. Journal of Contaminant Hydrology, 53, 85-100.
8. Chatterjee, A., Iwasaki, T., Ebina, T., and Hayashi, H. (1997) Quantum chemical calculation on clay-water interface. Applied Surface Science, 121/122, 167-170.
9. Delage, P., Marcial, D., Cui, Y.J., and Ruiz, X. (2006) Ageing effects in compacted bentonite: a microstructure approach. Ge ́otechnique, 56, 291-304.
10. Duval, F.P., Porion, P., Faugère, A.-M., and Van Damme, H. (2001) An NMR investigation of water self-diffusion and relaxation rates in controlled ionic strength laponite sols and gels. Journal of Colloid and Interface Science, 242, 319-326.
11. Fielderson, G.T. and Barbari, T.A. (1993) The use of FTi.r.- a.t.r spectroscopy to characterize penetrant diffusion in polymers. Polymer, 34, 1146-1153.
12. Garcia-Gutierrez, M., Mingarro, M., Missana, T., Martin, P.L., Sedano, L.A., and Cormenzana, J.L. (2004) Diffusion experiments with compacted powder/pellets clay mixtures. Applied Clay Science, 26, 57-64.
13. Gillham, R.W., Robin, M.J.L., Dytynyshyn, D.J., and Johnston, H.M. (1984) Diffusion of nonreactive and reactive solutes through fine-grained barrier material. Canadian Geotechnical Journal, 23, 541-550.
14. 3 non-ionic surfactant on a Casmectite. Clays and Clay Minerals, 57, 502-509.
15. Hicher, P.Y., Wahyudi, H., and Tessier, D. (2000) Microstructural analysis of inherent and induced anisotropy in clay. Mechanics of Cohesive-Frictional Materials, 5, 341-371.
16. Hunt, A.G. and Ewing, R.P. (2003) On the vanishing of solute diffusion in porous media at a threshold moisture content. Soil Science Society of America Journal, 67, 1701-1702.
17. Hunter, R. (1993) Introduction to Modern Colloid Science. Oxford University Press, Oxford, UK, 338 pp.
18. Ichikawa, Y., Kawamura, K., Nakano, M., Kitayama, K., and Kawamura, H. (1999) Unified molecular and homogenization analysis for bentonite behaviour: current results and future possibilities. Engineering Geology, 54, 21-32.
19. Ichikawa, Y., Kawamura, K., Nakano, M., Kitayama, K., Seiki, T., and Theramast, N. (2001) Seepage and consolidation of bentonite saturated with pure- or salt water by method of unified molecular dynamics and homogenization analysis. Engineering Geology, 60, 127-138.
20. Imai, Y., Nishimura, S., Inukai, Y., and Tateyama, H. (2003) Differences in quasicrystals of smectite-cationic surfactant complexes due to head group structures. Clays and Clay Minerals, 51, 162-167.
21. Jeschke, F. and Meleshyn, A. (2010) A Monte Carlo study of interlayer and surface structures of tetraphenyl-phosphonium- modified Na-montmorillonite. Geoderma (in press).
22. Johnston, C.T. and Tombacz, E. (2002) Surface chemistry of minerals. Pp. 37-67 i n: Soi l Mineralogy with Environmental Applications (J.B. Dixon and D.G. Schulze, editors). SSSA Book Series, no. 7, Soil Science Society of America, Madison, Wisconsin, USA.
23. Jougnot, D. and Revil, A. (2007) Diffusion of ions in unsaturated clay-rocks: theory and application to the Callovo-Oxfordian argillite. International Meeting on Clay in Natural and Engineered Barriers for Radioactive Waste Confinement, Lille, France, pp. 247-248.
24. Koh, S.M., Song, M.S., and Takagi, T. (2005) Mineralogy, chemical characteristics and stabilities of Cetylpyridinium-exchange smectite. Clay Minerals, 40, 213-222.
25. Kozaki, T., Inada, K., Sato, S., and Ohashi, H. (2001) Diffusion mechanism of chloride ions in sodium montmorillonite. Journal of Contaminant Hydrology, 47, 159-170.
26. Kung, K.-H.S. and Hayes, K.F. (1993) Fourier transform infrared spectroscopic study of adsorption of cetyltrimethylammonium bromide and cetylpyridinium chloride on silica. Langmuir, 9, 263-267.
27. Li, Y.-H. and Gregory, S. (1974) Diffusion of ions in sea water and in deep-sea sediments. Geochimica et Cosmochimica Acta, 38, 703-714.
28. Li, Z.H. and Bowman, R.S. (1998) Sorption of chromate and PCE by surfactant modified clay minerals. Environmental Engineering Science, 15, 237-245.
29. Longsworth, L.G. (1960) The mutual diffusion of light and heavy water. Journal of Chemical Physics, 64, 1914-1917.
30. Lorenzetti, R.L., Shannon, L., Bartelt-Hunt, Burns, S.E., and Smith, J.A. (2005) Hydraulic conductivities and effective diffusion coefficients of geosynthetic clay liners with organobentonite amendments. Geotextiles and Geomembranes, 23, 385-400.
31. Marry, V., Rotenberg, B., and Turq, P. (2008) Structure and dynamics of water at a clay surface from molecular dynamics simulation. Physical Chemistry Chemical Physics, 10, 4802-4813.
32. Mazo, M.A., Manevitch, L.I., Gusarova, E.B., Berlin, A.A., Balabaev, N.K., and Rutledge, G.C. (2008) Molecular dynamics simulation of thermomechanical properties of montmorillonite crystal. II. Hydrated montmorillonite crystal. The Journal of Chemical Physics C, 112, 17056-17062.
33. Meleshyn, A. (2009) Cetylpyridinium aggregates at montmorillonite- and muscovite-water interface: a Monte Carlo study of surface charge effect. Langmuir, 25, 6250-6259.
34. Meleshyn, A. and Bunnenberg C. (2006) Interlayer expansion and mechanisms of anion sorption of Na-montmorillonite modified by Cetylpyridinium chloride: A Monte Carlo study. Journal of Physical Chemistry B, 110, 2271-2277.
35. Michot, L.J., Villieras, F., Francois, M., Bihannic I., Pelletier, M., and Cases, J.-M. (2002) Water organisation at solidaqueous solution interface. Geoscience, 334, 611-631.
36. Mills, R. (1973) Self-diffusion in normal and heavy water in the range 1-45oC. Journal of Physical Chemistry, 77, 685-689.
37. Nakashima, Y. (2003) Diffusion of H2O in smectite gels: obstruction effects of bound H2O layer. Clays and Clay Minerals, 51, 9-22.
38. Nakashima, Y. and Mitsumori, F. (2005) H2O self-diffusion restricted by clay platelets with immobilized bound H2O layers: PGSE NMR study of water-rich saponite gels. Applied Clay Science, 28, 209-221.
39. Oyanedel-Craver, V.A., Fuller, M., and Smith, J.A. (2007) Simultaneous sorption of benzene and heavy metals onto two organoclays. Journal of Colloid and Interface Science, 309, 485-492.
40. Patel, H.A., Somani, R.S., Bajaj, H.C., and Jasra, R.V. (2007) Preparation and characterization of phosphonium montmorillonite with enhance thermal stability. Applied Clay Science, 35, 194-200.
41. Revil, A. and Jougnot, D. (2008) Diffusion of ions in unsaturated porous materials. Journal of Colloid and Interface Science, 319, 226-235.
42. Rytwo, G., Huterer-Harari, R., Dultz, S., and Gonen, Y. (2006) Adsorption of fast green and erythrosine-B to montmorillonite modified with crystal violet. Journal of Thermal Analysis and Calorimetry, 84, 225-231.
43. Rytwo, G., Kohavi, Y., Botnick, I., and Gonen, Y. (2007) Use of CV- and TPP-montmorillonite for the removal of priority pollutants from water. Applied Clay Science, 36, 182-190.
44. Schampera, B. and Dultz, S. (2009) Determination of diffusive transport in HDPy-montmorillonite by H2O-D2O exchange using in situ ATR-FTIR spectroscopy. Clay Minerals, 44, 249-266.
45. Shackelfo r d, C.D. and Daniel, E.D. (1991) Diffusion in saturated soil. I: Background. Journal of Geotechnical Engineering, 117, 467-484.
46. Simonyan, A.V., Behrens, H., and Dultz, S. (2009) Diffusive transport of water in porous feldspars from granitic saprolites: In situ experiments using FTIR spectroscopy. Geochimica et Cosmochimica Acta, 73, 7019-7033.
47. Soule, N.M. and Burns, S.E. (2001) Effect of organic cation structure on behaviour of organobentonites. Journal of Geotechnical and Geoenvironmental Engineering, 127, 363-370.
48. Tanaka, R. and Hirayama, N. (2008) Crystal structure of benzethonium chloride monohydrate. Analytical Sciences, 24, 163-164,
49. Van Loon, L.R., Glaus, M.A., and Müller W. (2007) Anion exclusion effects in compacted bentonites: towards a better understanding of anion diffusion. Applied Geochemistry, 22, 2536-2552.
50. Van Reeuwijk, L.P. (2003) Procedures for Soil Analysis (6th edition). ISRIC Technical paper 9. Wageningen,
51. Woche, S.K., Goebel, M.-O., Kirkham, M.B., Horton R., van der Ploeg R.R., and Bachmann, J. (2005) Contact angle of soils as affected by depth, texture, and land management. European Journal of Soil Science, 56, 239-251.
52. Yllera, A., Hernandez, M., Mingarro, A., Quejido, L.A., Sedano, J.M., Soler, J., Samper, J., Molinero, J.M., Barcala, P.L., Martýn, M., Fernandez, P., Wersin, P., Rivas, P., and Hernan, P. (2004) DI-B experiment: planning, design and performance of an in situ diffusion experiment in the Opalinus Clay formation. Applied Clay Science, 26, 181-196.
53. Zhu, J., Zhu, L., Zhu, R., and Chen, B. (2008) Microstructure of organo-bentonites in water and effect of steric hindrance on the uptake of organic compounds. Clays and Clay Minerals, 56, 144-154.